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Synthesize, Characterization and Thermal behavior of some New Mercury and Cadmium halides Coordination compounds of Recently synthesized Schiff base

Author Affiliations

  • 1Department of chemistry, Yasouj University, Yasouj 7591874831 IRAN
  • 2 Department of Basic Science, Yasouj Branch, Islamic Azad University, Yasouj, IRAN

Res. J. Recent Sci., Volume 1, Issue (11), Pages 9-15, November,2 (2012)

Abstract

Some new cadmium (II) and mercury (II) halides complexes of the bidentate Schiff base ligand N,N-bis [(E)-3-(2-nitrophenyl)allylidene)]benzene-1,2-diamine (L) were synthesized, and characterized by physical and spectral study such as elemental analysis, molar conductance, UV–visible spectra, FT-IR spectra, 1H NMR and 13C NMR spectra. All complexes were stable in DMF solvent and the low molar conductivity confirms their stabilization and the non-electrolytic nature of them. The changes in the location and shape of the peaks in UV-visible, FT-IR, and the 1H and 13C NMR spectra of complexes rather than free ligand are the other evidence to form Schiff base complexes. The suggested structure of the complexes is pseudo-tetrahedral. Thermal behaviors of complexes were also investigated.

References

  1. Lau K.Y., Mayr A. and Cheung K.K., Synhesis of transition metal isocyanide, bonding sites in peripheral locations, Inorg. Chim. Acta, 285, 223-232 (1999)
  2. Kwiathowski, M., and Bandoli, G., Nickel(II) complexes with unsymmetrical quadridentate Schiff bases having a pendant N-acyl substituent, J. Chem. Soc. Dalton Trans., 379-384 (1992)
  3. Costes J. P. and Fernandez-Garcia M.I., Easy synthesis of ‘half-units’: their use as ligands or as precursors of non-symmetrical Schiff base complexes, Inorg. Chim. Acta, 237, 57-63 (1995)
  4. Sun X.H., Li S.J., Liu Y.F., Chen B., Jia Y.Q. and Tao Y., Study on the Synthesis and Biological Activity of Schiff Bases of 3-Amino-dihydrothiophene-2-one, Chin. . Org. Chem., 27, 82 (2007)
  5. Adsule, S. Barve, V. Chen, D. Ahmed, F. Dou, Q.P. Padhye, S. and Sarkar, F. H., Novel schiff base copper complexes of quinoline-. 2 carboxaldehyde as proteasome inhibitors in human prostate cancer cells, . Med. Chem., 49, 7242-7246 (2006)
  6. Samir El-Medani M., Omyan A.M.A. and Ramaden R.N., Photochemical reactions of group 6 metal carbonyls with N-salicylidene-2-hydroxyaniline and bis-(salicylaldehyde) phenylenediimine, J. Mol. Struct.,738, 171-177 (2005)
  7. Ren S., Wang R., Komastu K., Krause P.B., Zyrianov Y., Mckenna C.E., Csipke C., Tokes Z.A. and Lien E.J., Synthesis, Biological evaluation, and quantitative structure activity relationship analysis of New Schiff Bases of Hydroxysemicarbazide as potential antitumor agents, J. Med. Chem., 45, 410-419(2002)
  8. Girgaonkar M.V. and Shirodkar S.G., Synthesis, characterization and Biological studies of Cu(II) and Ni(II) complexes with New Bidentate Shiff’s base ligands as 4-hydroxy-3-(1-(arylimino)ethyl)chromen-2-one, Res. J. Recent Sci.,1 (ISC-2011) , 110-116 (2012)
  9. Nair Smita, A Study of Transition Metal Complex of Diuretic Drug and study of its Physico-chemical properties as Potential Therapeutic Agent, Res. J. Recent Sci., 1(ISC-2011), 341-344 (2012)
  10. Colman J. and Hegedu L.S., Principles and Applications of Organotransition Metal Chemistry, University Science Book, California(1980)
  11. Zhao J., Zhao B., Liu J., Xu W.J. and Wang Z., Spectroscopy study on the photochromism of Schiff Bases N,N'-bis(salicylidene)-1,2-diaminoethane and N,N'-bis(salicylidene)-1,6-hexanediamine, Spectrochim. Acta: A,57, 149-154(2001)
  12. Liu W.-L., Zou Y., Li Y., Yao Y.G., Meng Q.J., Synthesis and characterization of copper(II) Schiff base complexes derived from salicylaldehyde and glycylglycylglycine, Polyhedron, 23, 849-855(2004)
  13. Ghaedi M., Shabani R., Shokrollahi A., Montazerozohori M., Sahraiean A. and Soylak M. Preconcentration and separation of trace amount of copper (II) on N, N-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads SP70, J. Haz. Matt., 170, 169-174 (2009)
