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An Overview on Research Trends in Remediation of Chromium

Author Affiliations

  • 1 Department of Chemistry, S.V. University, Tirupati-517 502, AP, INDIA
  • 2 Department of Soil Science, Regional Agricultural Research Station, Acharya N G Ranga Agricultural University, Tirupati, AP, INDIA

Res. J. Recent Sci., Volume 2, Issue (1), Pages 71-83, January,2 (2013)


Chromium is one of the toxic heavy metals which needs ample attention in terms of soil and environmental degradation. Among the heavy metals and their toxicity, chromium toxicity was well studied by the researchers with the corresponding remedial measures. In the present review paper, the occurrence, transformation, in different environments and the possible and currently practicing remedial measures and the evaluation of their efficacy to minimize the toxic effects of chromium was thoroughly discussed.


  1. Khezami L. and Capart R., Removal of chromium (VI) from aqueous solution by activated carbons: kinetic and equilibrium studies, J. Hazard. Mater.,123, 223-231 (2005)
  2. Eccles H., Treatment of metal-contaminated wastes: why select a biological process? Trends Biotechnol.,17, 462–465 (1999)
  3. Leung W.C., Wong M.F., Chua H., Lo W. and Leung C.K., Removal and recovery of heavy metals by bacteria isolated from activated sludge treating industrial efuents and municipal wastewater, Water Sci. Technol., 41(12), 233–240 (2000)
  4. Pedersen A.J., Characterization and electrolytic treatment of wood combustion y ash for the removal of cadmiumBiomass Bioenergy,25(4), 447–458 (2003)
  5. Skubal L.R., Meshkov N.K., Rajh T., Thurnauer, J. Photochem. Photobiol. A, Chem., 148, 393 (2002)
  6. Kotas J. and Stasicka Z., Chromium occurrence in the environment and methods of its speciation, Environ. Poll., 107, 263–283 (2000)
  7. Bruzzone G., Ghelli G. and Perrone D., US patent, , 112,583 (1992)
  8. Kato I. and Nagai S., Treatment of chromium containing wastewater, Japan Kokai Tokkyo Koho, JP03, 224–691 (1991)
  9. Mirbagherp S.A. and Hosseini S.N., Pilot plant investigation on petrochemical wastewater treatment for the removal of copper and chromium with the objective of reuse, Desalination, 171, 85–93 (2004)
  10. Chen Q.Y., Luo Z., Hills C., Xue G. and Tyrer M., Precipitation of heavy metals from wastewater using simulated flue gas: sequent additions of fly ash, lime and carbon dioxide, Water Res., 43, 2605-2614 (2009)
  11. Kongsricharoern N. and Polprasert C., Chromium removal by a bipolar electrochemical precipitation process,Water Science and Technology, 34(9), 109–116 (1996)
  12. Kang S.Y., Lee J.U., Moon S.H. and Kim K.W., Competitive adsorption characteristics of Co2þ, Ni2þ and Cr3þ by IRN-77 cation exchange resin in synthesized wastewater, Chemosphere,56, 141-147 (2004)
  13. Sally Bahowick, Gene Kumamoto, Douglas Dobie; Lawrence Livermore Nat’l Laboratory Ion exchange resin for removing hexavalent chromium from ground water at treatment facility C: Data on removal capacity, Regeneration efficiency and operation (1993)
  14. Sahu S.K., Meshram P., Pandey B.D., Kumar V. and Mankhand T.R., Removal of chromium(III) by cation exchange resin, Indion 790 for tannery waste treatment Hydrometallurgy, 99(3-4),170-174 (2009)
  15. Chanda M. and Rempel G.L., Chromium(III) removal by epoxy-crosslinked poly (ethyleneimine) used as get-coated on silica, 1. Sorption characteristics, Industrial Engineering Chemical Research, 36, 2184–2189 (1997)
  16. Pandey B.D., Cote G. and Bauer D., Extraction of chromium (III) from spent tanning baths, Hydrometallurgy, 40, 343–357 (1996)
