International Science Community Association Research Journal of Chemical Sciences 2231 - 606X 7 1 2017 01 18 Synthesis, compositional and spectral studies of some transition metal complexes with 3-aminolawsonoxime 25 31 EN Borse G.P. 1 Department of Chemistry, R.L. College, Parola–425 111, MS, India Pethe G.B. 1 Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India Bansod A.D. 2 Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India Devhade J.B. 3 Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India Maldhure A.K. 4 Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India Aswar A.S. 5 Department of Chemistry, Sant Gadge Baba Amravati University Amravati-444 602, MS, India Muskawar Prashant Narayan 1 Department of Chemistry, Amolakchand Mahavidyalaya, Yavatmal, 445 001, India Bhagat Pundlik Rambhau 2 Organic Chemistry Division, SAS, VIT University, Vellore, 632 014, India Nemade A.M. 1 Department of Chemistry, Dr. A.G.D. Bendale Mahila Mahavidyalaya, Jalgaon-425001, MS, India Patil K.D. 2 Department of Chemistry, Bhusawal Arts, Science and P O N Commerce College, Bhusawal-425201, MS, India Kolhe V.C. 3 Ex. Director, BCUD, North Maharashtra University, Jalgaon-425001, MS, India > Research Paper 2016 8 24 2017 01 18 The metal complexes which were synthesized from organic compounds containing oxygen and nitrogen donors are of great interest for structural study. The derivative of quinine, lawson (2-hydroxy-1,4- naphthoquinone) is natural coloring matter and is also indicated in the treatment of various ailment and diseases and as disinfectant. The hydroxyl derivative of 1,4- naphthoquinone is of great interest due to its slight therapeutic property. The general method is adopted for preparation of oxime, the ligand 3-Aminolawsoneoxime (3-Amino-2-hydroxy, 4-keto 1-naphthoxime) was synthesized from 3-Amino-2-hydroxy-1, 4-Naphthoquinone. Some of the transition metal such as Fe, Co, Ni and Cu are in form of their salts were used for the complexation. The synthesized complexes were characterized by various physico-chemical techniques such as compositional studies and spectral studies. It has been found that the probable formulation of the complexes is M L (H2O) 2. Wherein M : L stoichiometry is 1:1.The spectral data while and magnetic studies of the metal complexes proposed distorted tetrahedral structure for Fe, Co and Ni complexes and square planer structure may be proposed for copper complex. Copyright@ International Science Community Association