X-Ray Diffraction Study and Biological Analysis of Transition Metal Complexes of N-4-Disubstituted Thiosemicarbazone

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X-Ray Diffraction Study and Biological Analysis of Transition Metal Complexes of N-4-Disubstituted Thiosemicarbazone

Author Affiliations

¹ Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, MS, 431 004, INDIA

Res.J.chem.sci., Volume 5, Issue (12), Pages 33-37, December,18 (2015)

Abstract

Comparative studies on the X-ray diffraction parameters of some transition metal complexes like Fe (III), Cu (II), Zn (II) of ligand (L1) has been prepared by using N-4-Ethyl, phenyl-3-thiosemicarbazide and 2-hydroxybenzaldehyde in equimolar ratio. These complexes show various physicochemical properties. X-ray powder diffraction of Fe (III) complex has triclinic crystal system while Cu (II) and Zn (II) complex of ligand (L1) having monoclinic crystal systems with various unit cell parameters. These complexes also tested for biological analysis and shows considerable activity against bacteria and fungi in comparison with standard drug ciprofloxacin.

References

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[ref1] Sadler P. J., Gun Z., Pure Appl. Chem, 70, 863 (1998)

[ref2] Sadler P. J., Adv. Inorg. Chem, 1, 36 (1991)

[ref3] Abrams M. J., Murrer B. A., Science, 261, 725 (1993)

[ref4] Cameron B. R., Baird I. R., J. Inorg. Biochem, 83, 233 (2001)

[ref5] Bish D.L. and Post J. E., Editors, Modern Powder Diffraction, Reviews in Minerology, V, 20, Mineralogical Society of America(1990)

[ref6] Wall B., Driscoll C., Strong J. and Fisher E., The suitability of different preparations of thermoluminescent Lithium Borate for Medical Dosimetry, Physical Medical biology. 1023-1034 (1982)

[ref7] Azaroff and Burger, the powder method, Mc Graw Hill London (1958)

[ref8] Klop E. A. and Lammers M., Polymers,39, 5987 (1998)

[ref9] Sleema B. and Parameshwaran G., Asian J. Chem., 14, 961 (2002)

[ref10] Scovil J. P., Klayman C. F., Franchino, J. Med. Chem. 25,1261 (1982)

[ref11] Saxena N., Juneja H. D and Munshi K. N., J. Indian Chem. Soc.,70, 943 (1993)

[ref12] Suryawanshi D. D., Gaikwad S. T. and Rajbhoj A. S., Chemical Science Tranction, 3(1), 117-122 (2014)

[ref13] Bhattacharya K. C., An elementary Physics for Indian School, the Indian` Press Ltd. Allahabad, 105 (1934)

[ref14] Kizileikli J., Kurti Y. D., Akkurt B., Genel A. Y., Birteksoz S., Otut G. and Ulkuseven B., Folia Microbial, 52, 15 (2007)