@Editorial
<#LINE#>Pilgrimage of Phthalocyanine Macromolecule (Part-V)<#LINE#>Jain@N.C.<#LINE#>Research Journal of Chemical Sciences<#LINE#>
@Research Paper
<#LINE#>Fragmentations processes of 3-coumarinyl carboxylates in ESI / MS and their Correlation with the Electronic charges of their atoms<#LINE#>Jules@Yoda,Thierry@Chiavassa,Adama@Saba<#LINE#>12-16<#LINE#>1.ISCA-RJCS-2014-011.pdf<#LINE#> Laboratoire de Chimie Moléculaire et des Matériaux, Université de Ouagadougou, BURKINA FASO @ Laboratoire de Physique des Interactions Ioniques et Moléculaires, université de Provence, Marseille, FRANCE<#LINE#>13/1/2014<#LINE#>10/2/2014<#LINE#> 3-coumarinyl carboxylates are 3-hydroxyl-coumarin derivatives obtained by O-acylated. In this work, we have studied thecorrelation between electronic charges of atoms and the fragmentation processes of these compounds.. The method has been successfully applied many times for EIMS, but only one time for ESI/MS. In this paper, we would like to apply the method to the ESI/MS spectra of another sery of 3-coumarinyl carboxylates. Good correlations was obtained. <#LINE#> @ @ Abernethy J.L., The historical and current interest in coumarin, J. Chem. Educ, 46, 561 and 856 (1969) @No $ @ @ Murray R.D.H., Mendez .J., Brown. S.A, the natural coumarins: occurrence, chemistry and Biochemistry, Wiley & Sons New York, NY, USA (1982) @No $ @ @ Hassan A. Ewais, Abdulla M. Asiri, Iqbal M .I. Ismail Salem A. Hameed and Ahmed A. Abel-Khalek, Kinetics and Mechanism of the ring opening of 3-carboethoxycoumarin  by sodium hydroxide  and hydrazine, Murray, Research journalof Chemical Sciences, 2(12), 57-64 (2012) @No $ @ @ Levine W.G., In the pharmacological basis of therapeutics. 5th ed. Goodman L. S. and Gilman A., MacMillan, New York (1975) @No $ @ @ O’Reilley R.A., Vitamin K and the oral anticoagulant drugs, Annu Rev. Med., 27, 245-261 (1976) @No $ @ @ Silverman R.B., Model studies for a molecular mechanism of action of oral anticoagulants, J. Am. Chem. Sco., 103, 3910-3915 (1981) @No $ @ @ (a) Kim S.H., Jung E. J., SO E. M., Shen C. Z., Schun H. J., Kim Y.M., Kim I. K.,Enhanced Electrochemiflorescence and reduction mechanism of acetoxy coumarin derivatives in acetonitrile solution, Bull. Korean Chem. Sco., 27, 1329 (2006) (b) Roh S.–G., Baek M. S., Hong K.–S., Kim H. K., Synthesis and photophysical properties of luminescent lanthanide complexes based on coumarin-3-carboxylic acid for advanced photonic applications, Bull. Korean chem. Soc., 25, 343 (2004) @No $ @ @ (a)Zahradnik M., The Production and Application of Fluorescent Brightening Agents, Wiley & Sons, 1992) @No $ @ @ (b). Maeda, Laser Dyes, Academic Press, New York, 1994) @No $ @ @ Stefanou V., Matriadis D., MelagraKi G., Afantitis A., Athanasellis G., Igglessi-Markopoulou O.,Vickie McKee and John Markopoulos Functionalized 4-hydroxy coumarins: Novel synthesis, crystal structure and DFT calculations, molecules, 16, 384-402 (2011) @No $ @ @ Vijila C., Ramalingan A., Palanisamy P.K. and Masilmani V., Role of dipole moment of solvent in formation and stabilization of the tict states in coumarin 445 under nitrogen laser excitation, Spectrochimical acta part A, 57, 491-497 (2001) @No $ @ @ Ramegouda M., Change in energy of hydrogen bonds upon excitation of coumarin 1: TDDFT/EFP1 method, Research journalof Chemical Sciences, 3(7), 27-30 (2013) @No $ @ @ Su-Jin Park, Jong-Cheol Lee, and Kee-In Lee, A facile synthesis of 4-hydroxycoumarin and 4-Hydroxy-2-quinolone derivatives, Bull. Korean Chem.Sco., 28(7),1203-1205 (2007) @No $ @ @ Carboni S., Maloguzzi V., Marzili A., Ferulend a new coumarin derivative form ferula commis, Tetrahedron Lett., , 2763-2785 (1964) @No $ @ @ Trimèche B., Gharbi K., Romdhane A., Hammami S., Mighri S. A.Z ., Synthèse et étude de la réactivité d’un nouveau dérivé 4-oxocoumarinique, journal de la société chimique de Tunisie, 11, 91-99 (2009) @No $ @ @ Traven V. F., Negrebetsky V. V., Vorobjeva L. I. and Carberry E. A, Keto-enol tautomerism,NMR spectra, and H-D exchange of 4-hydroxycoumarins, Can. J.Chem., 75, 377- 383 (1997) @No $ @ @ Cissé L., Tine A., Kaboré L. and A. Saba, Mass spectrometry study of coumarins: Correlation between charges of atoms and fragmentations processes, Spectroscopy Letters, 42,95-99 (2009) @No $ @ @ Cissé L., Kaboré L., Tine A. and A. Saba,Analysis of fragmentation of coumarins in mass spectrometry using the electronic charges of atoms, Bull. Chem Soc. Ethiopia,24(2), 305 (2010) @No $ @ @ Cissé L., Kabore L., Saba A. and Tine A., Study of mass spectra of 4, 7-disubstituted coumarins: correlation between electronic charges of atoms and fragmentation process, Phys. Chem. News, 53, 101-1072010) @No $ @ @ Djandé A., Sessouna B., Cissé L., Kaboré L., Tine A and Saba A., AM1 and ESI/MS study of the fragmentation of 4-Acyl Isochroman-1,3-diones: Correlation between Electronic charges of Atoms and Fragmentations processes, Research journalof Chemical Sciences, 1(3),606 (2011) @No $ @ @ Res. J. Chem. Sci.   International Science Congress Association 1620.Djandé A., Sessouma B., Kini F. B. Kaboré L., Guissou I. P; Saba A, AM1 and Electronic Impact Study of the fragmentations of 4-acyl isochroman-1,3-diones, Bull. Chem. Soc. Ethiop., 26(2), 1-8 (2012) @No $ @ @ Saba A., Thèse Unique, Recherche dans la série des sels de benzopyrylium : Synthèse et étude de la structure des sels de 2-benzopyrylium, UFR-SEA, Université de Ouagadougou1996) @No $ @ @ Dewar M.J., Zoebish E .G., Healy E.F., Stewart J.P., Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model, J. Amer. chem. Soc, 107, 3902 (1985) @No 
<#LINE#>Phytotoxicity Assessment of Coir pith Effluent Generated during Lignin Recovery Process<#LINE#>Syamkumar@R,G.@Rojith,Rajathy@S,BrightSingh@I.S.<#LINE#>17-21<#LINE#>2.ISCA-RJCS-2014-014.pdf<#LINE#> School of Environmental Studies, Cochin University of Science and Technology, Cochin, Kerala - 682022, INDIA <#LINE#>16/12/2013<#LINE#>15/2/2014<#LINE#> Research programs are advancing for tackling the pollution risks of coir pith by converting the substrate into valuable products. The product development process shall generate byproducts or effluents that may be toxic in nature. An efficient oxidative delignification process was developed followed by lignin recovery from the process effluent. The toxicity assessment of effluent generated during lignin recovery process is of utmost importance for the safe disposal plans and the present study aims at assessing the phytotoxicity of the effluent. The test involved 96 hour exposure of Oryza sativa to 0.0% to 100% effluent concentrations. The parameters of analysis included root length (RL), shoot length (SL), seedling length (SDL), seed germination (SG), germination index (GI) and seed vigour index (SVI). The effluent produced significant inhibitory effect on growth of the plant. Root length (EC25=3.05, EC50=5.14) and germination index (EC25=2.78, EC50=4.78) were the most sensitive endpoints, whereas seed germination was the least sensitive (EC25=36.63, EC50=45.45). Based on sensitivity, different endpoints were arranged in decreasing order of sensitivity as: RL=GI>SDL=SVI>SL>SG. The outcome of this study points out the importance of further characterisation of the effluent generated during lignin recovery and adoption of suitable detoxification method.<#LINE#> @ @ Vardhanan Shibu Y., Haridas Ajit and Manilal V.B., Closed Retting: A green Technology for Controlling Coir Retting Pollution of Backwaters, J. Env. Res. and Dev.,7(4A), 1523-1530 (2013) @No $ @ @ Vinidini S., Gnanambal V.S., Sasikumar J.M. and Padmadevi S.N., Growth of two medicinal plants using biodegraded coir pith, Plant Archives., (5), 277-280 (2005) @No $ @ @ Ramalingam A., Gangatharan M., and Kasthury Bain R., Solid state bio-treatment of coir pith and paddy straw, Asian J Microbiol. Biotechnol. Environ. Sci., , 144-149 (2004) @No $ @ @ Rojith G., and  Bright Singh  I.S., Lignin recovery, biochar production and decolourisation of coir pith black liquor, Res.J.Recent Sci., 1(ISC-2011)  , 270-274 (2012) @No $ @ @ Paulraj Kanmani, Karuppasamy P., Pothiraj C., and Venkatesan Arul., Studies on lignocellulose biodegradation of coir waste in solid state fermentation using Phanerocheatechrysosporium and Rhizopusstolonifer, Afr. J. Biotechnol., 8(24),  6880-6887, (2009) @No $ @ @ Srivastava Ajeet Kumar and Agrawal Pushpa, Microbial pretreatment of lignocellulosics materials and production of bioethanol, J. Environ. Res. Develop.,7(1A), 375-380 (2012) @No $ @ @ Thomas S., Sarfarag S., Mishra L.C. andIyengar L., Degradation of phenols and phenolic compounds by a defined denitrifying bacteria culture, World J Micro.Biotechnol., 18(1), 57-63, (2002) @No $ @ @ Rojith G., and Bright Singh I.S., Delignification, cellulose crystallinity change and surface modification of coir pith induced by oxidative delignification treatment, Int .J. Env iron. Bioene.,, 46-55 (2012) @No $ @ @ Rojith G., and Bright Singh IS, Hydrogen Peroxide Prettreatment Efiicieancy Comparison and Characterisation of Lignin Recovered from Coir pith Black Liquor, J. Environ. Res. Develop.,(4), 1333- 1339 (2013) @No $ @ @ Organisation for Economic Co-operation, Development (OECD), Terrestrial plants: growth tests, OECD Guidelines for Testing of Chemicals, Paris, France, No. 208, (1984) @No $ @ @ Bhale U.N., Tolerance of Polluted Water on Seedling Growth of Some Cereal Crops, Int. J Latest Trends Bot.Sci., 1(1), 5-7 (2011) @No $ @ @ Cordova Rosa E.V., Simionatto E.L., de Souza Sierra M.M., Bertoli S.L. and Radetski C.M., Toxicity-based criteria for the evaluation of textile wastewater treatment efficiency., Environ Toxicol Chem 20(4), 839-45 (2001) @No $ @ @ Politycka B., Wojcik-Wojtkowiak D., Pudelski T., Phenolic compounds as a cause of phytotoxicity in greenhouse substrates repeatedly used in cucumber growing, Acta Hort., 156, 89–94 (1985) @No $ @ @ Tanaka F., Ono S., Hayasaka T., Identification and evaluation of toxicity of rice root elongation inhibitors in flooded soils with added wheat straw, Soil Sci. Plant. Nutr., 36, 97–103, (1990) @No $ @ @ Ma Y. B., and Nichol D. G., Phytotoxicity and Detoxification of, Fresh Coir Dust and Coconut Shell, Commun. Soil Sci. Plant Anal, 35(1 & 2), 205–218, (2004) @No $ @ @ Johannes Schindelin, Ignacio Arganda-Carreras, Erwin Frise, Verena Kaynig, Mark Longair, Tobias Pietzsch, Stephan Preibisch, Curtis Rueden, Stephan Saalfeld Benjamin Schmid, Jean-Yves Tinevez, Daniel James White, Volker Hartenstein, Kevin Eliceiri, Pavel Tomancak and Albert Cardona, Fiji: an open-source platform for biological-image analysis, Nature Methods. 