International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Pyrazole Methyl Substituted Compound used as a Corrosive Inhibitor for Mild Steel in Acidic Environment

Author Affiliations

  • 1Department of Chemistry, Karpagam University, Coimbatore, 21, INDIA

Res.J.chem.sci., Volume 5, Issue (5), Pages 1-12, May,18 (2015)

Abstract

The inhibitive effect of compound on mild steel in 1M H2SO4 and 1M HCl was investicated by weight loss, Potentiodynamic polarization and electro chemical impedence studies. The synthesized compound of 1-acetyl-4,5-dihydro-5-phenyl-3-(thiophen-2yl) pyrazoles was characterized by FTIR, 1H NMR, 13C NMR. The structure are also elucidated and purity confirmed by TLC. The corrosion inhibition rate was increased in increasing the concentration of our synthesized inhibitor (1-acetyl-4, 5-dihydro-5-methyl phenyl-3-(thiophen-2yl) pyrazoles). The synergetic effect also studied and observed good correlation between halides and our inhibitor. The adsorption isotherm was also confirmed by langumuir adsorption isotherm.

References

  1. Ajay Kumar K., Jayaroopa P., Int J Pharm Tech.,5(4), 1473-1486 (2013)
  2. Selvakumar P., Balanaga B. Karthik and Thangavelu C., Research Journal of Chemical Sciences,3(4), 87-95 (2013)
  3. Bockris J.O.M. and Reddy A.K.N., Modern Electrochemistry 2B, Electrodics in chemistry, Engineering, biology and Environmental Science, second ed., Kluwer Academic plenum publishers, New York, 1703 (2000)
  4. Ashassi Sorkhabi H., Asghari, Effect of hydrodynamic conditions on the inhibition performance of L-methionine as a green inhibitor, J. Electrochim Acta.,54, 162-167 (2008)
  5. Reeta Agarwal and Namboodhiri T.K.G., The inhibition of sulphuric acid corrosion of 410 stainless steel by thioureas, J.Corros. Sci,30, 37-52 (1990)
  6. Urgen M. and Cakir A.F., The Effect of Molybdate ions on the temperature dependent pitting potential of austenitic Stainless steel in neutral chloride solutions, J. Corros. Sci.,32, 841-852 (1991)
  7. Lu. Y.C. and Ives M.B., The improvement of the localized corrosion resistance of Stainless steel by cerium, J. Corros. Sci.,34, 1773-1785 (1993)
  8. Zhou Mingpeng, Wang Kaiming, DiaoYuemin and Zhou Bensheng, Corrosion inhibition of methylenephosphonic acids with R-N-[CH2PO(OH)2]2 structure in sulpuric acid solution, J. Chinese Society of Corrosion and Protection,14, 283-290 (1994)
  9. Al Mayout A.M, Al Suhybani A.A., Al Ameery A.K., Corrosion inhibition of 304SS in sulphuric acid solutions by 2-methyl benzoazole derivatives, Desalination,116, 25- 33 (1998)
  10. Yang W.Z. and Zhou B.S., Study on corrosion inhibition by N-Sulfonic amino di methylenephosphonic acid, J. Chinese Society of Corrosion and Protection,20, 105-110 (2000)
  11. Gopi D. and Rajeswari S., Surface characterization and electrochemical corrosion behavior of 304stainless steel in aqueous media, J. Solid State Electrochemistry,, 194-202 (2002)
  12. Abdallah M., Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304stainless steel in hydrochloric acid solution, J. Corros. Sci.,44, 717-728 (2002)
  13. Paul A. Kilmartin, Lissa Trier and Graham A Wright, Corrosion inhibition of polyaniline and poly (omethoxyaniline) on stainless steels, Synthetic metals,131, 99-109 (2002)
