@Research Paper <#LINE#>Hydrothermal Synthesis and Characterization of Zeolite: Effect of Crystallization Temperature<#LINE#>Deepesh@Bhardwaj,Radha@Tomar,S.Purnima@Khare,Goswami@Yogesh,Pankaj@Srivastva<#LINE#>1-4<#LINE#>1.ISCA-RJCS-2013-036.pdf<#LINE#>Institute of Information Technology and Management, Gwalior-474001, INDIA @ School of Studies in Chemistry, Jiwaji University, Gwalior, INDIA @ Dept of Physics, RGPV, Bhopal, INDIA Dept of Physics, ITM University, Gwalior, INDIA @ Dept. of Applied Physics, IIITM, Gwalior, INDIA <#LINE#>6/3/2013<#LINE#>14/7/2013<#LINE#>The synthesis and characterization of zeolites designed for the removal of pesticide, radioactive waste and as slow release fertilizer is described. The zeolites were hydro thermally synthesized by varying the concentrations of Si and Al at different crystallization temperature between 75°C to 150°C. Different instrumental techniques viz. X-ray diffraction, FTIR, SEM, EDS, TEM and TGA were used to characterize the product obtained at different synthesis parameters. The broad and sharp peaks obtained in diffractogram shows the amorphous and crystalline nature of the materials respectively. The composition of SZM was found approximately close to the concentrations of the precursors taken during synthesis. The FTIR spectra of these zeolites in framework vibration region also shows sharp feature for zeolites in the 500-650cm-1. High crystalline nature of the material is reveals by the absorption bands at 520-570 cm-1. The synthesized zeolites were used for the sorption studies for malathion, Pd(II), Ru(III) and plant nutrient Nitrate.<#LINE#> @ @ Breck D.W., Zeolite Molecular Sieves, Chemistry and Use; Wiley: New York, USA, (1974) @No $ @ @ Camblor M. A., Corma A. and Valencia S., Synthesis in fluoride media and characterisation of aluminosilicate zeolite beta, J. Mater. Chem.,, 2137-2145 (1998) @No $ @ @ Flanigen E.M., Khatami H., Seymenski H.A., Adv. Chemistry Series 101, in: E.M. Flanigen, L.B. Sand (Eds.), American Chemical Society, Washington, DC, 201–228 (1971) @No $ @ @ Mintova S., Valtchev V., Onfroy T., Marichal C., Knozinger H., and Bein T., Variation of the Si/Al ratio in nanosized zeolite Beta crystals, Micropor. Mesopor. Mater., 90, 237-245 (2006) @No $ @ @ Poe B.T., Mc.Millal P.F.M., Angell C.A. and Sato R.K., Al and Si coordination in SiO1bAl glasses and liquids: A study by NMR and IR spectroscopy and MD simulations, Chem. Geol., 96, 333-349 (1992) @No $ @ @ Tarte P., Infra-red spectra of inorganic aluminates and characteristic vibrational frequencies of AlO tetrahedra and AlO octahedra, Spectro. Chim. Acta.,23(A), 2127-2143 (1967) @No $ @ @ Farmer V.C, Fraser A.R. and Tait J.M., Characterization of the chemical structures of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy, Geochim. Cosmochim. Acta., 43, 1417-1420 (1979) @No $ @ @ Prasad P.S.R. and Prasad K.S., Dehydration and rehydration of mesolite: An in situ FTIR study, Micropor.Mesopor. Mater., 100, 287-294 (2007) @No $ @ @ Mozgawa W., The relation between structure and vibrational spectra of natural zeolites, J. Mol. Struct., 596, 129-137 (2001) @No <#LINE#>Differential Pulse Anodic Stripping Voltammetric Study of Zinc-Ethylenediamine Complex<#LINE#>Nurun@Nahar<#LINE#>5-9<#LINE#>2.ISCA-RJCS-2013-116.pdf<#LINE#>Department of Chemistry, Jahangirnagar University, Savar Dhaka-1342, BANGLADESH <#LINE#>9/7/2013<#LINE#>27/8/2013<#LINE#>Differential pulse anodic stripping voltammetric study of zinc-ethylenediamine complex has