9(7), 676-682 (2012) @No $ @ @ R, Core Team, R: A language and environment for statistical computing, R Foundation for Statistical Computing. Vienna, Austria. ISBN 3-900051-07-0, (2005) @No $ @ @ URL: http://www.R-project.org/. 18.Ritz C., and Streibig J. C., Bioassay Analysis using R, J. Statist. Software., 12(5), 1-22 (2005) @No $ @ @ Persoone G., Marsalek  B., Blinova I.,  Törökne A Zarina  D., Manusadianas L., Nalecz-jawecki G., Tofan, Stepanova N., Tothova, Kolar B., A practical and user-friendly toxicity classification system with Microbiotests for natural waters and wastewaters, Enviro. Toxicol.,18, 395-402 (2003) @No $ @ @ Sangeeta Dey, Manabendra Dutta, Choudhury and Suchismita Das, A Review on Toxicity of Paper Mill Effluent on Fish, Bull. Env. Pharmacol. Life Sci. 2 (3), 17-23 (2013) @No $ @ @ Mekki A., Dhouib A., Sayadi S., Polyphenols dynamics and phytotoxicity in a soil amended by olive mill wastewaters, J Environ Manage., 84(2),134-40 (2007) @No $ @ @ Varma K.V.R., Swaminathan T., and Subrahmanyam V.P.R., Heavy Metal Removal with Lignin, J. Environ. Sci. Health.,A 25(3), 243-265, (1990) @No $ @ @ Kalaiselvi P., Mahimairaja S., Srimathi P. and Senthil Kumar G., Impact of Industrial Effluents in Seed Invigouration: A Review, Asian. J. 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<#LINE#>Electrochemical synthesis and characterization of Zn-Se-Hg Thin film<#LINE#>R.K.@Pathak,Priyanka@Wagela<#LINE#>22-27<#LINE#>3.ISCA-RJCS-2014-018.pdf<#LINE#> Department of Chemistry, Govt. Holkar Science College, Indore, MP, INDIA Department of Engg. Chemistry, Vikrant Inst. of Tech. and Mgt., Indore, MP, INDIA<#LINE#>24/1/2014<#LINE#>25/2/2014<#LINE#> The electrochemical deposition and characterization on Hg containing ZnSe thin films are reported. Electrodeposition of ZnSeHg alloy coating onto aluminum substrates in a useful form from acid bath. The study of the electrochemical deposited alloys using electrochemical impedance spectral (EIS) and corrosion characteristics.  The composition and structure of these alloys were investigated. The corrosion parameters determined from the polarization curves recorded in 0.5M NaCl solution at room temperature. The impedance spectra recorded at the ocp showed in all cases, which may be explained by the development of corrosion products on the electrode surface. The surface morphology of deposited films was investigated by scanning electron microscopy (SEM). The compositional analysis of electrodeposited films was investigated by Energy dispersive X-ray spectroscopy (EDAX).  <#LINE#> @ @ S.I.A. Kobendza, Semiconducting thin films of AII VICompounds, Polish Scientific Publishers, Warsa (1990) @No $ @ @ Bhahada K.C., Tripathi B., Acharya N.K., Kulriya P.K. and Vijay Y.K., Chalcogenide Letters, 5(7), 137-142(2008) @No $ @ @ Chaparro A.M., Martinez M.A., Bayon R. and Herrero J., Thin solid Films, 177, 361 (2000) @No $ @ @ Lee J. Kim, Y.Kim, K.Huh, Y.Hyun, J.Kim, C. Bull.Korean Chem. Soc., 28, 1091 (2007) @No $ @ @ Seo D., Lee K., Yoon S. and Shim S., I.Bull.Korean Chem. Soc., 27, 762 (2006) @No $ @ @ Natarajan C., Nogami G., Sharon M. Thin Solid Films,261, 144 (1995) @No $ @ @ Chandramohan R., Mahaligam T., Chu J. and Sebastian P.J., Solar Energy Mater.Solar Cells,81, 371 (2004) @No $ @ @ Loglio F., Innocenti M., Pezzatini G. and Foresti M.L., J.Electroanal.Chem.,562, 117 (2004) @No $ @ @ Mishra S.S.D. and Singh K., Solar Energy Material & Solar Cells,93, 1202-1207 (2009) @No $ @ @ Afshar A., Dolati A.G. and Ghorbain M., Mater. Chem. Phys., 77, 352 (2002) @No $ @ @ Leith S.D., Wang W. and Schwartz D.T., J. Electrochem. Soc.,145, 2827 (1999) @No $ @ @ Jung-Yu iaLo, Kuo-Chuan Ho, Solar Energy Material & Solar Cells 86, 229-241 (2005) @No $ @ @ Juttner K., Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces, electrochim. Acta, 35, 1501 (1990) @No $ @ @ Pathak R.K., Electrosynthesis and characterization of CdSeHgTl thin films, Res. J. Chem.Sc.,3(4), 44 (2013) @No $ @ @ Kartik B., Selvakumar S. and Thangavelu C. Corrosion Behaviour of Carbon Steel in DTPMP-ST Zn2+ System: An Eco-Friendly System,Res.J. Chem. Sci.,3(10), 16 (2013) @No $ @ @ Pathak R.K. and Wagela P., Electrochemical preparation and characterization of Fe-cu alloy on anodized Alumina templets, J.Chem. & Cheml. Sci., 3(4), 251 (2013) @No $ @ @ Prabakaran M. Ramesh S. and Periasamy V. Synergistic effect of thiomalic acid and zinc ions in corrosion control carbon steel in aquous solution, Res.J. Chem. Sci., 4(1), 41 (2014) @No $ @ @ Pathak R.K. and Mohan S., The potentiostatic electrodeposition of Indium doped aluminum Selenide thin films, Orienta J. Chem., 29(30), 1047 (2013) @No $ @ @ R.K. and Sankwa S., Electrochemical and corrosion studies on electrosynthesised CdInGaSe thin films, J.Ind.Chem. Soc., 82, 845 (2005) @No $ @ @ S.I.A. Kobendza, Semiconducting thin films of AII VICompounds, Polish Scientific Publishers, Warsa (1990) @No
<#LINE#>Effect of Heat Treatment on Nutrient and Anti-nutrient Components of Melon (Citrullus colocynthis) Husks<#LINE#>A.S@Idoko,A.T.@Oladiji,M.T.@Yakubu,A.S.@Aska<#LINE#>28-32<#LINE#>4.ISCA-RJCS-2014-023.pdf<#LINE#>Department of Biochemistry, Federal University Dutsinma, Katsina state, NIGERIA @ Department of Biochemistry, University of Ilorin, Ilorin, NIGERIA @ Department of Chemistry, College of Education, Azare, BAUCHI STATE<#LINE#>28/1/2014<#LINE#>25/2/2014<#LINE#> The effects of heat treatment (boiling and autoclaving) on the nutrient and anti-nutrient components of melon husk were investigated. The proximate compositions (crude protein, lipid, fibre, ash and carbohydrate), mineral constituents (Calcium(Ca), Potassium(K), Sodium(Na), Iron(Fe), Copper(Cu), Zinc(Zn), Magnesium(Mg) and Phosphorous(P)) and antinutrients compositions (Tannin, Oxalate, Phytate, Hydrogen cyanide  (HCN), Tripsin inhibitor (TIA), Amylase inhibitor (AIA) and Lectin) were determined using standard methods in three portions of melon husk: Raw, Boiled and Autoclaved. The results of the proximate analysis revealed that variations in the proximate composition of the differently treated husks were significant except for the lipid content. However, there was no significant difference between the proximate compositions of raw and autoclaved melon husks except for ash and carbohydrate contents. The results of mineral analysis showed that boiling caused significant reductions in all the mineral elements analyzed. All the detected antinutrients were significantly reduced by heat treatments (boiling and autoclaving) and autoclaving was found to be more effective in reducing the levels of antinutrients than boiling. The results therefore showed that autoclaving is more effective in reducing the levels of antinutrients and had lesser effect on the nutrient composition of melon husk than boiling. It is concluded that melon husk, if heat treated, could be an alternative source of feed for live stock <#LINE#> @ @ Alkofahi A., Batshoun R., Owis W. and Najib N., Biological activity of some Jordanian plants extracts, Fitoterapia,5, 435–42 (1996) @No $ @ @ Achu, M.B., Fokou, E., Tchiegang, C., Fotso, M., and Tchouanguep, F.M.: Nutritive value of some curbitaceae oilseeds from different regions in Cameroon, Afr. J. Biotechnol., (11), 1329–1334 (2005) @No $ @ @ Egusi, Wikipedia, the free encyclopedia, Retrieved June  08 2012 (2012) @No $ @ @ Oluba M.O., Ogunlowo Y.R., Ojieh G.C., Adebisi K.E., Eidangbe G.O. and Isiosio I.O., Physicochemical properties and fatty acid composition of citrullus lanatus (Egusi melon) seed oil, J. Biol. Sci., (8), 814–817 (2008) @No $ @ @ Schafferman D., Beharav A., Shabelschy E. and Yaniv Z., Citrullus colocynthis, J. Arid of Environs.,40, 431-39 1998)  @No $ @ @ Yusuf A.A., Adewuyi S. and Lasisi A.A., Physicochemical composition of leaves, meals and oils of fluted pumpkin Telfairia occidentalis) and molon (Citrullus vulgaris), Agric. J., (1), 32-35 (2006) @No $ @ @ Ziyada A.K. and Elhussien S.A., Physical and Chemical Characteristics of Citrullus lanatus Var. Colocynthoide Seed Oil, J. of Physical Sci., 19(2), 69–75 ( 2008) @No $ @ @ Oyenuga V.A., Nigerian Foods and Feeding Stuffs, Their Chemistry and Nutritive Values (Pp. 8 - 16; 86- 89), Ibadan: Ibadan University Press (1978) @No $ @ @ Oloyede O.B., Otunola G.A. and Apata D.F., Assessment of protein quality of processed melon seed as a component of poultry feed, Biokemistri, 16) 80-87 (2004) @No $ @ @ Moerman D., Native American Ethnobotany, Timber press, Oregon, 453- 459 (1998) @No $ @ @ Isak R.S. and Alamgir A.S., Utilization of Wheat Husk Ash as Silica Source for the Synthesis of MCM-41 Type Mesoporous Silicates: A Sustainable Approach towards Valorization of the Agricultural Waste Stream, Res. J. Chem. 