  14. Denise S., Azambuja Emilse M.A., Martini and Iduvirges L, Muller, Corrosion behavior of Iron and AISI 304 stainless steel in Tungstate Aqueous solutions containing chloride, J. Braz.Chem.Soc.,14, 570-576 (2003)
  15. Abdallah M., Corrosion behavior of 304stainless steel in sulphuric acid solutions and its inhibition by some substituted pyrazolones, Materials Chemistry and Physics,82, 786–792 (2003)
  16. Refaey S.A.M., Taha F and Abd El-Malak A.M., Inhibition of stainless steel pitting corrosion in acidic medium by 2- mercaptobenzoxazole, Applied Surface Sci.,236, 175–185 (2004)
  17. Celeste Rabacal Alentejano, Idalina Vieira Aoki, Localized corrosion inhibition of 304stainless steel in pure water by oxyanions tungstate and molybdate, Electrochemica Acta.,49, 2779-2785 (2004)
  18. Meltem Dudukcu, Birgul Yazici, Mehmet Erbil, The effect of indole on the corrosion behaviour of stainless steel, Materials Chemand Phy., 87, 138–141 (2004)
  19. Behpour M., Ghoreishi. S.M., Mohammadi N. and Salavati- Niasari, MN-[(Z)-1-Phenylemethyleidene]-N{2-[(2-{[(Z)-1phenylmethylidine]amino}phenyl) disulfanyl] phenyl} amine and its derivatives on the corrosion of stainless steel 304 in acid media, J. Corros. Sci.,53, 3380-3387 (2005)
  20. Galal A., Atta N.F., Al-Hassan M.H.S., Effect of some thiophene derivative on the electrochemical behaviour of AISI 316austenitic stainless steel in acidic solutions containing chloride ions, I. Molecular structure and inhibition efficiency relationship, Materials Chem and Phy., 89, 38-48 (2005)
  21. Narvaez L., Cano E. and Bastidas D.M., 3-Hydroxybenzoic acid as AISI 316Lstainless steel corrosion inhibitor in a H2SO4-HF-H2O2 pickling solution, J.Applied Electrochemistry,35, 499-506 (2005)
  22. Galal A., Atta N.F. and Al-Hassan M.H.S., Effect of some thiophene derivatives on the electrochemical behavior of AISI 316austenitic stainless steel in acidic solutions containing chloride ions II, Effect of temperature and surface studies, Materials Chem and Phy.,89, 28–37 (2005)
  23. Sourisseau T., Chauveaub E. and Barouxa B., Mechanism of copper action on pitting phenomena observed on stainless steels in chloride media, J. Corros. Sci.,47, 1097–1117 (2005)
  24. Refaey S.A.M., Taha F.and Abd El-Malak A.M., Corrosion and inhibition of 316Lstainless steel in neutral medium by 2-Mercaptobenzimidazole, Int. J.Electrochem. Sci.,, 80- 91 (2006)
  25. Silva A.B., Agostinho S.M.L., Barcia O.E., Cordeiro G.G.O. and E. D’Elia, The effect of cysteine on the corrosion of 304L stainless steel in sulphuric acid, J. Corros. Sci,48, 3668–3674 (2006)
  26. Gopi D., Manimozhi S., Govindaraju K.M., Manisankar P. and Rajeswari S., Surface and electrochemical characterization of pitting corrosion behaviour of 304stainless steel in ground water media, J. Applied Electrochemistry,37, 439-449 (2007)
  27. Fouda A.S. and El-Dafrawy H., Inhibitive effect of some pyrimidine derivatives on the cyclic stressed specimens of stainless steel type 304 in acidic media, Int. J. Electro chem. Sci.,, 721-733 (2007)
  28. Aziz Yagan Nuran Ozcicek Pekmez, Attila Yildiz, Poly (Nethylaniline) coatings on 304stainless steel for corrosion protection in aqueous HCl and NaCl solutions. Electrochemica Acta., 53, 2474-2482 (2008)