been investigated using thin mercury film coated glassy carbon electrode at 30°C. The overall work was carried out at constant ionic strength (I = 0.20 mol dm-3) and pH (9.10±0.10). The electrode processes were found to be reversible and diffusion controlled. The results revealed that zinc forms three (1:1, 1:2 and 1:3- metal: ligand) complexes with ethylenediamine (en). The values of stability constant of zinc complexes were found to be 106.03, 1010.16 and 1013.98 for ZnL, ZnL and ZnL, respectively (the overall charges were omitted for simplicity). The percentage of all possible zinc species were calculated using the stability constant of zinc complexes and hydrolysis constant of zinc under present experimental conditions. <#LINE#> @ @ Patel Ketan B, Patel Yogesh M. and Patel Raksha B., Metal complexes of 5-[benzyloxy methyl] quinoline-8-ol and 8-quinolinol mixed ligand: A new transition metal complexes with In-Vitro antifungal activity, Res. J. Recent Sci., 2 (ISC-2012),55-60 (2013) @No $ @ @ Eisler R., Zinc hazard to fish, wildlife and invertebrates: a synoptic review, Contaminant Hazard Reviews, 10 (1993) @No $ @ @ Francis A.R and Masilamai D., Removal of zinc by non living biomass of Agaricus Bisporus, Res. J. Recent Sci., 1(9), 13-17 (2012) @No $ @ @ Buffle J., Complexation reaction in aquatic system: An analytical approach, Ellis Horwood, Chichester, pp. 467-562 (1988) @No $ @ @ Kissinger P.T. and Heinemann W.R., Laboratory Techniques in Electroanalytical Chemistry, Marcel Dekker, New York, (1996) @No $ @ @ Nahar N., Electrochemical study of speciation of lead(II) in aqueous solution in ppb level in presence of cysteine, Jahangirnagar University Journal of Science, 26, 55-66 (2003) @No $ @ @ arj M.M. and Malinowski E.R., Complexation between copper (II) and glycine in aqueous acid solutions by window factor analysis of visible spectra, Anal. Chem., 68, 1593-1598 (1996) @No $ @ @ Corrie A.M., Walker M.D. and Williams D.R., Thermodynamic considerations, Part XXII, Sequestering ligands for improving the treatment of plumbism and cadmiumism, J. Chem. Soc., Dalton Trans., 1012-1015 (1976) @No $ @ @ Gardiner H., The chemistry of cadmium in natural water-I: A study of cadmium complex formation using the cadmium specific-ion electrode, Water Res., 8, 23-30 (1974) @No $ @ @ Stiff M.J. Copper/bicarbonate equilibria in solutions of bicarbonate ion at concentrations similar to those found in natural water, Water Res., , 171-176 (1971) @No $ @ @ Nahar N., Anshaya R. and Abser M. N., Electrochemical Studies on Speciation of Cadmium(II) in ppb Level by Complexation with Ethylenediamine in Aqueous Media, Bangladesh J. Sci. Ind. Res., 44(1), 1-10 (2009) @No $ @ @ Nahar N., Mona N. P. and Abser M. N., Electrochemical Studies on Complexation and Speciation of Copper(II) in ppb Level with 1,10-Phenanthroline in Aqueous Media, Bangladesh J. Sci. Ind. Res, 46(12), 219-224 (2011) @No $ @ @ DeFord D.D. and Hume D.N., The Determination of consecutive formation constants of complex ions from polarographic data, J. Amer. Chem. Soc., 73, 5321-5322 (1951) @No $ @ @ Martell A.E. and Smith R.M., Critical Stability Constants, Plenum Press, New York,5, 143 (1982) @No <#LINE#>Spectro-Chemical Characterization of Rangpur (Sabjibari) Soil Fractions of Bangladesh<#LINE#>Y.@Zaker,M.A.@Hossain,P.@Paul,T.S.A.