International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Adsorption of Benzene on Activated Carbon from Agricultural Waste Materials

Author Affiliations

  • 1Department of Chemical/Petrochemical Engineering, Rivers State University of Science and Technology, Port-Harcourt, Rivers State, NIGERIA
  • 2Department of Petroleum Engineering, Rivers State University of Science and Technology, Port-Harcourt, Rivers State, NIGERIA

Res.J.chem.sci., Volume 4, Issue (9), Pages 34-40, September,18 (2014)

Abstract

Activated carbon was produced from three carbon rich agricultural waste materials; bamboo, coconut and palm kernel shells by pyrolysis and chemical activation (using tri oxo nitrate (v) acid (HNO3 )). The activated carbons were characterized and used as adsorbent for the removal of benzene from aqueous solution. The effects of various parameters such as particle size, adsorbent dosage and initial benzene concentration on the adsorption efficiency of the activated carbons were investigated. Benzene adsorption decreased with increase in particle size of activated carbon, decrease was minimal with activated carbon produced from bamboo. Benzene adsorption increased with increase in adsorbent dosage. Increase in initial benzene concentration resulted in increased adsorption using activated carbon from coconut and palm kernel shells; a decrease in adsorption using activated carbon from bamboo.

References

  1. Rajoriya R.K., Prasad B., Mishra I.M. and Wasewar K.L., Adsorption of Benzaldehyde on Granular Activated carbon: Kinetics, Equilibrium and Thermodynamics, Chem. Biochem. Eng. Q21(3), 219-226 (2011)
  2. Arriagada Y.T., Activated Carbon, Journal of Science and Technology, Elsevier Pub, 5( 2), 81–87, (2001)
  3. Yantasee W., Lin Y., Fryxell G.E., Alford K.L., Busche B.J. and Johnson C.D., Selective removal of Copper (II) from aqueous solutions using Fine Grained Activated Carbon Functionized with Amine, Ind. Eng. Chem. Res.,43, 2759-2764 (2004)
  4. Monser L. and Adhoum N., Modified activated carbon for the removal of copper, zinc, chromium, and cyanide from wastewater, Separation and Purification Technology, 26(2-), 137-146 (2002)
  5. Budinova F.N., Production and Characterization of Activated Carbon, Chem. Int’l, 4(12), 200-209 (2006)
  6. Eddleston D.D., The Use of Granulated Activated Charcoal, World Science, 46(6), 528-533, (2008)
  7. Awoyale, A. A., Eloka-Eboka, A. C. and Odubiyi, O. A., Production and Experimental Efficiency of activated carbon from local waste bamboo for waste water Treatment, International Journal of Engineering and Applied Science, 3(2), 8-17, (2013)
  8. Kalderis, D., Bethanis, S., Paraskeva, P. and Diamadopoulos, E., Production of activated carbon from bagasse and rice husk by a single-stage chemical activation method at low retention times, Bioresource Technology, 99(15), 6809-6816, (2008)
  9. Romanos J., Beckner M., Rash T., Firlej L., Kuchta B., Yu P., Suppes G., Wexler C. and Pfeifer, P., Nanospace engineering of KOH activated carbon, Nanotechnology, 23(1), 15401, (2012)
  10. Cobb, A., Warms, M., Manner, E. P. and Chiesa, S., Low-Tech coconut shell activated charcoal product, International Journal for Service Learning in Engineering, 7(1), 93-104, (2012)
  11. Lua, A. C. and Guo, J., Preparation and characterization of activated carbons from oil-palm stones for gas-phase adsorption, Colloids and Surfaces A, 179(2-3), 151-162, (2001)
  12. Ahmedna M, Marshall W.E. and Rao R.M., Granular activated carbons from agricultural by –products: preparation properties and application in cane sugar refining, Bulletin of Louisana state University Agricultural centre, 54 ( 2000)
  13. Khalil H.P.S.A., Jawaid M., Fiwoziam P., Umar R., Aminal I. and Hazizan Md. A., Activated carbon from various Agricultural wastes by chemical activation with KOH: Preparation and Characterization, Journal of Biobased Material and Bio energy, 7(5), 1-7, (2013)
  14. Gupta V.K. and Imran A., Removal of lead and chromium from waste water using bagasses fly ash – a sugar industry waste, Journal of colloid Interface Science, 271(2), 321-328, (2004)
  15. Ahmadpour A. and Do D.D., The preparation of activated carbon from macadamia nutshell by chemical activation, Carbon, 35, 1723-1732. (1997)
  16. Guo Y., Yu K., Wang Z. and Xu H., Effects of activation conditions in preparation of porous carbon from rice husk, Carbon, 41, 1645-1648, (2003)
  17. Haimour N.M. and Emeish S., Utilization of date stones for production of activated carbon using phosphoric acid, Waste management, 26 (6), 651-660, (2006)
  18. Sentorun,-Shalaby C., Ucak-Astarlioglu M.G., Artok L. and Sarici C., Preparation and Characterization of activated carbon by one-step stem pyrolysis/activation from apricot stones, Microporous and Mesoporous Materials, 88(1-3), 126-134, (2006)
  19. Stavropoulos G.G. and Zabaniotou A.A., Production and Characterization of activated carbons from olive-seed waste residue, Microporous and Mesoporous Materials, 82(1-2), 79-85, (2005)
  20. Lua A.C. and Guo J., Preparation and characterisation of chars from oil palm waste, Carbon, 36, 1663-1670, (1998)
  21. Evbuomwari B.O., Agbede A.M. and Atuka M.M., A Comparative Study of the physio-chemical properties of Activated Carbon from oil palm waste, International Journal of Science and Engineering Investigations, 2(19), 75-79 (2013)
  22. Huff J., Benzene-induced cancers: abridged history and occupational health impact, Int. J Occup. Environ. Health, 13(2), 213–221, (2007) PMID 17718179
  23. Ademuliyi T., Production of Activated Carbon from Agricultural Wastes, AIChE, 34, 59-62 (2008)
  24. ASTM D2867 – 09, Standard Test method for Moisture in Activated Carbon, www.astm.org/standards/D2867.htm, (2009)
  25. ASTM D2866 – 94, Standard Test method for Total ash Content of Activated Carbon, www.astm.org/Data Base, (2004)
  26. Ariyadejwanich P., Tanthapanichakoon W., Nakagawa K., Mukai S.R. and Tamon H., Preparation and characterization of mesoporous activated carbon from waste tires, Carbon, 41, 157-164, (2003)
  27. Narbaitz R.M. and Karimi-Jashni A., Electrochemical regeneration of granular activated carbons loaded with phenol and natural organic matter, Environmental Technology, 30(1), 27–36, (2009)
  28. Yao S., Liu Z. and Shi Z., Arsenic removal from aqueous solutions by adsorption onto Iron oxide/activated carbon magnetic composite, Journal of Environmental Health Science & Engineering, 12, 58 (2014)
  29. Bazrafshan E., Faridi H., Kord M.F. and Mahvi A.H., Arsenic removal from aqueous environments usingmoringa peregrinaseed extract as a natural coagulant,Asian J Chem.,25, 3557-3561 (2013)