5th International Young Scientist Congress (IYSC-2019).  International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Vanadium Pentoxide Cathode Material for Fabrication of All Solid State Lithium-Ion Batteries - A Case Study

Author Affiliations

  • 1 Department of Physics, Andhra Loyola College, Vijayawada – 520008, INDIA

Res. J. Recent Sci., Volume 2, Issue (3), Pages 67-73, February,2 (2013)

Abstract

Transition metal oxides have been a subject of research in recent years in view of their fundamental and technological aspects. Among these, vanadium creates many compounds with oxygen; these have different structural, optical and chemical properties. Vanadium pentoxide (V2O5) is a thermodynamically stable form which exhibits electrochromic properties. A lot of recent research has been focused on the synthesis and fabrication of nanostructured vanadium oxides to mitigate the slow electrochemical kinetics with high specific surface area and short diffusion distance. Vanadium pentoxide with a layered structure is promising for smart window applications. V2O5 crystallizes with an orthorhombic unit cell and belongs to Pmnm space group with lattice parameter a = 11.510 , b = 3.563 , c = 4.369 , where the b and c are often interchanged. The stoichiometry of V2O5 is considered as deformed octahedral VO6 which serves as the building block of the V2O5 structure. As a thin film, it exhibits multi colored electrochromism and has high potential for use in electrochromic display devices, color filters and other optical devices. Bulk and thin film V2O5 with vandal oxygen vacancies have been used as an oxidation catalyst. This paper deals with the detailed technological aspects of properties, different structures of V2O5 as candidate cathode material for the fabrication of all solid state lithium ion batteries with wide applications of V2O5 films as electrochromic cells and gas sensors.

References

  1. Karunakaran C. and Senthilvelan S.J., Colloid Interface Sci., 289, 466-472 (2005)
  2. Wang Y. and Cao G., J. Chem. Mater., 18, 2787-2793 (2006)
  3. Whittingham M.S., J. Electrochem. Soc., 123, 315-322 (1976)
  4. Watanabe T., Ikeda Y., Ono T., Hibino M., Hosoda M., Sakai K. and Kudo T., Solid State Ionics, 151, 313 (2002)
  5. Wang Y. and Cao G.Z., J. Electrochim. Acta., 51, 4865 (2006)
  6. Wang Y. and Cao G.Z., J. Chem. Mater., 18, 2787 (2006)
  7. Takahashi K., Limmer S.J., Wang Y. and Cao G.Z., J. Appl. Phys., 44, 662 (2005)
  8. Navone C., Baddour-Hadjean R., Pereira-Ramos J.P. and Salot R., J. Electrochem. Soc., 152, 1790 (2005)
  9. Giorgetti M., Berrettoni M. and Smyrl W.H., J. Chem. Mater., 19, 5991 (2007)
  10. Coustier F., Hill J., Owens B.B., Passerini S. and Smyrl W.H., J. Electrochem. Soc., 146, 1355 (1999)
  11. Sarkar P. and Nicholso P.S., J. Am. Ceram. Soc., 79, 1987 (1996)
  12. Gao X., Bare S.R., Weckhuysen B.M. and Wachs I.E., J. Phys. Chem. B 102 10842 (1998)
  13. Catana G., Ramachandra Rao R., Weckhuysen B.M., vander Voort P., Vansant E. and Schoonheydt R., J. Phys. Chem. B 102, 8005 (1998)
  14. Whittingham M.S., Chem. ReV., 104, 4271 (2004)
  15. Whittingham M.S., Song Y., Lutta S., Zavalij P.Y. and Chernova N.A., J. Mater. Chem., 15, 3362 (2005)
  16. Ying Wang and Guozhong Cao, Synthesis and Enhanced Intercalation Properties of Nanostructured Vanadium Oxides, J. Chem. Mater., 18, 2787-2804 (2008)
  17. Schoiswohl J., Surnev S., Netzer F.P. and Kresse G., Vanadium oxide nanostructures from zero- to three-dimensional, J. Phys. Condens. Matter., 18, R1–R14 (2006)
  18. Crespi A., Schmidt C., Norton J., Chen K. and Skarstad P. J. Electrochem. Soc., A 30, 274-231 (2001)
  19. Morcrette M., Rozier P., Dupont L., Mugnier E., Sannier L. and Galy, J. Tarascon, J.M. Nat. Mater., 2, 755 (2003)
  20. Morcrette M., Martin P., Rozier P., Vezin H., Chevallier F., Laffont L., Poizot P. and Tarascon, J. M. Chem. Mater., 17, 418 (2005)
  21. Karunakaran, C.; Senthilvelan, S. J. Colloid Interface Sci., 289, 466 (2005)
  22. Snow E. S., Perkins F. K., Houser E. J., Badescu S. C. and Reinecke T. L., Science 307, 1942 (2005)
  23. Ying Wang, Katsunori Takahashi, Kyoungho Lee and Guozhong Cao., Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium-Ion Intercalation, Adv. Funct. Mater., 16, 1133-1144 (2006)
  24. Baba M., Kumagai N., Kobayashi H., Nakano O., and Nishidate K., Fabrication Electrochemical Characteristics of All-Solid-State Lithium-Ion Batteries Using V2O5 Thin Films for Both Electrodes, Electrochemical and Solid-State Letters, 2(7), 320-322 (1999)
  25. Wang Y., Shang H. and Chou, Cao T., J. Phys. Chem. B 109, 11361(2005)
  26. Cao G. Z., J. Phys. Chem. B 108, 19921 (2004)
  27. Lee K., Wang Y. and Cao G. Z., J. Phys. Chem., 109, 16700 (2005)
  28. Takahashi K., Limmer S. J., Wang Y. and Cao G. Z., J. Phys. Chem. B 108, 9795 (2004)