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Development of Sensitive Voltammetric Method for Determination of Thorium in Waste Waters

Author Affiliations

  • 1MVJ College of Engineering, Bangalore, Karnataka, INDIA.
  • 2 Department of Chemistry, C.D.L.University, Sirsa 125055, Haryana, INDIA.

Res. J. Recent Sci., Volume 2, Issue (ISC-2012), Pages 47-50, February,2 (2013)

Abstract

An indirect voltammetric determination method of thorium based on the displacement reaction between Th (IV) and Zn (II) - EDTA complex in ammonium acetate buffer medium is described. The limit of quantification of 0.005 ppm was observed using differential pulse polarography. The possibly associated metal ions did not interfered in measurements. The method has been successfully applied for the analysis of thorium in waste water samples.

References

  1. Emsley J., The Elements, Oxford University Press, Oxford, (1988)
  2. Hirano Y., Ogawa Y. and Oguma K., Anal. Sci., 19, 303 (2003)
  3. Ahmed M. Jamaluddin and Haque M. Reazul, Res.J.chem.sci., 1(1), 46-59 (2011) , 47-50 (2013)
  4. Rohilla Rajni and Gupta Usha, Res. J. Chem. Sci. , 2(11), 8-13 (2012)
  5. Esat T.M., Int. J. Mass Spect. Ion Processes, 148, 159 (1995)
  6. Kumar Sukender, Singh Jaspreet, Das Sneha and Garg Munish, Res.J.chem.sci., 2(3), 46-51 (2012)
  7. Mohammed S.S., Batu M.A. and Mohammed M.B., Res. J. Chem. Sci., 2(12), 65-68 (2012)
  8. Okereke N.A. and Ekpunobi A.J., Res. J. chem. sci., 1(6), 64-70 (2011)
  9. Kulkurni M.J., Argekar A.A., Mathur J.N. and Page A.G., Anal. Chim. Acta, 370, 163 (1998)
  10. Benedik L. and Byrne A.R., J. Radioanal. Nucl. chem, 189, 325 (1995)
  11. Labrecque J.J., Adames D. and Parker W.C., Appl. Spect., 35, 502 (1991)
  12. Wang J., Analytical Electrochemistry, VCH Publishers, New York (1994)
  13. Bard A.J., Parsons R. and Jordan J. (Eds.), Standard Potentials in Aqueous Solutions, Marcel Dekker, New York (1985)
  14. Gritzner G., Gautmann V. and Michlmayr M., Z. Anal. Chem., 224, 245 (1967)
  15. Mosrafa M.M., Elewady Y.A and Girges M.A., J. Less Comm. Metals, 70, 59 (1980)
  16. Duyckaerts D. and Degueldre C., J. Electroanal. Chem., 119, 347 (1981)
  17. Cassayre L., Serp J. and Soucek P., Electrochim Acta, 52, 7432 (2007)
  18. Sindhu R.S., Pandeya K.B. and Singh R.P., Fresenius J. Anal. Chem., 290, 318 (1978)
  19. Plock C.E. and Vasquez J., Anal. Chim. Acta, 57, 113 (1971)
  20. Das S.K., Kulkarni A.V. and Dhaneshwar R.G., Analyst, 118, 1153 (1993)
  21. J.N. Li, F.Y. Yi, Z.M. Jiang and J.J. Fei, Microchim. Acta, 143, 1436 (2004)
  22. S. Liu, J. Li, X. Mao and P. Gao, Anal. Lett., 36, 381 (2003)
  23. Sharma P. and Agarwal A., Anal. Lett., 39, 1421 (2006)
  24. Sharma P.and Kherwa V., J. Indian Chem. Soc., 89, 1 (2012)
  25. Sharma P. and Dubey S., Indian J. Chem. Tech., 17, 396 (2010)
  26. Sharma P. and Agarwal A., Bull. Electrochem., 20, 145 (2004)
  27. Sharma P. and Agarwal A., Bull. Electrochem., 21, 129 (2005)
  28. H.W. Nurnberg, Approved Voltammetric Methods for the Determination of Some Toxic Trace Metals, Nuclear Research Centre Publication, K.F.A. Juelich (1977)
  29. Willard H., Merrit L. and Dean J., Instrumental Methods of Analysis, 5th edn. ED Van Nostrand, New York, (1974)
  30. Sharma P. and Vyas S., J. Electrochem. Soc. India, 48, 311 (1999)