@Islam<#LINE#>10-17<#LINE#>3.ISCA-RJCS-2013-117.pdf<#LINE#>Department of Chemistry, University of Dhaka, Dhaka-1000, BANGLADESH <#LINE#>9/7/2013<#LINE#>27/8/2013<#LINE#>Rangpur (Sabjibari) soil was fractionated to three different fractions as sand (≥140 µm), silt (53~140µm) and clay (≤53µm) based on particle size using hydrometer method. These three fractions were characterized by LIBS (Laser induced breakdown spectroscopy), XRD (X-Ray diffraction) and FT-IR (Fourier transform infra-red spectroscopy). pHzpc (Zero point charge pH) of clay and silt were also determined by titrimetric method. According to the results of LIBS Fe, Si,Cu, and Na are present in all fractions with different oxidation state. Ti is the only element which is present in clay fraction. XRD analysis indicates that d-values of the soil fractions are not similar to the d-values of any of clay minerals kaolinite, quartz, chlorite and illite. FT-IR spectra of all fractions show the presence of Zn=O, O-H, Al-O-Si, Fe-O, Al-OH and Si-O bonds with different vibrational modes. The pHzpc value of silt and clay were obtained as 6.35±0.02 and 5.98±0.02 respectively suggesting that silt surface is neutral but the surface of clay is slightly acidic. <#LINE#> @ @ Day P. R., Particle Formation and Particle Size Analysis, In: Methods of Soil Analysis, (eds. CA Black, DD Evans, JL White, LE Ensminger and FE Clark), Agronomy Monograph,Part I, 545-567 (1965) @No $ @ @ Gee G. W. and Bauder J. W., Particle-size Analysis. In: A. Klute (Editor), Methods of Soil Analysis, Part I. 2nd ed. Agronomy.9,383-399 (1986) @No $ @ @ Schmidt M. W. I., Rumpel C. and Kogel-Knabner I., Particle Size Fractionation of Soil Containing Coal and Combustion Particles, European J. Soil Sci., 50,515-522 (1999) @No $ @ @ Sjöberg M., Bergström L., Larsson A. and Sjöstrom E., The Effect of Polymer and Surfactant Adsorption, on the Colloidal Stability and Rheology of Kaolin Dispersions, Colloids and Surface A: Physicochemical and Eng. Aspect., 159, 197-208 (1999) @No $ @ @ Moss A. J. and Green P., Sand and Silt Grains: Predetermination of Their Formation and Properties by Microfractures in Quartz, Australian J. Earth Sci.,22(4),485–495 (1975) @No $ @ @ Micklethwait J. (editor in chief),The Hourglass Effect. The economist. http://www.economist.com/world/asia/ displaystory.cfm Story_id=14588255 (2009) @No $ @ @ Goudie A. S. and Viles H. A., The Nature and Pattern of Debris Liberated by Salt Weathering: A Laboratory Study, Earth Surface Processes and Landforms, 9, 95–98 (1995) @No $ @ @ Wright J.S., Smithand B. J. and Whalley W. B., Mechanisms of Loess-sized Quartz Silt Production and their Relative Effectiveness: Laboratory Simulations, Geomorphology, 23, 15–34 (1998) @No $ @ @ Brammer J.C., The Clays of Arkansas, U. S. Geological Survey Bulletin, 351, 247 (1808) @No $ @ @ Williams N.F. and Plumber N., Clay Resources of the Wilcox group in Arkansas, Arkansas Resources and Development Commission, Division of Geology.98(1951) @No $ @ @ Bilgic C., Investigation of the Factors Affecting Organic Cation Adsorption on Some Silicate Minerals, J. Colloid Interf. Sci.,281, 33–38 (2005) @No $ @ @ Zaker Y., Hossain M. A. and Islam T. S. A.,Adsorption Kinetics of MB onto Clay fractionated from Bijoypur Soil, Bangladesh, Res. J. Chem. Sci.,3(2), 65-72 (2013) @No $ @ @ Zaker Y, Hossain M. A. and Islam T. S. A.,Effect of Various Factors on the Adsorption of MB on Silt Fractionated from Bijoypur Soil, Bangladesh, Int. Res. J. Environment Sci.,2(6), 1-7 (2013) @No $ @ @ Biswas M. A. and Basak A. K., IR Studies of Some East Pakistan’s Clay, Pakistan J. of Scientific and Industrial Research, 4, 118-120 (1961) @No $ @ @ Brumley