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Synthesis, Spectroscopic and Physico chemical Characterization of Cu (II), Ni(II), Co(II) and Mn(II) Coordination compounds with 4-methoxy-salycylaldehyde-4-(2’-carboxy-5’-sulphophenyl)-3-thiosemi-carbazone (4-MSCST)

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Author Affiliations

  • 1Department of chemistry, Navyug Science College, Surat-395 007, INDIA
  • 2Department of chemistry, Sir P T Sarvajanik college of Science, Surat-395 007, INDIA

Res.J.chem.sci., Volume 5, Issue (3), Pages 49-52, March,18 (2015)

Abstract

The synthesis and characterization of copper (II), nickel (II), cobalt (II) and manganese (II) coordination compounds of 4-methoxy salycylaldehyde-4-(2’-carboxy-5’-sulphophenyl)-3-thiosemicarbazone (4-MSCST) have been presented. The prepared metal complexes are ML2 type (M= Cu, Ni, Co and Mn; L= 4-MSCST). The IR spectrum suggests that the thiosemicarbazones coordinate in their neutral form and they act as [Metal, N] bidentate chelating ligand. Magnetic properties and UV-visible spectra indicate the octahedral geometries of the 4-MSCST metal complexes. In this work we have proposed the possible structures of the formulated complexes using TGA studies. All the prepared compounds have been tested for their antimicrobial activities.

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