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Synthesis, Characterization and Antimicrobial Studies of Schiff Base Complexes of Arsenic(III), Antimony(III) and Bismuth(III) Chloride

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Author Affiliations

  • 1Department of Chemistry, Govt. Madhav Science P.G. College, Ujjain, INDIA
  • 2School of Studies in Chemistry and Biochemistry, Vikram University, Ujjain, INDIA

Res.J.chem.sci., Volume 5, Issue (8), Pages 39-44, August,18 (2015)

Abstract

In this study, thioacetamide and salicylaldehyde were condensed together to form 2-(thioacetylimino)methyl]phenol (LH), which further reacts with metals As (III), Sb(III) and Bi(III) chloride in ratio of 1:1 and 2:1respectively, to form complexes. All these were characterized by 1HNMR, 13CNMR and IR spectroscopy, elemental analysis and reported literature studies. On the basis of all supporting information, all metal complexes (M/L) in 1:1 (ML1) and1:2 (ML2) showed 4 and 5 coordinated geometry, distorted trigonal bipyramidal and distorted octahedral, respectively. These complexes showed good antibacterial, antifungal and antitubarcular activities.

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