W.C., Brownrigg C.M. and Brilis G.M., Characterization of Nitrogen-containing Aromatic Compounds in Soil and Sediment by Capillary Gas Chromatography-Mass Spectrometry after Fractionation, J. Chromatography A., 558(1), 223–233 (1991) @No $ @ @ Dai X.Y., Ping C.L., Candler R., Haumaier L. and Zech W., Characterization of Soil Organic Matter Fractions of Tundra Soils in Arctic Alaska by Carbon-13 Nuclear Magnetic Resonance Spectroscopy, Soil Science Society of Am. J., 65(1),87-93 (2001) @No $ @ @ Accoe F., Boeckx P., Van Cleemput O., Hofman G., Hui X., Bin H. and Guanxiong C., Characterization of Soil Organic Matter Fractions from Grassland and Cultivated Soils via C content and delta13C signature,Rapid Comm. Mass Spectrom., 16(23), 2157-64 (2002) @No $ @ @ Miran M. S., Mollah M. Y. A., Hussain A. and Rahman M. M., A Multi-Technique Characterization of Bijoypur Clay, Bangladesh J. Sci. Res., 21(1-2), 15-22 (2008) @No $ @ @ Abdel Rahman H. M., Olk D., Cocozza C. and Miano T., Fractionation and Characterization of Soil Organic Carbon during Transition to Organic Farming, European Geoscience Union, General Assembly 2012, Vienna, Austria, pp.-10727 (2012) @No $ @ @ Zaker Y., Islam M. S., Hossain M. A. and Islam T. S. A.,Physico-Chemical Characterization of Clay Fractionated from Bijoypur Soil, Bangladesh J. Agri. Environ.,9(1), (in press) (2013) @No $ @ @ Zaker Y., Islam M. S., Hossain M. A. and Islam T. S. A.,Physico-Chemical Characterization of Silt Fractionated from Bijoypur Soil, J. Asiatic Soc. Bangladesh. 39(1),(in press) (2013) @No $ @ @ Zaker Y, Ali M., Islam M. S., Hossain M. A. and Islam T. S. A.,Physico-Chemical Characterization of Sand Fractionated from Bijoypur Soil, under publication (Res. J. Recent Sci.(2013) @No $ @ @ Huang C. P. and Ostovic, Removal of Cd(II) by Activated Carbon Adsorption, J. Env. Div. ASCE.104, 863-878 (1989) @No $ @ @ NIST Atomic Spectra Database, http://physics.nist_gov/ physrefdata/ ASD/lines_form. html. (2010) @No $ @ @ Ozcan A. S. and Ozcan A., Adsorption of Acid Dyes from Aqueous solutions onto Acid-Activated Bentonite, J. Colloid Interface Sci., 276, 39-46 (2004) @No $ @ @ Xu Y. and Axe L., Synthesis and Characterization of Iron Oxide-Coated Silica and Its Effect on Metal Adsorption, J. Colloid and Interface Sci.,282(1), 11-19 (2005) @No $ @ @ Adrian S. and Kelleher B. P., FTIIR Spectroscopic Analysis of Kaolinite- Microbia Interactions, Vib. Spect.,61, 151-155 (2012) @No $ @ @ Phys. Chem. Ref. Data. Framework-Type Determination for Zeolite Structures in the Inorganic Crystal Structure Database, J. Phys. Chem. Ref. Data,39, 033-102(2010) @No <#LINE#>Determination and Contamination Assessment of Pb, Cd, and Hg in Roadside Dust along Kathmandu-Bhaktapur Road Section of Arniko Highway, Nepal<#LINE#>PawanRaj@Shakya,AchutRam@Pradhananga<#LINE#>18-25<#LINE#>4.ISCA-RJCS-2013-120.pdf<#LINE#>Department of Chemistry, Faculty of Science, Padma Kanya Multiple Campus, Tribhuvan University Kathmandu, NEPAL<#LINE#>12/7/2013<#LINE#>23/8/2013<#LINE#>Lead (Pb), cadmium (Cd) and mercury (Hg) were analyzed by atomic absorption spectrophotometer (AAS) in roadside dust samples collected from 10 major sampling sites along Kathmandu-Bhaktapur road section of Arniko Highway, Kathmandu valley, Nepal. Elevated levels of the heavy metals were found in the dust samples which were compared with background values (control). The metal concentrations varied from 69.09-471.40 mg/kg for Pb, 1.56-6.15 mg/kg for Cd and 0.59-1.89 mg/kg for Hg respectively