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Food and Agricultural Organization (FAO/UN), Rome, Food and Nutrition Paper, 26 (1982) @No $ @ @ Ogbe A.O. and George G.A.L., Nutritional and Anti-nutrient Composition of Melon Husks: Potential as Feed Ingredient in Poultry Diet, Research Journal of Chemical Sciences,2(2), 35-39 (2012) @No $ @ @ Udensi E.A., Onwuka G.I. and Okoli E.C., Effect of processing on the levels of some Antinutritional factors in Mucuna utilis, J. Plant Prod. Res., (), 1-7 (2003) @No $ @ @ Ugwu F.M. and Oranye N.A., Effects of some processing methods on the toxic components of African breadfruit (Treculia africana), African J. of Biotech.,22), 2329-2333 2006) @No $ @ @ Vijayakumari K., Pugalenthi M. and Vadivel V., Effect of soaking and hydrothermal processing methods on the levels of antinutrients and in vitro protein digestibility of Bauhinia purpurea L. seeds, Food Chemistry,103, 968 – 975 (2007) @No $ @ @ Vadivel V., Pugalenthi M. and Megha M., Biological evaluation of protein quality of raw and processed seeds of gila bean (Entada scendens Benth), Tropical and Subtropical Agro ecosystem,8, 125-133 (2008) @No $ @ @ Phytic acid, Wikipedia, the free encyclopedia, Retrieved Jan  08 (2012) @No $ @ @ Amylase inhibitor, Wikipedia, the free encyclopedia, Retrieved Jan  08 (2012) @No $ @ @ Evan A. and Worcester E., Kidney stone disease, J. Clin Invest., 11510), 598–608 (2005) @No $ @ @ Gogoi R., Niyogi, U.K. and Tyagi, A.K. Reduction in Trypsin Inhibitor Activity in Jatropha cake by Chemical, Thermal and Radiation Treatment, Res. J. Chem. Sci., ), 17-19, January (2014) @No 
<#LINE#>Evaluation of Physico-chemical Characteristics of Drinking Water Supply in Kathmandu, Nepal<#LINE#>Shova@TamrakarChirika<#LINE#>33-36<#LINE#>5.ISCA-RJCS-2014-026.pdf<#LINE#> Department of Chemistry, Faculty of Science, Padma Kanya Multiple Campus, Tribhuvan University, Kathmandu, NEPAL<#LINE#>31/1/2014<#LINE#>7/2/2014<#LINE#> In order to understand the quality of drinking water supply in Kathmandu metropolitan city, physico-chemical characteristics were studied and analyzed. Various physico-chemical parameters, such as turbidity, water temperature, pH, conductivity, total alkalinity, total hardness, calcium, magnesium, chloride, iron and total ammonia were studied and compared with National Drinking Water Quality Standard (NDWQS) of Nepal and WHO water quality guidelines. The results revealed that most of the parameters were in normal range and indicated suitability for drinking purposes.  <#LINE#> @ @ Ikem A., Odueyungbo S. and Egiebor Nyavor N.O.K., Chemical Quality of  Bottled Waters from Three Cities in Eastern Alabama, Sci. Total Environ, 285, 165-175 (2002) @No $ @ @ World Health Organization, Guidelines for drinking water quality, 3rd Edn., WHO, Geneva, (2006) @No $ @ @ International Center for Integrated Mountain Development (ICIMOD), Kathmandu Valley Environmental Outlook, Kathmandu, Nepal (2007) @No $ @ @ WHO, Guidelines for drinking-water quality, 3rd ed. WHO, Geneva, Switzerland, (2004) @No $ @ @ Standard methods for examination of waters and waste waters, 16th ed., APHA, AWWA and WPCF Inc. New York (1985) @No $ @ @ Katiwada N.R., Takizawa S., Tran T.V.N. and Inoue M., Groundwater contamination assessment for sustainable water supply in Kathmandu valley, Nepal, Water Sci. Tech., 46, 147-154 (2002) @No $ @ @ Kumar A., Gupta H.P. and Singh D.K., 1996. Impact of sewage pollution on chemistry and primary productivity of two fresh water bodies in Santal Paragana (Bihar), India,  J. Ecol., 23, 82-86 (1996) @No $ @ @ Parihar S.S., Kumar A., Kumar A., Gupta R.N., Pathak M., Shrivastav A. and Pandey A.C., Physico-Chemical and Microbiological Analysis of Underground Water in and Around Gwalior City, MP, India, Res. J. Recent Sci., 1, 62-65, (2012) @No $ @ @ Wetzel R.G., Limology, W.B., Saunders Co., Philadelphia, USA, 743 (1975) @No $ @ @ Wetzel R.G. and Likens G.E., Limnology Analyses, Springer-Verlag, New York (1991) @No $ @ @ Manivasakam N., Physicochemical Examination of Water, Sewage and Industrial Effluents, 2nd edn., Pragati Prakashan (2000) @No $ @ @ Fulvio D.E. and Olori L., In: Hardness of Drinking Water and Public Health, Pergamon Publication, New York (1965) @No $ @ @ McCarthy M.F., Should we restrict chloride rather than sodium? Med Hypotheses, 63, 138-148 (2004) @No $ @ @ Purohit S.S. and Saxena M.M., In: Water life and pollution, Agro Botanical Publication, New Delhi (1990) @No $ @ @ Trivedy R.K. and Goel P.K., Chemical and Biological Methods for Water Pollution Studies, Environmental Publications, Oriental Printing Press, Aligarh (1986) @No $ @ @ Versari A., Parpinello G.P. and Galassi S., Chemometric survey of Italian bottled mineral waters by means of their labelled physico-chemical and chemical composition, J. Food Compos. Anal., 15, 251-264 (2002) @No $ @ @ Pandey V.P., Chapagain S.K. and Kazama F. Evaluation of groundwater environment of Kathmandu Valley. Environ. Earth Sci., 60, 1329-1342 (2010) @No 
<#LINE#>Development of Electrochemical sensor based on Poly (xylenol orange) film towards the determination of L-Dopa and its simultaneous resolution in the presence of Uric acid: A cyclic Voltammetric study<#LINE#>P.V.@Narayana,Madhusudana@ReddyT,Gopal@P,Reddaiah@K.,Raghu@P<#LINE#>37-43<#LINE#>6.ISCA-RJCS-2014-036.pdf<#LINE#> Electrochemical Research Laboratory, Department of Chemistry, Sri Venkateswara University, Tirupati- 517 502, Andhra Pradesh, INDIA <#LINE#>7/2/2014<#LINE#>28/2/2014<#LINE#> The surface of carbon paste electrode (CPE) was modified based on electropolymerization of xylenol orange (XO) using cyclic voltammetry. This poly (XO) modified carbon paste electrode (poly(XO)MCPE) exhibited good electrocatalytic activity towards the quantification of L-dopa in 1mM phosphate buffer solution (PBS) at pH 5.0. The method was used to study the factors such as effects of pH,scan rate and concentration. Kinetic parameters such as diffusion coefficient (D), area of the modified electrode (A), limit of detection and limit of quantification of L-dopa were calculated. Simultaneous determination of L-dopa in the presence of uric acid (UA) was studied by differential pulse voltammetry (DPV). The interfacial electron transfer behaviour of L-dopa was studied by means of electrochemcal impedance spectroscopy (EIS).  The practical analytical application of poly(XO)MCPE towards the detection of L-dopa in a commonly available commercial tablet sample has also been evaluated.<#LINE#> @ @ Khor S., Hsu A., The pharmacokinetics and pharmacodynamics of levodopa in the treatment of Parkinson's disease, Curr. Clin. Pharmacol.,2(3), 234-243(2007) @No $ @ @ Honda H., Gindin R.A.,Gout while receiving levodopa for parkinsonism, J. Am.Med. Assoc., 219, 55–57 (1972) @No $ @ @ Katzenschlager R., Lees A.J., Treatment of Parkinson's disease: levodopa as the first choice, J. Neurol., 249, II/19–II/24 (2002) @No $ @ @ Weiner W.J., Diagnosis & Clinical Mangement, Demos Medical Publishing, New York, 2002  @No $ @ @ Nematollahi D., Rafiee M., Fotouhi L., Mechanistic study of homogeneous reactions coupled with electrochemical oxidation of catechols,J. Iran. Chem. Soc., 6, 448–476 (2009) @No $ @ @ Melamed.E, Offen.D, Shirvan.A., Ziv.I.,Levodopa-an exotoxin or a therapeutic drug?, J. Neurol.,247,  135–139 (2000) @No $ @ @ Popa.E, Kubota.Y, D.A. Tryk, A. Fujishima, Selective voltammetric and amperometric detection of uric acid with oxidized diamond film electrodes, Anal.Chem., 72, 1724–1727 (2000) @No $ @ @ Hansson.C., Agrup.G., Rorsman.H., Rosengren.A.M., Analysis of cysteinyldopas, dopa, dopamine, noradrenaline and adrenaline in serum and urine using high-performance liquid chromatography and electrochemical detection, J. Chromatogr., 162,  7–22 (1979) @No $ @ @ Cannazza.G., Di Stefano.A., Mosciatti.B., Braghiroli.D., M. Baraldi, F. Pinnen, P.Sozio, C.Benatti, C. Parenti, Detection of levodopa, dopamine and its metabolites in rat striatum dialysates following peripheral administration of -dopa prodrugs by mean of HPLC–EC, J. Pharmaceut. Biomed. Anal.36, 1079–1084 (2005) @No $ @ @ Helaleh M.I.H., Rahman N., Abu-Nameh E.S.M.,Use of cerium(iv) nitrate in the spectrophotometric determination of levodopa and methyldopa in the pure form and pharmaceutical preparations, Anal. Sci., 13, 1007–1010 (1997) @No $ @ @ Teixeira M.F.S., Marcolino-J´unior L.H., Fatibello-Filho O., Dockal E.R., Bergamini M. F., An electrochemical sensor for -dopa based on oxovanadium-salen thin film electrode applied flow injection system,  Sens. Actuat. B,122(2), 549–555 (2007) @No $ @ @ He W.W., Zhou X.W., Lu J.Q., Simultaneous determination of benserazide and levodopa by capillary electrophoresis–chemiluminescence using an improved interface, J. Chromatogr. A,1131, 289-292 (2006) @No $ @ @ Marques K.L., Santos J.L.M., Lopes J.A., Lima J.L.F.C., Simultaneous chemiluminometric determination of levodopa and benserazide in a multi-pumping flow system with multivariate calibration,  Anal. Sci., 24, 985-991(2008) @No $ @ @ Wring S.A., Hart J.P., Chemically modified, carbon-based electrodes and their application as electrochemical sensors for the analysis of biologically important compounds,  Analyst, 117,1215-1229 (1992) @No $ @ @ Yan X.X., Pang D.W., Lu Z.X., Lü  J.Q., Tong H., Electrochemical behavior of -dopa at single-wall carbon nanotube-modified glassy carbon electrodes, J. Electroanal. Chem.,569, 47-52 (2004) @No $ @ @ Hua G.Z., Chen L., Guo Y., Wang  X.L., Shao S.J, Selective determination of L-dopa in the presence of uric acid and ascorbic acid at a gold nanoparticle self-assembled carbon nanotube-modified pyrolytic graphite electrode, Electrochim. Acta., 55, 4711-4716 (2010) @No $ @ @ Reddaiah K., Reddy T.M., Raghu P., Electrochemical investigation of L-dopa and simultaneous resolution in the presence of uric acid and ascorbic acid at a poly (methyl orange) film coated electrode: A voltammetric study, J. Electroanal. Chem.,682, 164-171 (2012) @No $ @ @ Ohnuki Y., matsuda H., Ohsaka T., Oyama N., Permselectivity of films prepared by electrochemical oxidation of phenol and amino-aromatic compounds, J. Electroanal. Chem.,158, 55-67 (1983) @No $ @ @  Cai C.X.,  Xue K.H., Electrochemical characterization of electropolymerized film of Naphthol-green-B and its electrocatalytic activity toward NADH oxidation, Microchem J., 58, 197-208 (1998) @No $ @ @ Karyakin A.A., Bobrova O.A., Karyakina E.E., Electroreduction of NAD to enzymatically active NADH at poly(neutral red) modified electrodes, J. Electroanal. Chem., 399, 179-184 (1995) @No $ @ @ Wang B.Q., Li B., Wang Z.X., Xu G.B., Wang Q., Dong S.J., Sol-Gel thin-film immobilized Soybean peroxidase biosensor for the amperometric determination of hydrogen peroxide in acid medium,  Anal. Chem., 71, 1935-1939 (1999) @No $ @ @ Nicholson R.S., Shain I., Theory of stationary electrode polarography: Single scan and cyclic methods applied to reversible, irreversible and kinetic systems, Anal.Chem.,36, 706-723 (1964) @No $ @ @ Raghu P., Swamy B.E.K., Reddy T.M., Chandrashekar B.N., Reddaiah K., Sol–gel immobilized biosensor for the detection of organophosphorous pesticides: A voltammetric method, Bioelectrochemistry,83, 19-24 (2012) @No $ @ @ Reddaiah K., Reddy M.M., Raghu P., Reddy  T.M., An electrochemical sensor based on poly (solochrome dark blue) film coated electrode for the determination of dopamine and simultaneous separation in the presence of uric acid and ascorbic acid: A voltammetric method, Colloids Surf. B, 106, 145-150 (2013) @No $ @ @  Viswanathan S., ChinLiao W., Huang C.C., Rapid analysis of L-dopa in urine samples using gold nanoelectrode ensembles,  Talanta, 74,  229-234 (2007) @No $ @ @ Raghu P., Reddy T.M., Swamy B.E.K., Chandrashekar B.N., Reddaiah K.,  Development of AChE biosensor for the determination of methyl parathion and monocrotophos in water and fruit samples:A cyclic voltammetric study,  J. Electroanal. Chem.,665, 76-82 (2012) @No $ @ @ Chandra U., Swamy B.E.K., Gilbert O., Sherigara B.S., Voltammetric resolution of dopamine in the presence of ascorbic acid and uric acid at poly (calmagite) film coated carbon paste electrode,   Electrochim. Acta,55, 7166-7174 (2010) @No $ @ @ Gopal P., Reddy T.M., Reddaiah K., Raghu P., Narayana P.V., An electrochemical investigation and reduction mechanism of 3,5-Dinitrobenzoic acid at a glassy carbon electrode: A voltammetric study, J. Mol. Liq., 178,  168-174 (2013) @No $ @ @ Atta F.N., Galal A.A., Ahmed R., Poly(3,4-ethylene-dioxythiophene) electrode for the selective determination of dopamine in presence of sodium dodecyl sulfate, Bioelectrochemistry,80, 132–141 (2011) @No
<#LINE#>A Study on Removal of Cadmium(II) from Aqueous solutions by Adsorption on Red Mud<#LINE#>Sujata@Kumar,D.@Singh,M.@Upadhyay,A.K@Mishra,Saroj@Kumar<#LINE#>44-53<#LINE#>7.ISCA-RJCS-2014-037.pdf<#LINE#> Department of Chemistry, K. Govt. Arts and Sc. College Raigarh, CG, INDIA  @ Department of Chemistry, Kirodimal Institute of Technology, Raigarh, CG, INDIA @ Department of Chemistry, Dr. C.V. Raman University, Bilaspur, CG, INDIA <#LINE#>10/2/2014<#LINE#>15/3/2014<#LINE#> The present study aims to evaluate the removal characteristics of red mud as adsorbent to remove Cd(II) ion from aqueous solutions by batch experiments under various experimental  conditions. Freundlich and Langmuir adsorption isotherm models have been used to discuss the data obtained. Lagergren first-order equation, pseudo-second-order equation and intra-particle diffusion models have been used to discuss the kinetics. To have an idea about spontaneity and feasibility of the adsorption process, thermodynamic parameters such as change in free energy G, change in enthalpy H and change in entropy S have been evaluated and discussed. <#LINE#> @ @ Bhatnagar A. and Minocha A.K., Conventional and nonconventional adsorbents for removal of pollutants from water – A review, Indian J.Chem.Tech., 13, 203-217 (2006) @No $ @ @ Karthika C. and Sekar M., Removal of Hg(II) ions from aqueous solution by acid acrylic resins : A study through adsorption isotherms analysis, I. Res. J. Environment Sci., 1(1), 34-41 (2012) @No $ @ @ Singh Dhanesh and Singh A.,Chitosan for the removal of chromium from waste water., I. Res. J. Environment Sci.,1(3), 55-57 (2012) @No $ @ @ Samuel P., Ingmar P., Boubia C. and Daniel L., Trivalent chromium removal from aqueous solutions using raw natural mixed clay from BURKINA FASO., I.Res.J.Environment Sci., 2(2), 30-37 (2013) @No $ @ @ Kini S.M., Saidutta M.B., Murty V.R.C. and Kadoli S.V., Adsorption of basic dye from aqueous solution using ACl treated saw dust (Lagerstroemia microcorpa): Kinetic , Modeling of Equilibrium,Thermodynamic.,     I. Res. J. Environment.Sci., 2(8), 6-16 (2013) @No $ @ @ Haq B.I.U., Elias N.B. and Khanam Z., Adsorption studies of Cr(VI) and Fe(II) aqua solution using rubber tree leaves,  I.Res.J.Environment.Sci., 2(12), 52-56 (2013) @No $ @ @ Nadaroglu H. and Kalkan E., Removal of cobalt(II) ions from aqueous solutions by using alternative adsorbent and us trial red mud waste material.l, Int.J.Phy.Sciences., , 1386-1394 (2012) @No $ @ @ Han S.W., Kim D.K., Hwang I.G. and Bae J.H., Development of Pellet-type Adsorbents for Removal of Heavy Metal Ions from Aqueous Solutions using Red Mud, J.Ind.Eng.Chem., 8(2), 120-125 (2002) @No $ @ @ Kim J.S., Han S.W., Hwang I.G.,Bae J.H. and Tokunaga S., Astudy on removal of Pb++ ion using pellet-type red mud adsorbents, Env.Eng.Res. 7(1), 33-37 (2002) @No $ @ @ Mobasherpour I., Salahi E. and Asjodi A., Research on the batch and fixed bed column performance of red mud adsorbents for lead removal, Canadian Chemical Transactions, 2(1), 83-96 (2014) @No $ @ @ Das B., Mondal N.K., Roy P. and Chatterji S., Equilibrium, Kinetic and Thermodynamic Study on chromium(VI) removal from aqueous solutions using Pistia Stratiotes Biomass, Chem Sci Trans., 2(1), 85-104 (2013) @No $ @ @ John C., Interpretation of Infrared Spectra, A Practical Approach, Encyclopedia of Analytical Chemistry, R.A. Heyers (Ed.), John Wiley & Sons Ltd. Chichester, 10815 – 10837 (2000) @No $ @ @ Ekrem Kalkan, et.al., .Bacteria – Modified Red Mud for Adsorption of Cadmium Ions from Aqueous Solutions, Pol.J.Environ. Stud., 22(2), 417 – 429 (2013) @No $ @ @ Tsai W.T. and Chen H.R., Removal of malachite green from aqueous solution using low-cost chlorella-based biomass, J Hazard Mater., 175(1-3), 844-849 (2010) @No $ @ @ Sarin V. and Pant K.K., Removal of chromium from industrial waste by using eucalyptus bark, Bioresource Technol., 97(1), 15-20 (2006) @No $ @ @ Wongjunda J. and Saueprasearsit P.,Biosorption of Chromium(VI) using rice husk ash and modified husk ash Environ Res. J., 4(3), 244-250 (2010) @No $ @ @ Brummer G.W., Importance of Chemical Speciation in Environmental Process (Springer Verlag, Berlin) (1986) @No $ @ @ Bello O.S., Olusegun O.A. and Nioku V.O., Fly ash-An alternative to powdered activated carbon for the removal of Eosin dye from aqueous solutions, Bull.Chem.Soc. Ethiop.,27(2), 191-204 (2013) @No $ @ @ Anirudhan T.S. and Radhakrishnan P.G., Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell, J.Chem.Thermodynamics., 40(4), 702-709 (2008) @No $ @ @ Lagergren S., About the theory of so-called adsorption of soluble substsnces, der Sogenanntenadsorption geloster stoffe Kungliga Svenska psalka de Miens Handlingar., 24, 1-39(1898) @No $ @ @ Ho Y.S. and Mckay G., The kinetics of sorption of divalent metal ions onto sphagnum moss peat., Water Res. 34(3), 735-742 (2000) @No $ @ @ Weber W.J. and Morris J.C., Kinetics of adsorption on carbon from solution, J. Saint. Eng. Div. Am. Soc. Eng.,  89, 31-60 (1963) @No $ @ @ Kumar P.S., Ramakrishnan K., Kirupha S.D and Sivanesan S. Thermodynamic and Kinetic studies of cadmium adsorption from aqueous solution onto rice husk, Braz.J.Chem.Eng., 27, 347 (2010) @No $ @ @ Arivoli S., Hema M., Karuppaiah M. and Saravanan S., Adsorption of chromium ion by acid activated low cost carbon-Kinetic,Mechanistic,Thermodynamic and Equilibrium studies, E-Journal of Chemistry., 5(4), 820-831(2008) @No $ @ @ Senthilkumar P., Ramalingam S., Sathyaselvabala V., Kirupha D.S. and Sivanesan S., Desalination, 266(1-3), 63-71 (2011) @No $ @ @ Nevine K.A., Removal of direct blue-106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics, J. Haz. Mat.., 165(1-3), 52-62 (2009) @No $ @ @ Singh Dhanesh.and Rawat N.S., Bituminous coal for the Removal of Cd rich water, Ind. J. Chem. Technol., , 266-270 (1994) @No $ @ @ Singh Dhanesh. and Rawat N.S., Sorption of Pb(II) by bituminous coal, Ind. J. Chem. Technol., , 49-50 (1995) @No 
