International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Production of Activated Carbon from Sugarcane Bagasse by Chemical Activation with ZnCl2: Preparation and Characterization Study

Author Affiliations

  • 1NTT Institute of High Technology, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
  • 22Dong Nai University of Technology, Bien Hoa City, Dong Nai Province, Vietnam
  • 3NTT Institute of High Technology, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
  • 43Organic Material Department, Institute of Applied Material Science, Ho Chi Minh City, Vietnam
  • 5NTT Institute of High Technology, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
  • 64Department of Chemical Engineering, Ho Chi Minh City University of Technology, Vietnam
  • 7NTT Institute of High Technology, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam

Res.J.chem.sci., Volume 6, Issue (5), Pages 42-47, May,18 (2016)

Abstract

A protocol producing the activated carbon (AC) with high surface area and porosity with large adsorption capacity from non-toxic and low cost precursor source was developed. The ACwas prepared from sugarcane bagasse with ZnCl2as activating agent. Three preparing temperatures including 400oC, 500oC, and 600oC were investigated to compare the structural difference of the ACs. The properties of the ACsfabricated at these temperatures were determined using relevant techniques such as scanning electron microscopy (SEM), X–ray diffraction (XRD), thermo–gravimetric analysis (TGA),Fourier transform infrared (FT–IR) spectroscopy and nitrogen adsorption/desorptionmeasurement.Characterization results showed that the maximum BET surface area of the AC is1502.1 m2/g at 500oC. XRD patternsand SEM micrographs revealed that the ACshave the amorphous structure and heterogeneous surface. IR spectra also proved the presence of functional groups O–H, O–N asymmetric and C–C aromatic in the carbon. Moreover, the maximum AC yield of 45.7% was achieved at 500oC.

References

  1. Fine P. and Hadas E. (2012)., Options to reduce greenhouse gas emissions during wastewater treatment for agricultural use., Science of the Total Environment, 416, 289-299
  2. Ali I. and Gupta V. (2006)., Advances in water treatment by adsorption technology., Nature protocols, 1, 2261-2267.
  3. Kurniawan T., Chan G., Wai-hung L. and Babel S. (2006)., Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals., Science of the Total Environment, 366, 409-426
  4. Wang S. and Peng Y. (2010)., Natural zeolites as effective adsorbents in water and wastewater treatment., Chemical Enginnering Journal, 156, 11-24.
  5. Furukawa H., Cordova K., O’Keeffe M. and Yaghi O. (2013)., The Chemistry and Applications of Metal-Organic Frameworks., Science, 341, 1230444
  6. Szernik S. and Bridgwater A. (2004)., Overview of Applications of Biomass Fast Pyrolysis Oil., Energy Fuels, 18, 590-598.
  7. Ioannidou O. and Zabaniotou A. (2007)., Agricultural residues as precursors for activated carbon production - A review., Renewable and Sustainable Energy Reviews, 11, 1966-2005
  8. Xu J., Chen L., Qua H., Jiao Y., Xie J. and Xing G. (2014)., Preparation and characterization of activated carbon from reedy grass leaves by chemical activation with H3PO4., Applied Surface Science, 320, 674-680.
  9. Mohamad N., Lau L.C., Lee K., Mohamed A. (2013)., Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control - A review., Journal of Environmental Chemical Engineering, 1, 658-666
  10. Hayashi J., Kazehaya A., Muroyama K. and Watkinson A. (2000)., Preparation of activated carbon from lignin by chemical activation., Carbon, 38, 1873-1878
  11. Yahyaa M., Al-Qodah Z. and Ngah C. (2015)., Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review., Renewable and Sustainable Energy Reviews, 46, 218-235
  12. Hadi P., Xu M., Ning C., Lin C. and McKay G. (2015)., A critical review on preparation, characterization and utilization of sludge-derived activated carbons for wastewater treatment., Chemical Engineering Journal, 260, 895-906
  13. Allwar A., Noor M. and Nawi M. (2008)., Textural characteristics of activated carbons prepared from oil palm shells activated with ZnCl2 and pyrolysis under nitrogen and carbon dioxide., Journal of Physical Science, 19, 93-104
  14. Alothman Z. and Habila R. (2011)., Preparation of activated carbon using the copyrolysis of agricultural and municipal solid wastes at a low carbonization temperature., Proceedings of the international conference on biological and environmental chemistry, 24, 67-72
  15. Pietrzak R., Nowicki P., Kazmierczak J., Kuszynska I., Goscianska J. and Przepiórski J. (2014)., Comparison of the effects of different chemical activation methods on properties of carbonaceous adsorbents obtained from cherry stones., Chemical Engineering Reseaarch Design, 92, 1187-1191
  16. Caturla F., Molina-Sabio M. and Rodríguez-Reinoso F. (1991)., Preparation of activated carbon by chemical activation with ZnCl2., Carbon, 29, 999-1007.
  17. Lastoskie C. and Gubbins K. (1993)., Pore size heterogeneity and the carbon slit pore a density functional theory model., Langmuir, 9, 2693-2702
  18. Gusatti M., Barrosoa G., Camposb C., Souzaa D., Rosárioa J., Limaa R., Milioli C., Silvaa L., Riellaa H. and Kuhnen N. (2011)., Effect of Different Precursors in the Chemical Synthesis of ZnO Nanocrystals., Materials Research, 14, 264-267.
  19. Danish M., Hashim R., Mohamad Ibrahim M., Rafatullah M., Sulaiman O., Ahmad T., Shamsuzzoha M. and Ahmad A. (2011)., Sorption of Copper (II) and Nickel (II) Ions from Aqueous Solutions Using Calcium Oxide Activated Date (Phoenix dactylifera) Stone Carbon: Equilibrium, Kinetic, and Thermodynamic Studies, Journal of Chemical and Engineering Data, 56, 3607-3619
  20. Adinaveen T., Kennedy L., Vijaya J. and Sekara G. (2013)., Studies on structural, morphological, electrical and electrochemical properties of activated carbon prepared from sugarcane bagasse., Journal of Industrial and Engineering Chemistry, 19, 1470-1476.
  21. Liu Y., Zhu X., Qian F., Zhang S. and Chen J. (2014)., Magnetic activated carbon prepared from rice straw–derived hydrochar for triclosan removal., RSC Advance, 4, 63620-63626
  22. Mohammad Y., Shaibu-Imodagbe E., Igboro S., Giwa A. and Okuofu C. (2015)., Effect of Phosphoric Acid Modification on Characteristics of Rice Husk Activated Carbon., Iranica Journal of Energy and Environment, 6, 20-25.