  17. Sapari N., Idris A. and Hisham N., Total removal of heavy metal from mixed plating rinse wastewater, Desalination,106(1–3), 419–422 (1996)
  18. Kabay N., Arda M., Saha B. and Streat M., Removal of Cr(VI) by solvent impregnated resins (SIR) containing aliquat 336, Reactive and Functional Polymers, 54(1–3), 103–115 (2003)
  19. Lin S.H. and Kiang C.D., Chromic acid recovery from waste acid solution by an ion exchange process: equilibrium and column ion exchange modeling, Chemical Engineering Journal, 92(1–3), 193–199 (2003)
  20. Sengupta A.K. and Kim L., Am. Inst. Chem. Eng. J., 34, 2019–2029 (1988)
  21. Vigneswaran S., Ngo H.H., Chaudhary D.S. and Hung Y.T., Physico– chemical treatment processes for water reuse, in: Wang, (2004)
  22. Pugazhenthi G., Sachan S., Kishore N. and Kumar A.,Separation of chromium (VI) using modified ultrafiltration charged carbon membrane and its mathematical modeling, Journal of Membrane Science, 254(1–2), 229–239 (2005)
  23. Saffaj N., Loukil H., Younssi S.A., Albizane A., Bouhria M., Persin M. and Larbot A., Filtration of solution containing heavy metals and dyes by means of ultrafiltration membranes deposited on support made of Morrocan clay, Desalination, 168, 301–306 (2004)
  24. Barakat M.A., Removal of Cu(II), Ni(II), and Cr(III) ions from wastewater using complexation–ultrafiltration technique, J. Environ. Sci. Technol.,1(3), 151-156 (2008)
  25. Bohdziewicz J., Removal of chromium ions (VI) from underground water in the hybrid complexation-ultrafiltration process, Desalination, 129(3), 227–235 (2000)
  26. Muthukrishnan M., Guha B.K., Effect of pH on rejection of hexavalent chromium by nanofiltration, Desalination,219, 171-178 (2008)
  27. Aroua M.K., Zuki F.M. and Sulaiman N.M., Removal chromium ions from aqueous solutions by polymer-enhanced ultra filtration, J. Hazard. Mater.,147, 752 -758 (2007)
  28. Chiha M., Samar M.H. and Hamdaoui O., Extraction of chromium (VI) from sulphuric acid aqueous solutions by a liquid surfactant membrane (LSM), Desalination, 194(1–3), 69–80 (2006)
  29. Rana P., Mohan N. and Rajagopal C., Electrochemical removal of chromium from wastewater by using carbon aerogel electrodes, Water Research, 38(12), 2811–2820 (2004)
  30. Martinez S.A., Rodriguez M.G., Aguolar R. and Soto G., Removal of chromium hexavalent from rinsing chromating waters electrochemicals reduction in a laboratory pilot plant, Water Science and Technology, 49(1), 115–122 (2004)
  31. Chen G.H., Electrochemicals technologies in wastewater treatment, Sep. Purif. Technol., 38(1), 11–41 (2004)
  32. Heidmann I. and Calmano W., Removal of Zn(II), Cu(II), Ni(II), Ag(I) and Cr(VI) present in aqueous solutions by aluminium electrocoagulation, J. Hazard. Mater., 152, 934-941 (2008)
  33. Ölmez T., The optimization of Cr(VI) reduction and removal by electrocoagulation using response surface methodology, J.Hazard.Mater., 162, 1371-1378 (2009)
  34. Sanjay K., Arora A., Shekhar R. and Das R.P., Electroremediation of Cr (VI) contaminated soils: Kinetics and energy efficiency, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 222, 253-259 (2003)
  35. Kongsricharoern N. and Polprasert C., Electrochemical precipitation of chromium (Cr6þ) from an electroplating wastewater, Wat. Sci. Technol., 31, 109-117 (1995)
  36. Ana M., Nieto Castillo Æ Juan Jose´ Soriano Æ Rafael A. Garcý´a-Delgado., Changes in chromium distribution during the electrodialytic remediation of a Cr (VI)contaminated soil Environ Geochem Health, 30, 153–157 (2008)
  37. Herrmann J.M., Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants, Catal. Today,53, 115–129 (1999)