<#LINE#>Measurement of Deexcitation Cross Sections of Ne(3P1) by CH4 Using a Pulse Radiolysis Method<#LINE#>Bahadur@KhadkaDeba<#LINE#>54-57<#LINE#>8.ISCA-RJCS-2014-040.pdf<#LINE#>Central Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu,NEPAL<#LINE#>13/2/2014<#LINE#>8/3/2014<#LINE#> The cross sections for the deexcitation of Ne(3P1)  by CH4  have been measured as a function of the mean  collisional energy in the range of 17.2-36.8 meV or  in the temperature range from 134 K to 285 K using a pulse radiolysis method as combined with time-resolved optical absorption spectroscopy.  The deexcitation cross sections are in the range of 10-24 Å for Ne() by CH. The behavior of the collisional energy dependence cross sections are increase slightly with increasing the collisional energy. The results are interpreted in terms of an electron –exchange interaction. <#LINE#> @ @ Hotop H. and Niehaus A., Reactions of  Excited Atoms and Molecules with Atoms and Molecules,  Z. Physik, 228, 68-88 (1969) @No $ @ @ Siska  P.E., Molecular Beam Studies  of Penning   Ionization,   Reviews of Modern Physics, 65(2), 337-412 (1993) @No $ @ @ Hatano Y., Electronic and atomic collision processes in ionized gases as studied by the pulse radiolysis method. In: Proceedings of 19th Int. Conf. on Phenomena in Ionized  Gases. (ed.)  Zigman, V.J.  Univ. Belgrade,  Czech Republic, 242-253  (1989) @No $ @ @ Hatano Y., Pulse radiolysis in the gas phase, In: Pulse Radiolysis, (ed.) Tabata Y.  CRC Press, Boca Raton, 199-217 (1991) @No $ @ @ Ukai M. and Hatano  Y.,  Deexcitation of excited rare gas atoms in metastable and resonance states as studied by the  pulse radiolysis method. In: Gaseous Electronics and Its Applications.  (ed.) Crompton, R. W., Hayashi, M. ,  Boyd, D. E.,  and Makabe, T.  KTR Scientific Publishers, Tokyo,  Japan, 51-83 (1991) @No $ @ @ Hatano Y., Collisional deexcitation of  excited rare gas atoms in the metastable and resonant states. In: Handbook of Hot Atoms Chemistry, (ed.) Adloff,  J.P.  Kodansha,  167-175 (1992) @No $ @ @ Brunetti B. and Vecchiocattivi F., Autoionization dynamics of collisional complexes.  In: Cluster Ions. (ed.)  Ng, C. Y.,  Baer, T.,  and Powis, I. John Wiley and Sons Ltd, New York,  USA, 359-438 (1993) @No $ @ @ Khadka D.B., Fukuchi Y., Kitajima M., Hidaka K., Kouchi  N., Hatano Y. and Ukai M., Deexcitation of  Ne()  and  Ne() in collisions with Ar, Kr, and Xe,  Journal of Chemical Physics,107(7), 2386-2394 (1997) @No $ @ @ Khadka D.B., Kouchi N. and Hatano Y., Temperature dependence deexcitation rate constants of Ne(3P1) by N2 Journal of Nepal Chemical Society, 17 – 18, 30-33 (1998-99) @No $ @ @ Fukuzawa H., Murata M., Kiyoto N., Mukai T., Fukuchi Y., Khadka D. B., Odagiri T., Kameta K., Kouchi  N. and Hatano Y.,  Collisional deexcitation of the excited rare gas atoms in resonant states: The Watanabe-Katsuura theory revisited,  Journal of Chemical Physics,118(1), 70-74 (2003) @No $ @ @ Khadka D.B., Pulse radiolysis studies of collisional deexcitation of Ne() by N,  Res. J. Chem. Sci.,4(3),  (2014) accepted for publication  @No $ @ @  Ohno K., Tanaka H., Yamakita Y., Maruyama R., Horio T. and  Misaizu F.,  Penning ionization electron spectroscopy of van der Waals clusters,  J. Electron  Spectrosc. Relat. Phenom.,112, 115-128 (2000) @No $ @ @ Yencha A.J., Ruf M.W. and Hotop H.,  Penning ionization electron spectroscopy of hydrogen iodide,  J. Phys. D, 29(3), 163-177 (1994) @No $ @ @ Khadka D. B., Deexcitation probabilities of Ne() by Ar for the case E  D, J. Nepal Chem. Soc., 24, 19-23 (2009) @No $ @ @ Khadka D. B., Deexcitation probabilities of Ne() by Xe for the case E  D, J. Nepal Chem. Soc.,  25, 70-74(2010) @No $ @ @ Khadka D. B., Calculation of deexcitation probability of Ne() by Ar for the case E &#x-3.3;å ¦&#x-3.3;å ¦ D,  J. Nepal Chem. Soc., 30, 52-55 (2012) @No $ @ @ Miller W. H., Theory of Penning ionization, J. Chem. Phys.,  52, 3563-3572 (1970) @No $ @ @ Zagrebin A. L. and Paviovskaya N. A., Radiatitive quenching of the metastable states of Ar, Kr, and Xe colliding with He and Ne atoms, Opt. Spektrosk., 66(4), 794-799 (1989) @No $ @ @ Srivastava R. K., Narayan V., Kumar A., Prasad O. and Sinha L., Theoretical studies on the isomers of Quinazolinone by first Principles, Res. J. Recent Sci., 1(3), 11-18 (2012) @No $ @ @ Onigbinde Adebayo O., Munson B. and Amos-Tautua Bamidele M.W., Structural identification of C + and  + ions obtained from Polyethylene Glycols and Polyethylene Glycol Dialkyl Ethers and other  sources using Chemical ionization and Fourier Transformation ion  Cyclotron Mass Spectrometry,   Res. J. Chem. Sci.,3(6), 3-9  (2013) @No $ @ @ Ramegowda M., Change in energy of Hydrogen bonds upon excitation of Coumarin 1: TDDFT/EFP1 method,  Res. J. Chem. Sci.,3(7), 25-30  (2013) @No $ @ @ Najumunnisa T., Musthafa M. and Mohamed Aslam P., Effect of angular momentum transfer on isomeric cross-section ratio, Res. J. Recent Sci.,   3(ISC-2013), 20-22 (2014) @No $ @ @ Kitajima, M., Hidaka, K., Kusumori, H., Ukai, M., Kouchi,  N., and Hatano, Y., Deexcitation of He(2P) in  a collision with Ne,  Journal of Chemical Physics,100(11), 8072-8079 (1994) @No $ @ @ Yokoyama A., Takao S., Ueno T. and Hatano Y.,    Measurements of deexcitation rate constants of Ne ( ,   and )  by N and SF using a pulse radiolysis method, Chemical Physics, 45, 439-446 (1980) @No 
<#LINE#>Synthesis of Medicinal Soap from Non Edible (Jatropha Oil) and Study of its Quality Parameters including Antimicrobial Activity<#LINE#>JuzerAli@Rangwala,Geetha@Sarasan<#LINE#>58-62<#LINE#>9.ISCA-RJCS-2014-041.pdf<#LINE#> Department of Chemistry, Holkar Science College, Indore, INDIA <#LINE#>13/2/2014<#LINE#>21/3/2014<#LINE#> In this research sample of soap was prepared by using Jatropha Oil (purchased from dealer) by adding concentrate caustic soda solution in appropriate temperature range. Crude sample was washed, dried and several parameters such as % yield, TFM value, Total Alkali Content, Free Caustic Alkali Content, pH, Solubility, CMC Value and Antimicrobial Activity were determined.  It was found that TFM value of Jatropha Soap is more than 60 %. According to BIS norms such soap can be categorized as Grade III Soap and it can be used for general bathing purpose. Also, Total Alkali Content,Free Caustic Alkali content,pH value etc. were found within prescribed value of BIS. CMC value of Jatropha Soap was around 0.012 M which shows that it can be used as a surfactant for purpose of micellar catalysis which is of great industrial significance owing to it’s cheap price. Surprisingly, Study of Antimicrobial activity on S.aureus revealed that Jatropha Soap has more bactericidal effect as compared to commercial antiseptic soap which indicates that Jatropha Oil can be utilized for production of high quality medicated soap. <#LINE#> @ @ Kulyal Poonam, Kanti Tiwari Uma, Shukla Arvind and K. Gaur Anil, Chemical constituents isolated from seed oil of Jatropha curcas, Asian J. Chem.,23, 7, 2939 – 2942 (2011) @No $ @ @ Warra. A,  Cosmetic potentials of physic nut (Jatropha curcas Linn.) seed oil: A review,  Am. J. Sci. Ind. Research3(6), 358-366 (2012) @No $ @ @ Holla K.S., Millwala R.H., Shitole A.D., Rajan N.S.S., Tallow substitute from Ratanjyot Oil (Jatropha curcas),‘Journal of Oil Technologists’ Association of India, 25(4), 75-77 (1993) @No $ @ @ Singh Rachana, Agarwal Tarun , Rastogi Rinki, Arora Neha, Rastogi Meghna, Comparative Analysis of Antibacterial Activity of Jatropha curcas Fruit Part,. J. Pharm. Biomed. Sci, 15(15), 1-4 (2012) @No $ @ @ Joshi Archana, Singhal Pankaj and Bachheti R. K. Physicochemical Characterization of Seed Oil of Jatropha curcasL., Collected from Dehradun (Uttarakhand) India, Int.J. Appl.Biol. Pharm.Technol., 2, 123-127 (2011) @No $ @ @ Akbar Emil, Yaakob Zahira, Kamarudin Kartom, Ismail Manal, Salimon Jumat, Characteristic and Composition of Jatropha curcas Oil Seed from Malaysia and its Potential as Biodiesel Feedstock, Eur.J. Appl. Eng. Sci.Res.,29,3, 396-403 (2009) @No $ @ @ The Chemistry Behind Jatropha Soap, Article adopted from www.virtualsciencefair.org. (2013) @No $ @ @ Mak-Mensah E.E. and Firempong C.K., Chemical characteristics of toilet soap prepared from neem (Azadirachta indica) seed oil,Asian J. Plant Sci. Res., 1(4), 1-7 (2011) @No $ @ @ Hautfenne, International Union of Pure and Applied Chemistry, Standard Methods For The Analysis Of Oils, Fats And Derivatives, 6th Edition, 1st Supplement: Part 5, Section IV,Alkaline Soaps (1982) @No $ @ @ Ogunniran K.O., Ajanaku K.O., James O.O., Ajani O.O., Adekoya J.A. and Nwinyi O.C., Synthesis, characterization, antimicrobial activity and toxicology study of some metal complexes of mixed antibiotics, Afr. J. Pure Appl. Chem.,2(7), 069-074 (2008) @No $ @ @ Ing J., Oremusová, CSc. and PharmDr. A. Lengyel : Critical Micelle Concentration Of   Ionic Surfactants By Conductometric Method  Article adopted from www.fpharm.uniba.sk (2013) @No $ @ @ Rawat M.K. and Sangeeta Studies on micellar properties of some Alkaline Earth metal Soaps, J.Ind.Council of Chemists, 23,1, 14-22 (2006) @No $ @ @ Janardhan K.R., Soaps and Detergents Article adopted from www.vigyanprasar.gov.in (2013) @No $ @ @ S.Antony Raja, D.S.Robinson smart, and C.Lindon Robert Lee, Res.J.chem.sci.,1(1), 81-87(2011) @No $ @ @ Ogunwole O.A. and Ogunwole O.A., Res.J. Chemical Sci., 2(11) (2012) @No
