5th International Young Scientist Congress (IYSC-2019).  International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Selective Recognition of Endosulfan Pesticide in Environmental Matrix with Molecularly Imprinted Polymer Membrane

Author Affiliations

  • 1Membrane Biophysics Research Laboratory, C.B.S.H., G.B. Pant University of Agriculture and Technology, Pantnagar, Uttarakhand, INDIA
  • 2 Department of Chemistry, D.A.V. (P.G.) College, Dehradun, Uttarakhand, INDIA
  • 3 Department of Chemistry, D.B.S. (P.G.) College, Dehradun, Uttarakhand, INDIA

Res.J.chem.sci., Volume 4, Issue (4), Pages 63-70, April,18 (2014)

Abstract

The excessive and uncontrolled uses of Endosulfan pesticide in crops have raised an alarm for its toxicity not only in crops but also in drinking water. So, it has become imperative to detect and separate the hazardous pesticide Endosulfan from contaminated water. In present studies, molecularly imprinted membrane has been fabricated for the specific recognition of Endosulfan pesticide, which is widely being used in controlling insects. The composite membranes have been prepared by using Methacrylic acid (MAA) as functional monomer and Ethylene Glycol Di Methyl Acrylate (EGDMA) as cross linker. MAA was chosen as a functional monomer, as it is capable of strong electrostatic interactions with Endosulfan. The molecular imprinting of Endosulfan on membrane matrix was confirmed by the Solid Phase Extraction (SPE), UV-Visible spectrophotometer, Fourier Transform Infra-Red (FTIR) Spectrophotometry and Scanning Electron Microscopy (SEM). This was followed by sensing of the herbicide by SPE measurements.

References

  1. Kuniuki S., Effects of organic fertilization and pesticide application on growth and yield of field-ground rice for 10 years, Jap. J. Crop Sci.,70, 530-540 (2001)
  2. Dobhal R., Uniyal D.P., Singh P., Tyagi S., Sharma B., Singh R., Pesticides management in surface and ground waters in India, Int. J. Sci. Tech. Manag., 2, 8-17 (2011)
  3. Kihampa C. and Wenaty A., Impact of mining and farming activities on water and sediment quality of the Mara river basin, Tanzania, Res. J. Chem. Sci., 3, 15-24 (2013)
  4. Sharma B., Tyagi S., Singh R., Singh P., Monitoring of organochlorine pesticides in fresh water samples by gas chromatography and bioremediation approaches, Natl. Acad. Sci. Lett.,35, 401-413 (2012)
  5. Mahajan S. and Billore D., Assessment of physico-chemical characteristics of the soil of Nagchoon pond Khandwa, MP, India, Res. J. Chem. Sci., 4, 26-30 (2014)
  6. Our planet, our health, Report of the WHO commission on health and environment, World Health Organization, Geneva (1992)
  7. Andreescu S. and Marty J.L., Twenty years research in cholinesterase biosensors: From basic research to practical applications, Biomol Engg.,23, 1-15 (2006)
  8. Piletsky S.A., Panasyuk T.L., Piletskaya E.V., Receptor and transport properties of imprinted polymer membranes - A review, J. Membr. Sci.,157, 263-278 (1999)
  9. Sellergren B., Direct drug determination by selective sample enrichment on an imprinted polymer, Anal. Chem., 66, 1578-1582 (1994)
  10. Baggiani C., Anfossi L., Giovannoli C., Molecular imprinted polymers: useful tools for pharmaceutical analysis, Curr. Pharm. Anal.,2, 219-247 (2006)
  11. Lanza F. and Sellergren B., The application of molecular imprinting technology to solid phase extraction,Chromatogr., 53, 599-611 (2001)
  12. Tamayo F.G., Turiel E., Martin-Esteban A., Molecularly imprinted polymers for solid-phase extraction and solid-phase microextraction: recent developments and future trends, J. Chromatogr. A, 1152, 32-40 (2007)
  13. Wulff G. and Sarhan A., Use of polymers with enzymeanalogous structures for the resolution of racemates, Angew. Chem. Int. Ed. Engl.,11, 341-344 (1972)
  14. Arshady R. and Mosbach K., Synthesis of substrate-selective polymers by host–guest polymerization, Macromol. Chem. Phys., 182, 687-692 (1982)
  15. Allender C.J., Brain K.R., Heard C.M., Binding cross-reactivity of boc-phenylalanine enantiomers on molecular imprinted polymers, Chiral., 9, 233-237 (1997)
  16. Ensing K. and Boer de T., Theoretical considerations for the application of molecular imprints for chemical analysis, Trends Anal. Chem., 18, 138-145 (1999)
  17. Mosbach K., Yu Y., Andersch J., Ye L., Generation of new enzyme inhibitors using imprinted binding sites: the anti-idiotypic approach, a step toward the next generation of molecular imprinting, J. Am. Chem. Soc.,123, 12420-12421 (2001)
  18. Sellergren B. and Buechel G., A porous, molecularly imprinted polymer and preparation, PCT Int. Appl., (1999)
  19. Nematollahzadeh A., Sun W., Aureliano C.S.A., Lutkemeyer D., Stute J., Abdekhodaie M.J., Shojaei A., Sellergren B., High-capacity hierarchically imprinted polymer beads for protein recognition and capture, Angew. Chem. Int. Ed.,50, 495-498 (2011)
  20. Zhao H., Chen Y., Tian J., Yu H., Quan X., Selectively electrochemical determination of chloramphenicol in aqueous solution using molecularly imprinted polymer-carbon nanotubes-gold nanoparticles modified electrode, J. Electrochem. Soc.,159, 231-236 (2012)
  21. Lord H. and Pawliszyn J., Evolution of solid-phase microextraction technology, J. Chromatogr. A, 885, 153-193 (2000)
  22. Berggren C., Bayoudh S., Sherrington D., Ensing K., Use of molecularly imprinted solid-phase extraction for the selective clean-up of clenbuterol from calf urine, J. Chromatogr. A,889, 105-110 (2000)
  23. Jodlbauer J., Maier N.M., Lindner W., Towards ochratoxin: A selective molecularly imprinted polymers for solid-phase extraction, J. Chromatogr. A,945, 45-63(2002)
  24. Matsui J., Fujiwara K., Ugata S., Takeuchi T., Solid-phase extraction with a dibutylmelamine-imprinted polymer as triazine herbicide-selective sorbent, J. Chromatogr. A,889, 25-31 (2000)
  25. Mullett W.M. and Lai E.P.C., Molecularly imprinted solid phase extraction micro-column with differential pulsed elution for theophylline determination, Microchem., 61, 143-155 (1999)
  26. Mullett W.M., Martin P., Pawliszyn J., In-tube moleculary imprinted polymer solid-phase microextraction for the selective determination of propranolol, Anal. Chem.,73, 2383-2389 (2001)
  27. Sellergren B., Polymer- and template-related factors influencing the efficiency in molecularly imprinted solid-phase extractions, Trac-Trends Anal. Chem.,18, 164-174(1999)
  28. Lorenzo A.R., Antonia M.C., Alvarez-Lorenzo C., Concheiro A., To remove or not to remove? The challenge of extracting the template to make the cavities available in molecularly imprinted polymers (MIPs), Int. J. Mol. Sci.,12, 4327-4347 (2011)