along with the average concentrations 245.36 mg/kg, 2.89 mg/kg and 1.04 mg/kg, respectively for the same elements. These values were compared with results from various cities/countries world wide. Pollution indices such as contamination factor (CF), degree of contamination (CD) and geo-accumulation index (Igeo) of the heavy metals indicated various levels of contamination in the roadside dust across the study sites. The results suggest that traffic emission, automobiles and other anthropogenic activities are the potential sources of the metal contamination.<#LINE#> @ @ Li X., Poon C.S. and Liu P.S., Heavy metal contamination of urban soils and street dusts in Hong Kong, Appl. Geochem., 16, 1361-1368 (2001) @No $ @ @ Pagotto C., Remy N., Legret M. and Lecloirec P., Heavy metal pollution of Road dust and road side soil near a major rural highway, Environ. 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Geochem., S2, 269–272 (1993) @No $ @ @ Li X. and Liu P.S., Heavy metal contamination of urban soils and street dusts in Hong Kong, Appl. Geochem., 16, 1361– 1368 (2001) @No $ @ @ Trivedy R.K. and Goel P.K., Chemical and Biological Methods for Water Pollution Studies, Environmental Publications, Oriental Printing Press, Aligarh (1986) @No $ @ @ Soil Survey Staff, in Soil Survey Laboratory Methods Manual, Version No. 4.0, USDA NRCS, Soil Survey Investigations Report No. 42, U.S. Govt. Print. Office, Washington, DC, (2004) @No $ @ @ Watanabe I., Maehata A., Ozaki H. and Kuno K., Heavy metal concentration in street dusts collected around Oze, Nikko national park, in 1999 and their local and seasonal variations, Environ. Sci., 15, 113–125 (2002) @No $ @ @ Håkanson, L., An ecological risk index for aquatic pollution control: A sedimentological approach, Water Res., 14, 975–1001 (1980) @No $ @ @ Mmolawa K.B., Likuku A.S. and Gaboutleeloe G.K., Assessment of heavy metal pollution in soils along major roadside areas in Botswana. Afri. J. Environ.Sci. Technol., , 186-196 (2011) @No $ @ @ Duong T.T. and Lee B.K., Determining contamination level of heavy metals in road dust from busy traffic areas with different characteristics, J. Environ. Manage,92, 554–562 (2011) @No $ @ @ Müller G., Index of geo-accumulation in sediments of the Rhine River, Geojournal, , 108–118 (1969) @No $ @ @ Yaalon D.H., Soils in Mediterranean region: what makes them different?, Catena,28, 157–169 (1997) @No $ @ @ Fuente D., Chico B. and Morcillo E., The effects of soluble salts at the metal/paint interface: advances in knowledge, Port. Electrochim. Acta, 24, 191–206 (2006) @No $ @ @ Stone M. and Marsalek J., Trace metal composition in street sediment: Sault St. Marie, Canada, Water, Air, Soil Pollut., 87, 149–169 (1996) @No $ @ @ Acosta J.A., Faz A., Kalbitz K., Jansen B. and Martnez-Martnez S., Heavy metal concentrations in particle size fractions from street dust of Murcia (Spain) as the basis for risk assessment, J. Environ. Monit.,13, 3087–3096 (2011) @No $ @ @ Smichowski P., Gómez D.R., Frazzoli C. and Caroli S., Traffic-related elements in airborne particulate matter, Appl. Spectros. Rev., 43, 23-49 (2008) @No $ @ @ Faiz Y., Tufail M., Javed M.T., Chaudhry M.M. and Siddique N., Road dust pollution of Cd, Cu, Ni, Pb and Zn along Islamabad Expressway, Pak.. Microchem. J., 92, 186-192 (2009) @No $ @ @ Idrees F. and Momani A., Trace Elements in Street and Household Dusts in Amman, Jordan. Soil Sed. Contam., 16: 485-496 (2007) @No $ @ @ Charlesworth S., Everett M., McCarthy R., Ordonez