  38. Chenthamarakshan C.R., Rajeshwar K. and Wolfrum E.J., Heterogeneous photocatalytic reduction of Cr(VI) in UV-irradiated titania suspensions: effect of protons, ammonium ions, and other interfacial aspects, Langmuir,16, 2715–2721 (2000)
  39. Mohapatra P., Samantaray S.K. and Parida K., Photocatalytic reduction of hexavalent chromium in aqueous solution over sulphate modified titania, J. Photochem. Photobiol. A: Chem., 170, 189–194 (2005)
  40. Dasa D.P., Parida K. and Ranjan B.D., Photocatalytic reduction of hexavalent chromium in aqueous solution over titania pillared zirconium phosphate and titanium phosphate under solar radiation, J. Mol. Catal. A: Chem., 245, 217–224 (2006)
  41. Gkika E., Troupis A., Hiskia A. and Papaconstantinou E., Photocatalytic reduction of chromium and oxidation of organics by polyoxometalates, Appl. Catal. B: Environ.,62, 28–34 (2006)
  42. Yoona J., Shimb E., Baec S. and Jooa H., Application of immobilized nanotubular TiO2 electrode for photocatalytic hydrogen evolution: reduction of hexavalent chromium (Cr(VI)) in water, J. Hazard. Mater., 161 (2–3), 1069–1074 (2009)
  43. Wang L., Wang N., Zhu L., Yu H. and Tang H., Photocatalytic reduction of Cr(VI) over different TiO2 photocatalysts and the effects of dissolved organic species,J. Hazard. Mater.,152, 93–99 (2008)
  44. Basaldella El.I., Va´ zquez P.G., Iucolano F. and Caputo D., Chromium removal from water using LTA zeolites: effect of pH, J. Colloid Interface Sci.,313, 574–578, Biotechnology62, 569–573 (2007)
  45. Kent D.B., Davis J.A., Anderson L.C.D. and Rea B.A., Transport of chromium and selenium in a pristine sand and gravel aquifer: Role of adsorption processes, Water Resour. Res., 31, 1041–1050 (1995)
  46. Sharma D.C. and Forster C.F., Removal of hexavalent chromium from aqueous solutions by granular activated carbon, Water S.A., 22(2), 153–160 (1996)
  47. Selomulya C., Meeyoo V. and Amal R., Mechanisms of Cr(VI) removal from water by various types of activated carbons, Journal of Chemical Technology and Biotechnology 74(2), 111–122 (1999)
  48. Karthikeyan T., Rajgopal S. and Miranda L.R., Chromium(VI) adsorption from aqueous solution by Hevea brasiliensis sawdust activated carbon, Journal of Hazardous Materials, 124(1–3), 192–199 (2005)
  49. Bishnoi N.R., Bajaj M., Sharma N. and Gupta A., Adsorption of Cr(VI) on activated rice husk carbon and activated alumina, Bioresour. Technol.,91(3), 305–307 (2003)
  50. Tang P., Lee C.K., Low K.S. and Zainal Z., Sorption of Cr(VI) and Cu(II) in aqueous solution by ethylenediamine modified rice hull, Environ. Technol.,24, 1243–1251 (2003)
  51. Udaybhaskar P., Iyengar L. and Rao A.V.S.P., Cr(VI) interaction with chitosan, Journal of Applied Polymer Science,39(3), 739–747 (1990)
  52. Lee M.Y., Hong K.J., Shin-Ya Y. and Kajiuchi T., Adsorption of Cr(VI) by chitosan-based polymeric surfactants, Journal of Applied Polymer Science, 96(1), 44–50 (2005)
  53. Banerjee S.S., Joshi M.V. and Jayaram R.V., Removal of Cr(VI) and Hg(II) from aqueous solutions using fly ash and impregnated fly ash, Sep. Sci. Technol.,39, 1611–1629 (2004)
  54. Aoyama M., Kishino M. and Jo T.S., Biosorption of Cr(VI) on Japanese ceder bark, Sep. Sci. Technol.,39(5), 1149–1162 (2004)
  55. Raji C. and Anirudhan T.S., Batch Cr(VI) removal by polyacrylamide grafted sawdust: kinetics and thermodynamics, Water Res., 32(12), 3772–3780 (1998)
  56. Spinelli V.A., Laranjeira M.C.M. and Fa’vere V.T., Preparation and characterization of quaternary chitosan salt: adsorption equilibrium of chromium(VI) ion, Reactive and Functional Polymers, 61(3), 347–352 (2004)
  57. Sankararamakrishnan N., Dixit A., Iyengar L. and Sanghi R., Removal of Cr(VI) using a novel cross linked xanthated chitosan, Bioresource Technology, 97(18), 2377–2382 (2006)
