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Study the Effect of PVSA on the CMC of Brij-56 using Dye Solubilization Method

Author Affiliations

  • 1Department of Chemistry, JET’s ZulalBhilajirao Patil College, Deopur, Dhule - 424002 (MS) India

Res.J.chem.sci., Volume 6, Issue (7), Pages 25-28, July,18 (2016)

Abstract

The micellization and solubilization phenomenon of non-ionic surfactants has been studied by various methods such as cloud point determination, surface tension measurement, dye solubilization etc. in presence and in absence of additives. The solubilization phenomenonfor non-ionic surfactant Brij-56 with the water insoluble orange OT dye has been discussed. The effect of additive polyelectrolyte PVSA on the critical micelle concentration (CMC) of non-ionic surfactant Brij-56 has been studied in aqueous medium by measuring the absorbance of the pure Brij-56 aqueous system as well as Brij-56 and PVSA mixed aqueous system with Orange-OT dye using dye solubilization method. The absorbance increases with increasing concentration of pure Brij-56 in aqueous medium with Orange-OTdye. The absorbance of Brij-56 and PVSAmixed aqueous systems with Orange-OTdye also show same trend. The results of the investigation verify that, the CMC of pure Brij-56 decreases with increasing concentration of additive PVSA in aqueous medium. Therefore the effect of additive PVSA on the CMC of Biij-56 support to made probable evidence that the dye solubilization is complex phenomenon of micelles aggregation of surfactant monomers so as to perform various surface activities.

References

  1. Shoji N., Ueno M. and Meguro K. (1976)., Determination of critical micelle concentrations of some surfactants by keto-enoltautomerism of benzoylacetone., Journal of The American OIL Chemist
  2. Dominguez A., Fernandez A., Gonzalez N., Iglesias E. and Montenegro L. (1997)., Determination of Critical Micelle Concentration of Some Surfactants by Three Techniques., Journal of Chemical Education, 74 (10), 1227-1231.
  3. Shinoda K. and Nakagawa T. (1963)., Colloidal Surfactants: Some Physicochemical Properties., Academic Press, New York, 9-15. Library of Congress Catalog Card no.62-13114.
  4. Goto R., Koizumi N., Hayama N. and Sugano T. (1953)., Micelle Formation of Non-ionic Surfactants. (I) Properties of Aqueous Solution of Polyoxyethylene mono-alkyl Ether., Bulletin of the Institute for Chemical Research, Kyoto University , 31(4), 285-294.
  5. McBain J.W., Merrill Jr. R.C. and Vinograd J.R. (1940)., Solubilizing and detergent action in non-ionizing solvents., J.Am. Chem. Soc., 62, 2880 -2881.
  6. Becher P. (1967)., Non-ionic Surfactants., M J Schick, Ed., Marcel Dekker, New York, N.Y.,478-482, , ISBN-0-8247-7530-9.
  7. Ross S. and Olivier J.P. (1959)., A New Method for the Determination of Critical Micelle Concentrations of Un-ionized Associations Colloids in Aqueous or in Non-aqueous Solution., J. Phys. Chem., 63(10), 1671–1674.
  8. Patil A.A. and Patil T.J. (2011)., Measurement of Critical Micelle Concentration of Technical Grade Non-ionic Detergent in Presence of Chloramine-T using Dye Solubilization Technique., Orient. J. of Chem., 27(2), 753-756.
  9. Han Lu. Qianru, Chen. Wang, Yu. Chuanbo, Gao. and Shunai. Che. (2011)., Synthesis of amino group functionalized monodispersedmesoporous silica nanospheres using anionic surfactant., Microporous and Mesoporous Materials, 139(1-3), 94-103.
  10. Feng F., Coutinho D., Yang Z., Ferraris J.P. and Balkus Jr. Kenneth (2005)., Synthesis of proton conducting tungstosilicatemesoporous materials and polymer composite membranes., Microporous and Mesoporous Materials, 81 (1-3), 217-234.
  11. Hayward R.C., Peter Alberius C.A., Kramer E.J. and Chmelka B.F. (2004)., Thin Films of Bicontinuous Cubic Mesostructured Silica Templated by a Nonionic Surfactant., Langmuir, 20(14), 5998-6004.
  12. Pourjavadi A. and Ghasemzadeh H. (2007)., Carrageenan-g-Poly (Acrylamide) / Poly (Vinylsulfonic Acid, Sodium Salt) as a Novel Semi-IPN Hydrogel: Synthesis, Characterization and Swelling Behavior., Polym. Engg. and Sci., 47(9), 1388-1395.
  13. Li J., Li H.Z., Yang H.Y., Zhu P.P. and He P.S. (2008)., Effects of NH4Cl on the interaction between poly(ethylene oxide) and ionic surfactants in aqueous solution., Chinese Journal of Polymer Science, 26(1), 31-37.
  14. Goddard, E. D. and Ananthapadmanabhan, Kavssery P. (1993)., Interactions of surfactants with polymers and proteins., CRC, Boca Raton, FL. pp123, ISBN-9780849367847.
  15. Saito S. (1989)., Non-ionic surfactants- Physical chemistry., Edited by M.J. Schick, Marcel Decker Inc. New York, 881-890, ISBN-0-8247-7530-9.
  16. Egan R.W. (1976)., Hydrophile-Lipophile Balance and Critical Micelle Concentration as Key Factors Influencing Surfactant Disruption of Mitochondrial Membranes., J. Biol. Chem., 251(14), 4442-4447.
  17. Patel J., Varade D. and Bahadur P. (2004)., Effect of tetraalkylammonium bromides on micellar behaviour of ionic and non-ionic surfactants., Ind. J. of Chemistry, 43(A), 715-721.