A. and De Miguel E., A comparative study of heavy metal concentration and distribution in deposited street dusts in a large and a small urban area: Birmingham and Coventry, West Midlands, UK, Environ. Inter.,29, 563-573 (2003) @No $ @ @ Ahmed F. and Ishiga H., Trace metal concentrations in street dusts of Dhaka city, Bangladesh, Atmos. Environ., 40, 3835-3844 (2006) @No $ @ @ Sezgin N., Ozcan H.K., Demir G., Nemlioglu S. and Bayat C., Determination of heavy metal concentrations in street dusts in Istanbul E-5 highway, Environ. Inter., 29, 979-985 (2003) @No $ @ @ Shinggu D.Y., Ogugbuaja V.O., Barminas J.T. and Toma I., Analysis of street dust for heavy metal pollutants in Mubi, Adamawa State, Nigeria, Inter. J. Phy. Sci.., , 290-293 (2007) @No $ @ @ Ferreira-Baptista L. and De Miguel E., Geochemistry and risk assessment of street dust in Luanda, Angola: A tropical urban environment, Atmos. Environ., 39, 4501-4512 (2005) @No $ @ @ Akhter M.S. and Madany I.M., Heavy metals in street and house dust in Bahrain. Water Air Soil Pollut., 66, 111-119 (1993) @No $ @ @ Christoforidis A. and Stamatis N., Heavy metal contamination in street dust and roadside soil along the major national road in Kavala's region, Greece, Geoderma, 151, 257–263 (2009) @No $ @ @ Ambade B., Evaluation of heavy metal contamination in road dust fallout of Bhilai City, Int. J. Adv. Engg. Res. Stud.,1, 81-83 (2012) @No <#LINE#>Synthesis and Antimicrobial Activity of some Salicylaldehyde Schiff bases of 2-aminopyridine<#LINE#>Vinita@Gupta,Sanchita@Singh,Y.K.@Gupta<#LINE#>26-29<#LINE#>5.ISCA-RJCS-2013-127.pdf<#LINE#>Department of Chemistry, Agra College, Agra, UP, INDIA @ Department of Chemistry, B.K. Birla Institute of Engineering and Technology, Pilani, Rajasthan, INDIA <#LINE#>27/7/2013<#LINE#>7/8/2013<#LINE#> Schiff bases particularly (1) N-(2-hydroxylbenzylidene) pyridin-2-amine, (2) N-(5-nitro-2- hydroxylbenzylidene) pyridin-2-amine, (3) N-(5-bromo-2- hydroxylbenzylidene) pyridin-2-amine, (4) N- (5-methoxy-2-hydroxylbenzylidene) pyridin-2-amine are prepared from 2- aminopyridine and substituted benzyaldehydes. The synthesized compounds are characterized by elemental analysis, IR and HNMR. The result shows that the compounds are capable to prevent the growth of S. aureus and E. coli in diverse concentrations. The growth prevention capability was affected by the solvent and substitute group on the salicyldene part.<#LINE#> @ @ Gupta Y. K.*, Agarwal S.C., Madnawat S.P. and Ram Narain, Synthesis, Characterization and Antimicrobial Studies of Some Transition Metal Complexes of Schiff Bases, Res. J. Chem. Sci., 2(4)68-71, April (2012) @No $ @ @ Parekh J, Inamdhar P, Nair R, Baluja S, Chanda S, Synthesis and antibacterial activity of some Schiff bases derived from 4-aminobenzoic acid, J. Serb. Chem. Soc., 70,1155-1161(2005) @No $ @ @ Sinha D, Tiwari AK, Singh S, Shukia G, Mishra P, Chandra H, Mishra AK, Synthesis, characterization and biological activity of Schiff base analogue of indole-3- carboxaldehyde, Eur. J. Med. Chem., 43, 160-165, (2008) @No $ @ @ Gupta Yogesh Kumar*, Gupta Vinita and Singh Sanchita, Synthesis, characterization and antimicrobial activity of pyrimidine based derivatives, Journal of Pharmacy Research, Elsevier7(6), 491-495 (2013) @No $ @ @ Hou H, Zhu J, Qi Z, Zhou B, Li M, Liu Y, Antibacterial activity and structure-activity relationship of Schiff bases on Staphylococcus aureus by microcalorimetery, Wuhan Univ. J. Nat. Sci.,15, 71-77 (2010) @No $ @ @ Aggarwal N, Kumar