  29. Pardo A., Merino M.C., Coy A.E. and Viejo F., Arrabal R. And Matykina E., Effect of Mo and Mn additions on the corrosion behaviour of AISI 304 and 316stainless steels in HSO, Corros. Sci.,50, 780-794 (2008)
  30. Satpati A.K and Ravindran. P.V, Electrochemical study of the inhibition of corrosion of stainless steel by 1,2,3- benzotriazole in acidic media, Materials Chem and Phy., 109, 352–359 (2008)
  31. Pardo. A, Merino. M.C, Coy. A.E, Viejo. F, Arrabal. R and Matykina. E, Pitting corrosion behaviour of austenitic stainless steels: combining effects of Mn and Mo additions, J. Corros. Sci., 50, 1796–1806 (2008)
  32. Hosseini S.M.A. and Salari M., Corrosion inhibition of stainless steel 302 by 1-methyl-3-pyridine-2-yl-thiourea in acidic media, Indian J. Chemical technology,16, 480-485 (2009)
  33. Dubey R.S. and Yogesh Potdar, Corrosion inhibition of 304stainless steel in sodium chloride by ciprofloxacin and norfloxacin, Indian J. Chemical technology,16, 334-338 (2009)
  34. Matjaz Finsgar, Stefan Fassbender, Fabio Nicolini and Ingrid Milosev, Polyethyleneimine as a corrosion inhibitor for ASTM 420Stainless steel in near neutral saline media, J. Corros Sci.,51, 525-533 (2009)
  35. Behpour M., Ghoreishi S.M., Soltani N. and Salavati- Niasari M., The inhibitive effect of some bis- N,S-bidentate Schiff bases on corrosion behaviour of 304stainless steel in hydrochloric acid solution, J. Corros Sci., 51, 1073–1082 (2009)
  36. Matjaz Finsgar, Stefan Fassbender, Sabine Hirth and Ingrid Milosev, Electrochemical and XPS study of polyethyleneimines of different molecular sizes as corrosion inhibitors for AISI 430stainless steel in nearneutral chloride media, Materials Chem and Phy.,116, 198–206 (2009)
  37. Fouda. A.S and Ellithy. A. S, Inhibition effect of 4- phenylthiazole derivatives on corrosion of 304L stainless steel in HCl solution, J. Corros. Sci., 51, 868–875 (2009)
  38. Hosseini. S.M.A, Azim. A, Sheikhsoaei. I and Salari. M, Corrosion inhibition of 302Stainless steel with schiff base compounds, J. Iran. Chem. Soc., 7, 779-806 (2010)
  39. Samide A., Ciuciu A. and Negrila C., Surface analysis of inhibitor film formed by Poly(Vinyl Alcohol) on stainless steel in sodium chloride solution, Portugaliae Electrochemica Acta.,28, 385-396 (2010)
  40. Fouda A.S., Abdallahb M., Al-Ashreya S.M. and Abdel- Fattahb A.A., Some crown ethers as inhibitors for corrosion of stainless steel type 430 in aqueous solutions, Desalination,250, 538–543 (2010)
  41. Al-Nowaiser F.M., Corrosion Inhibition of Type 430Stainless Steel in HCl Solution by Dipyridinium Salts, J. King Abdulaziz University Sci.,22, 89-100 (2010)
  42. Azza EI and Sayed EI Shenway, Corrosion inhibition of lysine as basic amino acids on 316L stainless steel in 0.5M H2SO4 solution, J. American Sci., 7, 600-605 (2011)
  43. Nada F., Atta A.M., Fekry Hamdi and Hassaneem M., Corrosion inhibition, hydrogen evoluation and antibacterial properties of newly synthesized organic inhibitors on 316L stainless steel alloy in acidic medium, International J. Hydrogen energy.,36, 6462-6471 (2011)
  44. Herle R., Shetty P., Shetty S.D. and Kini U.A., Corrosion inhibition of 304SS in Hydrochloric acid solution by NFurfuryl N'-Phenyl Thiourea, Portugaliae Electrochimica Acta.,29, 69-78 (2011)
