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Potential of Ionic Conductivity and Transport Properties Solid Biopolymer Electrolytes Based Carboxy Methylcellulose/ Chitosan Polymer Blend Doped with Dodecyltrimethyl Ammonium Bromide

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Author Affiliations

  • 1 Advanced Materials Research Group, School of Fundamental Sciences, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, MALAYSIA
  • 2 Center of Corporate Communication and Image Development, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, MALAYSIA

Res. J. Recent Sci., Volume 3, Issue (10), Pages 69-74, October,2 (2014)

Abstract

The production of an electrolyte via solution casting techniques has been applied in carboxy methylcellulose (CMC)/ chitosan (CS) biopolymer blend doped with different composition of dodecyltrimethyl ammonium bromide(DTAB). Conductivity of the electrolytes at the ambient temperature (303K) containing 5wt. % of DTAB was increased 1.85 x 10-6Scm-1. The Electrical Impedance Spectroscopy (EIS) shows the temperature dependence of ionic conductivity has obeys the Arrhenius Rule where increasing the temperature will increase the conductivity of the electrolytes. The transference number measurement (TNM) shows conductivity of the electrolytes was relate with the ionic mobility, µ and the diffusion coefficient, D of cations and anions in the SBEs systems. The systems show more cationic than anionic conductor reveals that this system is a proton conductor.

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