<#LINE#>Selective Recognition of Endosulfan Pesticide in Environmental Matrix with Molecularly Imprinted Polymer Membrane<#LINE#>K.P.@Singh,Ajeet@Kumar,Shweta@Tyagi,Rakesh@Singh,Prashant@Singh<#LINE#>63-70<#LINE#>10.ISCA-RJCS-2014-042.pdf<#LINE#>Membrane Biophysics Research Laboratory, C.B.S.H., G.B. Pant University of Agriculture and Technology, Pantnagar, Uttarakhand, INDIA @ Department of Chemistry, D.A.V. (P.G.) College, Dehradun, Uttarakhand, INDIA @ Department of Chemistry, D.B.S. (P.G.) College, Dehradun, Uttarakhand, INDIA<#LINE#>19/2/2014<#LINE#>24/3/2014<#LINE#> The excessive and uncontrolled uses of Endosulfan pesticide in crops have raised an alarm for its toxicity not only in crops but also in drinking water. So, it has become imperative to detect and separate the hazardous pesticide Endosulfan from contaminated water. In present studies, molecularly imprinted membrane has been fabricated for the specific recognition of Endosulfan pesticide, which is widely being used in controlling insects. The composite membranes have been prepared by using Methacrylic acid (MAA) as functional monomer and Ethylene Glycol Di Methyl Acrylate (EGDMA) as cross linker. MAA was chosen as a functional monomer, as it is capable of strong electrostatic interactions with Endosulfan. The molecular imprinting of Endosulfan on membrane matrix was confirmed by the Solid Phase Extraction (SPE), UV-Visible spectrophotometer, Fourier Transform Infra-Red (FTIR) Spectrophotometry and Scanning Electron Microscopy (SEM). This was followed by sensing of the herbicide by SPE measurements.  <#LINE#> @ @ Kuniuki S., Effects of organic fertilization and pesticide application on growth and yield of field-ground rice for 10 years, Jap. J. 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Sci., 4, 26-30 (2014) @No $ @ @ Our planet, our health, Report of the WHO commission on health and environment, World Health Organization, Geneva (1992) @No $ @ @ Andreescu S. and Marty J.L., Twenty years research in cholinesterase biosensors: From basic research to practical applications, Biomol Engg.,23, 1-15 (2006) @No $ @ @ Piletsky S.A., Panasyuk T.L., Piletskaya E.V., Receptor and transport properties of imprinted polymer membranes - A review, J. Membr. Sci.,157, 263-278 (1999) @No $ @ @ Sellergren B., Direct drug determination by selective sample enrichment on an imprinted polymer, Anal. Chem., 66, 1578-1582 (1994) @No $ @ @ Baggiani C., Anfossi L., Giovannoli C., Molecular imprinted polymers: useful tools for pharmaceutical analysis, Curr. Pharm. 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Ed.,50, 495-498 (2011) @No $ @ @ Zhao H., Chen Y., Tian J., Yu H., Quan X., Selectively electrochemical determination of chloramphenicol in aqueous solution using molecularly imprinted polymer-carbon nanotubes-gold nanoparticles modified electrode, J. Electrochem. Soc.,159, 231-236 (2012) @No $ @ @ Lord H. and Pawliszyn J., Evolution of solid-phase microextraction technology, J. Chromatogr. A, 885, 153-193 (2000) @No $ @ @ Berggren C., Bayoudh S., Sherrington D., Ensing K., Use of molecularly imprinted solid-phase extraction for the selective clean-up of clenbuterol from calf urine, J. Chromatogr. A,889, 105-110 (2000) @No $ @ @ Jodlbauer J., Maier N.M., Lindner W., Towards ochratoxin: A selective molecularly imprinted polymers for solid-phase extraction, J. Chromatogr. A,945, 45-63(2002) @No $ @ @ Matsui J., Fujiwara K., Ugata S., Takeuchi T., Solid-phase extraction with a dibutylmelamine-imprinted polymer as triazine herbicide-selective sorbent, J. Chromatogr. A,889, 25-31 (2000) @No $ @ @ Mullett W.M. and Lai E.P.C., Molecularly imprinted solid phase extraction micro-column with differential pulsed elution for theophylline determination, Microchem., 61, 143-155 (1999) @No $ @ @ Mullett W.M., Martin P., Pawliszyn J., In-tube moleculary imprinted polymer solid-phase microextraction for the selective determination of propranolol, Anal. Chem.,73, 2383-2389 (2001) @No $ @ @ Sellergren B., Polymer- and template-related factors influencing the efficiency in molecularly imprinted solid-phase extractions, Trac-Trends Anal. Chem.,18, 164-174(1999) @No $ @ @ Lorenzo A.R., Antonia M.C., Alvarez-Lorenzo C., Concheiro A., To remove or not to remove? The challenge of extracting the template to make the cavities available in molecularly imprinted polymers (MIPs), Int. J. Mol. Sci.,12, 4327-4347 (2011) @No 
<#LINE#>The Phase Evolution at High-Temperature Treatment of the Oxide-Fluoride Ceramic Flux<#LINE#>V.E.@Sokolsky,O.S.@Roik,A.O.@Davidenko,V.P.@Kazimirov,V.V.@Lisnyak,V.I.@Galinich,I.A.@Goncharov<#LINE#>71-77<#LINE#>11.ISCA-RJCS-2014-052.pdf<#LINE#> Chemical Department, Kyiv National Taras Shevchenko University, 01601 Kyiv, UKRAINE @ The E.O. Paton Electric Welding Institute of NAS of Ukraine, 03680 Kyiv, UKRAINE <#LINE#>7/3/2014<#LINE#>1/4/2014<#LINE#> The products of high temperature treatment of the oxide-fluoride ceramic flux of the composition MgO (30.0 mass. %) – Al (25.0 mass. %) – SiO (20.0 mass. %) – CaF (25.0 mass. %), which was obtained using liquid glass as a binder, were examined by means of X-ray powder diffraction (XRPD). The slag obtained by the ceramic flux remelting at 1773 K according to XRPD data contains MgAl, CaF and MgSiO4 phases. High temperature X-ray diffraction data (HTXRD), collected at heating regime, show that the initial components exist in the ceramic flux at temperatures (T)  1473 K. The partial melting of the ceramic flux is accompanied with formation of crystalline MgAl4 phase. Detail examination of the slag samples by means of scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) microanalysis confirms results of the XRPD and HTXRD studies.  <#LINE#> @ @ Yu D.W. and Devletian J.H., Electroslag Surfacing: A potential process for rebuilding and restoration of ship components, Proc. of the NSRP 1988 Ship Production Symp.,The society of naval architects and marine engineers (U.S.), Jersey City, 11A-1-18 (1988) @No $ @ @ Kuskov Yu.M., Penetration of the parent metal in electroslag surfacing in a current-supplying solidification mould, Weld. Int., 16, 48-50 (2002) @No $ @ @ Cary H.B. and Helzer S.C., Modern Welding Technology, Pearson/Prentice-Hall, Upper Saddle River, 6th Ed., 736 (2005) @No $ @ @ Podgaetskii V. and Lyuborets I., Welding fluxes, Naukova Dumka, Kiev, 165 (1978) @No $ @ @ Podgaetskii V. and Kuzmenko V., Welding Slags. A Handbook, Naukova Dumka,Kiev, 253 (1988) @No $ @ @ Wright S., Zhang L., Sun S. and Jahanshahi S., Viscosity of a CaO-MgO-Al-SiO melt containing spinel particles at 1646 K, Metall. Mater. Trans. , 31, 97-104 (2000) @No $ @ @ Nightingale S.A. and Monaghan B.J., Kinetics of spinel formation and growth during dissolution of MgO in CaO-Al-SiO slag, Metall. Mater. Trans. B, 39, 644-648 (2008) @No $ @ @ Park J.H., The effect of boron oxide on the crystallization behavior of MgAl spinel phase during the cooling of the CaO-SiO-10 mass.% MgO-30 mass.%Al systems, Met. Mater. Int., 16, 987-992 (2010) @No $ @ @ Park J.H., Solidification behavior of calcium aluminosilicate melts containing magnesia and fluorspar,  J. Am. Ceram. Soc., 89, 608-615 (2006) @No $ @ @ Park J.H., Solidification structure of CaO–SiO–MgO–Al(–CaF) systems and computational phase equilibria: Crystallization of MgAl spinel, CALPHAD, 31, 428-437 (2007) @No $ @ @ Sokolsky V.E., Roik A.S., Davidenko A.O., Kazimirov V.P., Lisnyak V.V., Galinich V.I. and Goncharov I.A., X-Ray diffraction and SEM/EDX studies on technological evolution of the oxide-fluoride ceramic flux for submerged arc-surfacing, . Min. Metall. Sect. B Metall., 48, 101-113 (2012) @No $ @ @ Kraus W. and Nolze G. Powder cell 3.2, Federal Institute for Materials Research and Testing (BAM), available online at: http://www.ccp14.ac.uk/ccp/web-mirrors/powdcell/a_v/v_1/powder/e_cell.html, (10.01.2012) (2012) @No $ @ @ Match! Phase Identification from Powder Diffraction, Crystal Impact, available online at http://www.crystalimpact.com/match/download.htm, (10.01.2012) (2012) @No $ @ @ Sokol'skii V.E., Kazimirov V.P. and Kuzmenko V.G., X-ray diffraction study of the multi component oxide systems, . Molec. Liq., 93, 235-238 (2001) @No $ @ @ Rooi Ping L., Azad A.-M. and Wan Dung T., Magnesium aluminate (MgAl) spinel produced via self-heat-sustained (SHS) technique, Mat. Res. Bull., 36, 1417-1430 (2001) @No 
@Review Paper