  58. Xu Y.H., Bai J.M., John Thomas and Wang J.P., (B9). (FeCo)3Si–SiOx core–shell nanoparticles fabricated in the gas phase, Nanotechnology, 18, 065701 (2007)
  59. Singh Ritu, Misra Virendra and Singh R.P., Remediation of Cr(VI) contaminated soil by Zero-Valent Iron Nanoparticles (nZVI) entrapped in Calcium Alginate Beads2011 2nd International Conference on Environmental Science and Development IPCBEE, , (2011)
  60. Jo S., Lee J.Y., Kong S.H., Choi J. and Park J.W., Iron monosulphide as a scavenger for dissolved hexavalent chromium and cadmium, Environmental Technology, 29, 975-983 (2008)
  61. Vemula Madhavi, Ambavaram Vijaya Bhaskar Reddy, Kalluru Gangadhara Reddy and Gajulapalli Madhavi,A simple method for the determination of efficiency of stabilized Fe0 nanoparticles for detoxification of chromium (VI) in water, Journal of Chemical and Pharmaceutical Research, 4(3), 1539-1545 (2012)
  62. Shujing Li, Tielong Li, Zongming Xiu and Zhaohui Jin, Reduction and immobilization of chromium(VI) by nano scale Fe0 particles supported on reproducible PAA/PVDF membrane, Journal of Environmental Monitoring,12, 1153–1158 (2010)
  63. Kanmani P., Aravind J. and Preston D., Remediation of chromium contaminants using bacteria, International journal of Science and technology, 9(1), 183-193 (2010)
  64. Liyuan Chai, Shunhong Huang, Zhihui Yang, Bing Peng, Yan Huang, Yuehui Chen, Cr (VI) remediation by indigenous bacteria in soils contaminated by chromium-containing slag, Journal of Hazardous materials, 167(1-3), 516-522 (2009)
  65. Ackerley D.F., Gonzalez C.F., Keyhan M., Blake II, R., Matin A., Mechanism of chromate reduction by the E. coli protein, NfsA, and the role of different chromate reductases in minimizing oxidative stress during chromate reduction, Environmental Microbiology, 6, 851–860 (2004)
  66. Appenroth K.J., Bischoff M.B., Gabrys H., Stoeckel J., Swartz H.M., Walczak T. and Winnefeld K., Kinetics of chromium (V) formation and reduction in fronds of the duckweed Spirodela polyrhiza—a low frequency EPR study, Journal of Inorganic Biochemistry,78, 235–242 (2000)
  67. Abubakr Alhasin, Stephen J. Gurman, Loretta M. Murphy, Ashleeperry, Thomas J. Smith, Philip E. Gardiner, Remediation of Chromium(VI) by a Methane-Oxidizing Bacterium, Environ. Sci. Technol., 44,400–405 (2010)
  68. Fredrickson J.K., Kostandarithes H.M., Li S.W., Plymale A.E. and Daly M.J., Reduction of Fe(III), Cr(VI), U(VI), and Tc(VII) by Deinococcus radiodurans R1, Applied and Environmental Microbiology,66, 2006–2011 (2000)
  69. Kashefy K. and Lovley D.R., Reduction of Fe(III), Mn(IV), and toxic metals at 100 1C by Pyrobaculum islandicum, Applied and Environmental Microbiology,66, 1050–1056 (2000)
  70. Nandakumar P.B.A., Dushenkov V., Motto H. and Raskin I., Phytoextraction: The use of plants to remove heavy metals from soils, Environ. Sci. Technol., 29, 1232-1238 (1995)
  71. Dushenkov V., Nanda Kumar PBA, Motto H. and Raskin I., Rhizofiltration-the use of plants to remove heavy metals from aqueous streams, Environ. Sci. Technol., 29, 1239-1245 (1995)
  72. Romero-Gonz´alez J., Peralta-Videa J.R., Rodr´guez E., Delgado M., Gardea-Torresdey J.L., Potential of Agave lechuguilla biomass for Cr(III) removal from aqueous solutions: thermodynamic studies, Bioresour. Technol., 97(1), 178–182 (2006)
  73. Park C.H., Keyhan M., Matin A., Purification and characterization of chromate reductase in PseudomonasputidaAbs. Gen. Meet, American Soc. Microbial., 99(4),536-548 (1999)
  74. Karkhanis M., Jadia C.D., Fulekar M.H., Rhizofilteration of metals from coal ash leachate, Asian J. Water, Environ. Pollut3(1), 91-94 (2005)