  14. Ghaedi M., Shokrollahi A., Montazerozohori M. and Derki Z., Design and Construction of Azide Carbon Paste Selective Electrode based on a New Schiff's Base complex of Iron, IEEE Sens. J.,, 814–819(2010)
  15. Ghaedi M., Montazerozohori M., Mousavi A., Khodadoust S. and Mansouri M., Construction of new iodide selective electrodes based on bis(trans-cinnamaldehyde)1,3-propanediimine(L) zinc(II) chloride [ZnLCl2] and bis(trans-cinnamaldehyde) 1,3-propanediimine(L) cadmium(II) chloride [CdLCl2], Mat. Sci. Engin. C,32, 523–529(2012)
  16. Sharghi H. and M. Nasseri A., Bull. Chem. Soc. (Jpn.),76, 137 (2003)
  17. Alexander S., Udayakumar V., Gayathri V., Hydrogenation of olefins by polymer-bound palladium(II) Schiff base catalyst, J. Mol. Cat. A: Chem.,314, 21-27(2009)
  18. Gehad G.M., Omar M.M. and Ahmed M.M. Hindy, Synthesis, characterization and biological activity of some transition metals with Schiff base derived from 2-thiophene carboxaldehyde and aminobenzoic acid, Spectrochim. Acta A,62, 1140–1150 (2005)
  19. Montazerozohori M., Joohari S. and Musavi S.A., Synthesis and spectroscopic studies of some cadmium(II) and mercury(II) complexes of an asymmetrical bidentate Schiff base ligand, Spectrochim. Acta A,73, 231-237(2009)
  20. Montazerozohori M., Nouroozi V., Hashemi S., Kazemi Z., Joohari S. and Musavi S.A., Synthesis and Characterization of Some Four Coordinated Zinc(II) and Mercury(II) Complexes, Asian J. Chem.;23, , 5399 -5402 (2011)
  21. Montazerozohori M. and Musavi S. A., Synthesis and spectral characterization of a new symmetric bidentate Schiff-base and its zinc complexes, J. Coord. Chem., 61(24), 3934-3942(2008)
  22. Saleh A.A., Synthesis and spectroscopic studies of novel mononuclear complexes of cyclic and acyclic Schiff-base derivatives of tridentate and tetradentate coordination with some bivalent transition metal ions, J. Coord. Chem., 58, 255 (2005)
  23. Yilmaz I. and Cukurovali A., Synthesis, Characterization and Antimicrobial Activity of the Schiff Bases Derived From 2,4-Disubstituted Thiazole and 3-Methoxy Salicylaldehyde and Their Cobalt(II), Copper(II), Nickel(II) and Zinc(II) Complexes, Trans. Met. Chem.,28, 399-404 (2003)
  24. El-Ajaily M.M., El-Ferjani R.M. and Maihub A.A., Preparation and Physical Investigation of Complexes Derived from 4-Dimethylaminobenzaldehyde and 4-Aminoantipyrine Schiff Base with Ni(II), Cu(II), Rh(III), and Pt(IV) Ions, J. J. Chem., 2, 287-296 (2007)
  25. Singh R.V., Joshi S.C. and Dwivedi R., Synthetic, sterochemical, and biological aspects of manganese complexes with unsymmetrical sulfur containing bidentate Schiff bases, Phosph. Sulf. Silic., 179, 227-236(2004)
  26. Prakash P. Dholakiya and Patel M.N., Preparation, Characterization, and Antimicrobial Activities of Some MixedLigand Complexes of Mn(II), Co(II), Ni(II), Cu(II), and Cd(II) with Monobasic Bidentate (ON) Schiff Base and Neutral Bidentate (NN) Ligands, Syn. React. Inorg. Met.-Org. Chem.,34, 383-395 (2004)
  27. Dehghanpour S., Mahmoudkhani A.H. and Amirnasr A.M., Synthesis and characterization of [Cu(Phca2en)(PPh3)X] (X= Cl, Br, I, NCS, N) complexes. crystal structures of [Cu(Phca2en)(PPh3)Br] and [Cu(Phca2en)(PPh3)I], Struct. Chem., 17, 255-262 (2006)
  28. Habibi M.H., Montazerozohori M., Lalegani A., Harington R.W. and Clegg W., N,N-Bis(2-nitrocinnamaldehyde) ethylenediaminedicholorozinc(II), Anal. Sci.: X-ray Struct. Anal. Online, 23, X51-53 (2007)
  29. Habibi M.H., Montazerozohori M., Lalegani A., Mokhtari R., Harington R.W. and Clegg W., N,N -Bis[3-(2-nitrophenyl)prop-2-enylidene]ethylenediamine- N',N-chlorido(triphenylphosphine-K2 P)copper(I), Acta Cryst. E63, m2933-m2934 (2007)
  30. Habibi M.H., Montazerozohori M., Lalegani A., Harington R.W. and Clegg W., Synthesis and Crystal Structure of [CuL(PPh3)Cl] L = N,N-Bis(4-trifluromethylbenzylidene) ethylenediamine, Anal. Sci.: X-ray Struct. Anal. Online, 23, X49-51 (2007)