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Comparative Thermokinetics Study of Terpolymeric Resins derived from p-Hydroxyacetophenone, Resorcinol and Glycerol

Author Affiliations

  • 1 Department of Chemistry, Institute of science, Nagpur, MS, INDIA
  • 2 Department of Chemistry, Arts, Commerce and Science College, Arvi, Dist. Wardha, MS, INDIA V.N.I.T., Nagpur, MS, INDIA

Res.J.chem.sci., Volume 4, Issue (2), Pages 81-86, February,18 (2014)

Abstract

The terpolymeric resins abbreviated as PARG-I and PARG-II were synthesized by polyphosphoric acid (PPA) catalyzed polycondensation of p-hydroxyacetophenone, resorcinol and glycerol in 1:1:3 and 2:1:4 molar proportions respectively. The resins were characterized by various physico-chemical methods such as elemental analysis, IR, 1H NMR, UV-Vis and non-aqueous conduct metric titration. The thermokinetic parameters were determined using Freeman-Carroll and Sharp-Wentworth methods. The order of degradation was determined by FC method and confirmed by SW method.

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