<#LINE#>Diverse Pharmacological aspects of Benzimidazole Derivatives: A Review<#LINE#>Enumula@Sreenivasulu,Anees@Pangal,Gazge@Muiz,Javed@A.Shaikh,Ahmed@Khursheed<#LINE#>78-88<#LINE#>12.ISCA-RJCS-2014-032.pdf<#LINE#> Dept. of Chemistry & Post Graduate Research Centre, Abeda Inamdar Sr. College of Arts, Science & Commerce, Camp, Pune – 411001, INDIA <#LINE#>6/2/2014<#LINE#>1/3/2014<#LINE#> Benzimidazole is the heterocyclic compound formed by the fusion of benzene and imidazole ring. Benzimidazole analogs are of great significant because of their various clinical applications and biological activity. Benzimidazoles are considered as an optimistic class of bioactive heterocyclic compounds that possesses a range of biological activities. The work in this article relates to benzimidazole as it is a versatile heterocycle possessing a wide spectrum of biological activities like antimicrobial, antiviral, antidiabetic, anticancer activity, numerous antioxidant, antiparasitic, antihelmintics, antiproliferative, antiHIV, anticonvulsant, anti-inflammatory, antihypertensive, antineoplastic, proton pump inhibitor and antitrichinellosis. Benzimidazoles possess significant biological activities likepotential antitumor agents, smooth muscle cell proliferation inhibitors and in various areas of chemistry. <#LINE#> @ @ Spasov A.A. and Yozhitsa I.N., Benzimidazole derivatives: spectrum of pharmacological activity and toxicological properties, J. Pharm. Chem., 33, 232-243 (1999) @No $ @ @ Mavrova A.T.S., Anichina K.K. and Vuchev D.I., Synthesis and antitrichinellosis activity of some 2-substituted-[1,3]thiazolo[3,2-a]benzimidazol-3(2H)-ones, Bioorg. Med. 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Synthesis and anti-bacterial activity of some novel 2-(6-fluorochroman-2-yl)-1-alkyl/acyl/aroyl-1H-benzimidazoles, Eur. J. Med. Chem.,41, 599604 (2006) DOI PMid:16527375 @No $ @ @ JT Leonard; L Jeyaseeli; M Kumar; R Sivakumar. Synthesis, anti-inflammatory and antibacterial activities of 4-substituted phenyl benzimidazoles, Asian J. Chem, 18, 1104-1106 (2006) @No $ @ @ Deshmukh M.B., Suryavanshi A.W., Deshmukh S.A., Jagtap S.A., Microwave assisted synthesis of 2,3,4-trisubstituted 1,2- dihydropyrimido-[1,2-]benzimidazole, Ind. J. Chem., 86B, 302-305 (2009) @No $ @ @ KF Ansari; C Lal. ‘Synthesis and evaluation of some new benzimidazole derivatives as potential antimicrobial agents’, Eur. J. Med. Chem., 44, 2294-2299 (2009) @No $ @ @ Kazimierczuk Z., Upcroft, J.A., Upcroft, P., Gorska, A., Starosciak, B., Laudy, A., Synthesis, antiprotozoal and antibacterial activity of nitro- and halogeno-substituted benzimidazole derivatives, Acta Biochim. 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Substituted benzimidazoles: anti-viral activity and synthe-sis of nucleosides. ARKIVOC iii: 225- 250(2009) @No $ @ @ R. V. Devivar, E. kawashima, Benzimidazole ribonucleosides: design,synthesis, and antiviral activity of certain 2-(alkylthio)-and 2-(benzylthio)-5,6-dichlro-1-(d-ribofuranosyl)benzimidazoles, J. Med. Chem., 37, 2942-2949(1994) @No $ @ @ Pandey, V.K., Shukla, A., Synthesis and biological activity of isoquinolinyl benzimidazoles, Ind. J. Chem., 38B, 1381(1999) @No $ @ @ Yadav, L. D. S., Pal, D.R., Synthesis and antiviral activity of new 1,3,4-dithi(thiadi)azino(4,5-a) benzimidazole derivatives involving oxidative N-S and N-N bond formations, Ind. J. Chem. 35B, 111(1996) @No $ @ @ Kristina S., Marijeta M., Katja E., Ivan S., Magdalena G., Kresimir P., Grace, K. Z., Synthesis, antiviral and antitumor activity of 2-substituted-5-amidino-benzimidazoles, Bioorg. Med. Chem. 15, 4419-4422(2007) @No $ @ @ Bishnoi A., Pandey V. 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Bhattacharjee., Efficacy of Proton Pump Inhibitor Drugs against Plasmodium falciparum In Vitro and Their Probable Pharmacophores,  Antimicrob. Agent Chemother., 46(8), 2627-32 (2002) @No $ @ @ G. Sachs, E. Carison & P. Lindberg., Gastric H,K-ATPASE as Therapeutic Target, Annual Review of Pharmacology and Toxicology, 28, 269-284 (1988) @No $ @ @ B.Wallmark & O.Lorentzon,J. Gastroenterol,The mechanism of action of omeprazole--a survey of its inhibitory actions in vitro, Scand J Gastroenterol Suppl.20(108), 37-51(1985) @No $ @ @ H.Larsson & E. Carlson, Inhibition of gastric acid secretion by omeprazole in the dog and rat, J. Gastroenterol., 85(4), 900-907 (1983) @No $ @ @ V. Figala, K. Klemm & B. Kohl., Acid activation of (H+–K+)-ATPase inhibiting 2-(2-pyridylmethyl-sulphinyl)benzimidazoles: isolation and characterization of the thiophilic ‘active principle’ and its reactions, J. Chem. Soc., Chem. Commun., , 125-127 (1986) @No $ @ @ Lindberg P, Nordberg  P, Alminger T, Brändström A, Wallmark B., The mechanism of action of the gastric acid secretion inhibitor omeprazole, 29(80), 13271329 (1986) @No $ @ @ JB Bariwal; AK Shah; MK Kathiravan; RS Somani; JR Jagtap; KS Jai ‘Synthesis and antiulcer activity of novel pyrimidylthiomethyl and Pyrimidylsulfinylmethyl benzimidazoles as potential reversible proton pump inhibitors’, Ind. J. Pharm. Ed. Res., 42, 225-231 (2008) @No $ @ @ JS Shukla; S Saxena; R Rastogi, Synthesis of some newer, 1-heterocyclic amino/iminomethyl-2-substituted benzimidazoles as a potent CNS, anticonvulsant and monoamine oxidase inhibitory agents,  Curr. Sci., 51(17), 820-822 (1982) @No $ @ @ Mavrova AT, Anichina KK, Vuchev DI, Issenov JA, Denkova PS, Kondeva MS, Micheva MK ,Antihelminthic activity of some newly synthesized 5(6)-(un)substituted-1H-benzimidazol- 2-ylthioacetylpiperazine derivatives, Eur J Med Chem, 41,1412–1420 (2006) @No $ @ @ Lopez-Vallezo F, Medina-Franco JS, Hernandez-Campos A, Rodriguez- Morales S, Yepez L, Cedillo R, Castillo R Molecular modeling of some 1H-benzimidazole derivatives with biological activity against Entamoeba histolytica: a comparative molecular field analysis study, Bioorg Med Chem, 15,1117–1126(2007) @No $ @ @ Croft S. L., Yardley V., Chemotherapy of leishmaniasis, Curr. Pharm. Des., 8(4), 319-342 (2002) @No $ @ @ R.R. Tidwell, S.K. Jones, N.A. Naiman, L.C. Berger, W.B. Brake, C.C. Dykstra, J.E. Hall, Activity of cationically substituted bis-benzimidazoles against experimental Pneumocystis carinii pneumonia, Antimicrobial Agents and Chemotherapy, 37(8), 1713-1716 (1993) @No $ @ @ D. W. Boykin, A. Kumar, J. Spychala, M. Zhou, R. Lombardy, W. D. Wilson, C. C. Dykstra, S. K. Jones, J. E. Hall, R. Tidwell, C. Laughton, C. M. Nunn & S. Neidle, Dicationic diarylfurans as anti-Pneumocystis carinii agents, J. Med. Chem., 38(6), 912-916 (1995) @No $ @ @ Cushion M. T.; Walzer P. D.; Ashbaugh A.; Rebholz S.; Brubaker R.; Vanden E. J. J.;Mayence A.; Huang T. L., In vitro selection and in vivo efficacy of piperazine- and alkanediamide-linked bisbenzamidines against Pneumocystis pneumonia in mice, Antimicrob Agents Chemother, 50(7), 2337-43 (2006) @No $ @ @ A. Mayence, E.J. Vanden, L. LeCour, L.A. Walker, B.L. Tekwani & T.L. Huang, Piperazine-linked bisbenzamidines: a novel class of antileishmanial agents, Eur. J. Med. Chem., 39(6), 547-553 (2004) @No $ @ @ T.G. Hector, E.H. Nunez, I.L. Rivera & J.G Alvarez., Design, synthesis and in vitro antiprotozoal activity of benzimidazole-pentamidine hybrids, Bioorg. Med. Chem. Lett., 18(110), 3147-51 (2008) @No $ @ @ A.T.Mavrova, K. K. Anichina, D. I. Vuchev, J.A. Tsenov, P.S. Denkova, S. Kondeva Magdalena & M.K. Micheva, Antihelminthic activity of some newly synthesized 5(6)-(un)substituted-1H-benzimidazol-2-ylthioacetylpiperazine derivatives, Eur. J. Med. Chem., 41(12), 1412-20 (2006) @No $ @ @ Kumar D, Jacob MR, Reynolds MB, Kerwin SM Synthesis and evaluation of anticancer benzoxazoles and benzimidazoles related to UK-1, Bioorg Med Chem, 10(12), 3997–4004 (2002) @No $ @ @ Vedula MS, Pulipaka AB, Venna C, Chintakunta VC, Jinnapally S, Kattuboina VA, Vallakati RK, Basetti V, Akella V, Rajgopal S, Reka AK, Teepireddy SK, Mamnoor PK, Rajagopalan R, Bulusu G, Khandelwal A, Upreti VV, Mamidi SR New styryl sulfones as anticancer agents, Eur J Med Chem, 38(9), 811–824 (2003) @No $ @ @ Ramla MM, Omar MA, Tokuda H, El-Diwani HI Synthesis and inhibitory activity of new benzimidazole derivatives against Burkitt’s lymphoma promotion, Bioorg Med Chem,15(19), 6489–6496 (2007) @No $ @ @ Hranjec, M., Starcevic, K., Pavelic, S.K., Lucin, P., Pavelic, K., Zamola, G.K., Synthesis, spectroscopic characterization and antiproliferative evaluation in vitro of novel Schiff bases related to benzimidazoles, Eur. J. Med. 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Chem., 45(7), 2949-60 (2010) @No $ @ @ BB Kumar,  PV Rao, Synthesis and structural studies on transition metal complexes derived from 1-(2-thienyl)-1-ethanole-1-benzimidazole, Asian J. Chem., 18, 3060-3064(2006) @No
<#LINE#>Methods of Decontamination of Toluene Di-Isocyanate (TDI) spills and leftovers<#LINE#>SureshBabu@KV,RamaTeja@AS,N@SrinivasBabu,V@Arunachalam,Maheswar@CVS,Audisesha@ReddyK<#LINE#>89-93<#LINE#>13.ISCA-RJCS-2014-039.pdf<#LINE#> Satish Dhawan Space Center, SHAR Centre, Sriharikota, Andhra Pradesh– 524124, INDIA<#LINE#>10/2/2014<#LINE#>21/3/2014<#LINE#> TDI (Toluene Di-Isocyanate) is widely used in the production of polyurethanes and it is to be handled carefully due to its toxic effects on the human health and environment. TDI spills and leftovers are to be treated with extreme care in order to avoid human exposure to the toxic gases and wastes. It is necessary to neutralize or convert the reactive isocyanate groups of the spills or leftover of TDI into harmless compounds. This report elaborately describes the effects of TDI on human health and also the reactions of TDI with important functional groups and chemicals like amines, alcohols and water. This report also brings out the neutralization methods available for treatment of the minor spills and leftover of TDI.  <#LINE#> @ @ Hepburn C., Polyurethane Elastomers, Second Edition, Elsevier Science Publishing Co., ISBN No. 1-8516-6589-7 (1991) @No $ @ @ Robert P. Streicher, Christopher M. Reh, Rosa Key Schwartz, Paul C Schlecht, Mary Ellen Cassinelli, Determination of Airborne Isocyanate Exposure, NIOSH Manual of Analytical Methods, 115–140 (1998) @No $ @ @ Mary Jo Reilly, Kenneth D. Rosenman John H. Peck, Work- Related Asthma from exposure to isocyanate  levels below the michigan OSHA permissible limit, Isocyanates, sampling Analysis and Health effects, STP 1408, ASTM, ISBN No. 0-8031-2879-7 (2002) @No $ @ @ Michael Szycher, Szycher’s Handbook of Polyurethanes, Second Edition, CRC Press, ISBN No.1-4398-6313-8 (2012) @No $ @ @ Das Bakul, T.V. Ramana Reddy, M.T.K. Balaji and T. Veera Reddy, Development of Eco-friendly Neutralizing Agents for Toluene Diisocyanate, Research Journal of Chemical Sciences,  3(5), 7–11 (2013) @No $ @ @ One Step Ahead, Product Stewardship Handbook for Africa, ISOPA Guidelines, (2000) @No $ @ @ Dow VORANATE™ T – 80 Toluene Diisocyanate Safe Handling and Storage Guide, (2010) @No $ @ @ Kathy Kiestler, Effeciencies of Various Formulations of Decontamination Solutions Utilizing Toluene Diisocyanate, Polyurethanes Expo, 473-476 (1999) @No $ @ @ Isocyanates in Industry, WORKSAFE Bulletin, Workers’ Compensation Board of British Columbia, (2010) @No $ @ @ Safe Work Procedures for Isocyanate Containing Products, IATSE Local 891, (2000) @No $ @ @ Material Safety Data Sheet, MONDUR TD 80, MSDS No. 112000032041, Bayer Material Science (2014) @No $ @ @ Veera Reddy T, Bakul Das, T.V. Ramana Reddy, Studies on Feasibility of water and sodium carbonate solution as decontaminant for disposal of Toluene Diisocyanate waste, International Journal of Chemical Science, 10(4), 1959–1968 (2012) @No $ @ @ Veera Reddy T. and Bakul Das, Neutralization of Toluene Diisocyanate Spillage – A threat to our Ecosystem, International Journal of Research in Chemistry and Environment, 2(4), 125–129 (2012) @No $ @ @ Guidelines for Safe Loading/Unloading, Transportation and Storage of TDI and MDI in bulk, ISOPA Guidelines (2006) @No 