  45. James O.O., Ajanaku K.O., Ogunniran K.O., Ajani O.O. Siyanbola T.O. and John M.O., Adsorption Behaviour of pyrazolo [3, 4-b] pyridine on corrosion of stainless steel in HCl solution, Trends in Applied Sciences Research.,, 910- 917 (2011)
  46. Gonzalez. M.B and Saidman. S.B, Electrodeposition of polypyrrole on 316L stainless steel for corrosion prevention, J. Corros. Sci.,53, 276-282 (2011)
  47. Davoodi A., Pakshir M., babaiee M. and Ebrahimi G.R., A comparative study of 304L and 316L stainless steel in acidic media, J. Corros. Sci.,53, 399-408 (2011)
  48. Aysegul Oncul, Kerim Coban, Esma Sezer and Bahire Filiz Senkal, Inhibition of the corrosion of stainless steel by poly-N-vinylimidazole and N-vinylimidazole, Progress in Organic Coatings,71, 167–172 (2011)
  49. Necla Caliskan and Esvet Akbas, The inhibition effect of some pyrimidine derivatives on austenitic stainless steel in acidic media, Materials Chem and Phy.,126, 983–988 (2011)
  50. Ramadev Herle, Prakash Shetty, Divakara Shetty. S and Achutha Kini. U, Corrosion Inhibition of Stainless Steel in Hydrochloric Acid by N - (2-mercaptophenyl) -N' phenyl Thiourea, International J. Chemistry and Applications,, 151-158 (2011)
  51. Diwan Singh Rajan and Shiv Darshan Malik, Surfactants as Corrosion Inhibitors for Stainless Steel in HCl Solution, J. Pure and Applied Science and Technology, 1, 23-35 (2011)
  52. Hamza M.M., Abd El Rehim S.S and Magdy Ibrahim. A.M., Inhibition effect of hexadecylpyridinium bromide on the corrosion behavior of some austenitic stainless steels in H2SO4solutions, Accepted in Arabian Journal of Chemistry, Article In Press, (2015)
  53. Abdel Ghanyl N.A., The Inhibitive Effect of some amino acids on the corrosion behaviour of 316L stainless steel in sulphuric acid Solution, Modern Applied Science, 19 (2011)
  54. Nasrin Soltani, Nahid Tavakkoli, Maryam Khayatkashani, Mohammad RezaJalali and Ahmad Mosavizade, Green approach to corrosion inhibition of 304stainless steel in hydrochloric acid solution by the extract of Salvia officinalisleaves, J. Corros. Sci., 62, 122–135 (2012)
  55. Patric Raymond P., Peter Pascal Regis A., Rajendran S. and Manivannan M., Investigation of Corrosion Inhibition of Stainless steel by Sodium tungstate, Res. J. Chem. Sci.,3(2), 54–58 (2013)
  56. Sakari A.and Midorikawa H.; Bull. Soc. Japan, 41, 430 (1968); Chem. Abstr., 69, 18985 (1968)
  57. Abd B.A., El- Maksoud., Int. J. Electrochem. Sci.,, 528-555 (2008)
  58. Annand R.R., Hurd R.M. and Hackerman N., J. Electrochem. Soc.,112, 1965 (1968)
  59. Cook E.Z., Hackerman N., J. Phys. Chem.,55, 549 (1951)
  60. Abd S.A., Maksoud El, Int. J. Electrochem. Sci.,, 528–555 (2008)
  61. Ebenso E.E., Hailemichael Alemu, Umoren S.A. and Obot I.B., Int. J. Electrochem. Sci.,, 1325 (2008)
  62. Chitra S., Parameswari K., Vidhya M., Kalishwari M. and Selvaraj A., Int. J. Electrochem. Sci.,, 4593 (2011)
  63. Ergun U., Yuzer D. and Emregul K.C., Mater. Chem. Phy.,109, 492 (2008)
  64. Shealty D.S., Shetly P. and Nayak H.V.S., J. Chilean Chem. Soc.,51, 849 (2006)
  65. Hemapriya V.*, Parameswari K. and Bharathy G., Rasayan J Chem.,5(4), 468-476 (2012)
  66. Fouda A.S.*, Abdallah M.and El-Badrawy Z., Afr. J. Pure Appl. Chem.,5(8), 224-236 (2011)
  67. Ezhilarasi M.R., Prabha B. and Santhi T., Rasayan J chem., 8(1), 71-83 (2015)