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Physical Properties of Zinc chloride in Aqueous Dextrose Solution

Author Affiliations

  • 1Assistant Professor, Islampur College, Islampur, Uttar Dinajpur: 733202, INDIA

Res.J.chem.sci., Volume 5, Issue (1), Pages 27-32, January,18 (2015)

Abstract

The apparent molar volume (?V), viscosity B-coefficient have been determined of zinc chloride in 2%, 4% and 6% aqueous solution of dextrose at 303.15K, 308.15K and 313.15 K from density (?) and viscosity (?) measurements respectively. The limiting apparent molar volumes (?V0) and experimental slopes (SV*), derived from the Masson equation, have been interpreted in terms of solute–solvent and solute–solute interactions respectively. The viscosity data were analyzed using the Jones–Dole equation and the derived parameter B has also been interpreted in terms of solute–solvent interactions in the solutions. The structure making/breaking behavior of Zinc chloride is inferred from the sign of (d2?V0/dT2)P and dB/dT.

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