<#LINE#>Organic Agricultural Crop Nutrient<#LINE#>Pawan@Malik,Minkashi#Verma<#LINE#>94-98<#LINE#>14.ISCA-RJCS-2014-046.pdf<#LINE#> Department of Chemistry, SLBawa DAV College, Batala (Dist.Gsp), Punjab, INDIA<#LINE#>28/2/2014<#LINE#>24/3/2014<#LINE#> Organic agriculture is farming without the use of pesticides, herbicides, fungicides etc. To maintain the better nutrient management in organic farming, there are various factors which support nutrient supply to plants either by recycling or proper management of biologically related phenomena such as limited use of slowly soluble off farm materials. Regenerative agriculture is a dynamically advanced modified techniques involving use of organic farming methods. Basic idea of organic farming is the minimum use of nonrenewable resources such as fossil fuel used for manufacture of fertilizers. The excessive use of fertilizers containing nitrogen in farming cause a serious and havoc damage to the ecosystem. In the present study, an attempt has been made to focus on the long term goal to help and maintain sustainable farming by adopting new techniques and save our environment by avoiding the overuse of fertilizers. The study concluded that these practices not only prevent pollution but also maintaining nature over ecological balance. Sustainable organic farming providing enormous environmental benefits. So, organic agriculture is eco-friendly, improve soil fertility and sustain high yield. <#LINE#> @ @ Pierre A and Ian, Liu et al., Seng, (2010) @No $ @ @ Elizabeth, Ryan, and Amy (2004) @No $ @ @ Elizabeth, et al., Sununtar (2006) @No $ @ @ Suthamathy N. and Seran T.H., Residual effect of organic manure EM Bokashi applied to proceeding crops of vegetable cowpea on succeeding crop of radish, Res.J.Agriculturre and forestry Sci.,), 2-5 (2013) @No $ @ @ www.enviropacinc.com (2013) @No $ @ @ www.gandlseedtreaters (2013) @No $ @ @ www.cytozyme.com (2013) @No $ @ @ www.amway.com (2013) @No $ @ @ www.ams.usda.gov (2013) @No $ @ @ Getproductsupport.net (2013) @No $ @ @ www.midwestagriculturesolutions.com (2013) @No $ @ @ Myleso O., Henning H.J., Lucimer S. Abreu, Gustavo F, Almeido Ahmed EI Araby, Qiao Yu Hui, A comparative study of farm nutrient flow of certified organic and non-organic farm, Nutr Cycl Agroecosyst, 87, 455-470 (2010) @No $ @ @ Wikipedia.org (2013) @No $ @ @ Singh R., Kumar S.S. and Mishra U.K., Emerging trends in agricultural, Res. J.Recent. Sci., ), 36-38 (2013) @No 
@Case Study
<#LINE#>Hydrochemistry of Groundwater in and around Chennai, India - A Case Study<#LINE#>A.@Annapoorani,A.@Murugesan,Ramu@A.,N.G.@Renganathan<#LINE#>99-106<#LINE#>15.ISCA-RJCS-2014-027.pdf<#LINE#> Department of Chemistry, Vel Tech Multi Tech Dr RR, Dr SR Engineering College, Avadi, Chennai-600 062, TN, INDIA @ Department of Chemistry, Sriram Engineering College, Perumalpattu, Veppampattu RS, Chennai-602 024, TN, INDIA @ School of Chemistry, Madurai Kamaraj University, Madurai – 625 021, TN, INDIA @ Department of Chemistry, Vel Tech Dr RR, Dr SR Technical University, Avadi, Chennai – 600 062, TN, INDIA<#LINE#>2/2/2014<#LINE#>10/3/2014<#LINE#> Groundwater quality in and around Chennai is to be known prior to its utility for the survival. With this objective, 240 samples from 60 places were collected in and around Chennai. The analysis and classification is stipulated by international standards. Hydro-chemical and statistical analysis were carried out to assess the groundwater quality. The physico-chemical parameters, sodium / chloride ratio, chloride / bicarbonate ratio, calcium / magnesium ratio are used to identify the intrusion of salt water in the coastal aquifers.  Calcium / Sodium ratio is used to identify the hard rock interaction or sedimentary rock interaction.  From the study, it is concluded that, groundwater in Chennai is a threat under the saltwater intrusion. The anthropogenic activity is a key factor for seawater intrusion and contamination.  <#LINE#> @ @ Chidambaram S., Sumar G.S., Prasanna M.V., Peter A.J., Ramanthan A.L. and Srinivasamoorthy, A study on the hydrogeology and hydrogeochemisty of groundwater from different depths in a coastal aquifer: Annamalai Nagar: TamilNadu, India, Environmental Geology, 57(1), 59-73 (2008) @No $ @ @ Sankaran S., Sonkamble S., Krishnakumar K. and Mondal N.C., Integrated approach for demarcating subsurface pollution and saline water intrusion zones in SIPCOT area: a case study from Cuddalore in Southern India, Environ Monit Assess, 184, 5121-5138 (2012) @No $ @ @ Suresh Babu D.S., Hindi E.C., Da Rosa Filho E.F. and Bittencourt AVL., Characteristics of valadares Island Aquifer,  Paranagua coastal Plain, Brazil, Environmental Geology, 41, 954-959 (2002) @No $ @ @ Malini S., Nagaiah N., Paramesh L., Venkataramaiah P. and Balasubramanian A.,  Groundwater quality around Mysore, Karnataka, India, International Journal of Environmental Studies, 60, 87-98 (2003) @No $ @ @ Rajmohan N. and Elango L., Hydrogeochemistry and its relation to groundwater level fluctuation in the Palar and Cheyyar river basins, southern India, Hydrogeological Processes, 20, 2415-2427 (2006) @No $ @ @ Krishna Kumar S., Chandrasekar N., Seralathan P., Prince S Godson and Magesh N.S., Hydrogeochemical study of shallow carbonate aquifers, Rameswaram Island, India, Environmental Monit. Assess, 184, 4127-4138 (2012) @No $ @ @ Venugopal T., Giridharan L., Jayaprakash  M. and Periakali P., Environmental impact assessment and seasonal variation study of the groundwater in the vicinity of River Adyar, Chennai, India, Environmental Monitoring and Assessment, 149, 81-97 (2009) @No $ @ @ Deshpande S.M. and Aher K.R., Evaluation of groundwater quality and its suitability for drinking and agriculture use in parts of Vaijapur District, Aurangabad, MS, India, Research Journal of Chemical Sciences, 2(1),25-31 (2012) @No $ @ @ Vaishnav M.M. and Dewangan S., Assessment of water Quality status in Reference to statistical parameters in different aquifers of Balco Industrial area, Korba, C.G, India, Research Journal of Chemical Sciences, 1(9), 67-72 (2011) @No $ @ @ Balakrishnan A.,  Ramu A. and Murugesan A., Assessment of Heavy Metal Distribution in Groundwater in and around Gulf of Mannar Seashore Area Using GIS Technique, Research Journal of Chemical Sciences, 4(1), 9-16 (2014) @No $ @ @ Shib Abir, Seasonal Variations in Physico-Chemical Characteristics of Rudrasagar Wetland-A Ramsar Site, Tripura, North East, India, Research Journal of Chemical Sciences, 4(1), 31-40 (2014) @No $ @ @ Matini L. Tathy C. and Moutou J.M., Seasonal Groundwater Quality Variation in Brazzaville, Congo, Research Journal of Chemical Sciences, 2(1), 7-14 (2014) @No $ @ @ Todd D.K., Groundwater hydrology (2nd Edition) New York: Wiley (1980) @No $ @ @ Sukhija B.S., Varma V.N., Nagabhushanam P. and Reddy D.V., Differentiation of paleomarine and modern seawater intruded salinities in coastal groundwaters (of Karaikal and Tanjavur, India) based on inorganic chemistry, organic biomarker fingerprints and radiocarbon dating, Journal of Hydrology, 174, 173-201 (1996) @No $ @ @ Sexana V.K., Singh V.S., Mondal N.C. and Jain S.C., Use of chemical parameters to delineation fresh groundwater resources in Potharlanka Island, India, Environmental Geology, 44(5), 516-521 (2003) @No $ @ @ Beddows P.A., Smart P.L., Whitaker F.F. and Smith S.L., Decoupled fresh-saline groundwater circulation of a coastal carbonate aquifer: Spatial patterns of temperature and specific electrical conductivity, Journal of Hydrology, 346, 18-32 (2007) @No $ @ @ Sarwade D.V., Nandakumar M.V.,  Kesari M.P., Mondal N.C., Singh V.S. and Singh B., Evaluation of seawater ingress into an Indian Attoll, Environmental Geology, 52(2), 1457-1483 (2007) @No $ @ @ Kim K.Y. Park Y.S. Kim G.P. and Park K.H., Dynamic freshwater-saline water interaction in the coastal zone of Jeju Island, South Korea, Hydrogeology Journal, 17, 617-629 (2009) @No $ @ @ Rabinove C.L. Longford R.H. and Brookhart J.W., Saline water resources of north Dakota (p 364) Us Geographical Survey Water Supply, Paper 1418 (1958) @No $ @ @ Giridharan L., Venugopal T. and Jayaprakash M., Assessment of water quality using chemometric tools: A case study of river cooum, South India, Arch Environ Contam Toxicol, 56, 654-669 (2009) @No $ @ @ Rengarajan R. and Balasubramanian A., Corrosion and Scale formation characteristics of groundwater in and around Nangavalli, Salem District, Tamil nadu, J.Applied Hydrology, 3(2), 10-18 (1990) @No