R, Dureja P, Rawat DS, Schiff base as potential fungicides and nitrification inhibitors, J. Agric. Food Chem.,57, 8520-8525 (2009) @No $ @ @ Adsule S, Barve V, Chen D, Ahmed F, Dou QP, Padhye S,Sarkar FH, Novel Schiff base copper complexes of quinoline-2-carboxaldehyde as proteasome inhibitors in Human prostate cancer cells, J. Med. Chem.,49, 7242- 7246 (2006) @No $ @ @ Hadjoudis E., Photochromic and thermochromic anils, Mol. Eng.,5, 301-337 (1995) @No $ @ @ Houlden SA, Csizmadia IG, The geometry and electronic structure of substituted Schiff's bases, Tetrahedron, 25,1137-1153 (1969) @No $ @ @ Guha D., Mandal A., Koll A., Filarowski A., Mukherjee S., Proton transfer reaction of a new orthohydroxy Schiff base in protic solvents at room temperature, Spectrochim. Acta A., 56, 2669-2677 (2000) @No $ @ @ Issa RM, El-Daly SA, El-Wakiel NA UV/Vis, IR and H NMR spectroscopic studies of bis azo-dianil compounds based on 5-(2- carboxyphenyl azo)-salicylaldehyde and primary diamines, Spectrochim. Acta A.,59, 723-728,(2003) @No $ @ @ Schiff W, Szady-Chelmieniecka A, Grech E, Przybylski P, Brzezinski B, Spectroscopic studies of new Schiff and Schiff–Mannich bases of ortho-derivatives of 4-Bromophenol, J. Mol. Struct., 643, 115-121, (2002) @No $ @ @ Prisakar VI, Tsapkov VI, Buracheeva SA, Byrke MS, Gulya AP, Synthesis and antimicrobial activity of coordination compounds of copper with substituted salicylaldehyde thiosemicarbazones, Pharm. Chem. J.,39,30-32, (2005) @No $ @ @ Pelttari E, Karhumaki E, Langshaw J, Perakyla H, Elo H, Antimicrobial properties of substituted salicylaldehyde and related compounds, Z. Naturforsch,62C, 487-497, (2007) @No $ @ @ Chohan ZH, Arif M, Sarfraz M,Metal-based antibacterial and antifungal amino acid derived Schiff bases: their synthesis, characterization and in-vitro biological activity, Appl. Organomet. Chem., 21, 294-302 (2007) @No $ @ @ Tsapkov VI, Prisacar VI, Buracheva SA, Lazakovich DV, Gulya AP, Synthesis and antimicrobial activity of sulfazine-containing copper(II) coordination compounds with substituted salicylaldehydebenzoylhydrazones, Pharm. Chem. J.,42, 523-526, (2008) @No $ @ @ Shi L, Ge HM, Tan SH, Li HQ, Song YC, Zhu HL, Tan RX, Synthesis and antimicrobial activity of Schiff bases derived from 5- chloro-salicylaldehyde, Eur. J. Med. Chem., 42, 558-564 (2007) @No $ @ @ Mims C., Dockrell H.M., Goering R.V., Roitt I., Wakelin D., Zuckerman M, Medical Microbiology, Elsevier Mosby, updated 3rd edition, 11-12 (2004) @No <#LINE#>Potentiality of some Synthesized Benzimidazolo-quinazolinone and Pyrimido-benzimidazole Ligands for Selective Extraction of the Rare Earth Elements<#LINE#>G.M.@Hussein<#LINE#>30-38<#LINE#>6.ISCA-RJCS-2013-128.pdf<#LINE#>Nuclear Materials Authority, P.O Box 530, El-Maadi, Cairo, EGYPT<#LINE#>26/7/2013<#LINE#>7/8/2013<#LINE#>Three synthesized multidentate organic solvents; namely 1,2-dihydro-3H-benzimidazolo [1,2-a] quinazolin - 4 - one (4a), 1,2-dihydro - 2, 2 dimethyl benzimidazolo [1,2-a] quinazolin - 4 (3H) - one(4b) and 3 - (cyclohexane - 1 – on - 2yl)pyrimido[1,2-a] benzimidazole (4c) were examined for their extractive potentiality of the rare earth elements from Kadabora sulfate leach liquor. The influential parameters controlling the extraction process including the extractant type, the sulfuric acid concentration, the contact time, the organic/aqueous ratio and the solvents concentration were determined. It was also found that the extractability of the synthesized multidentate organic compounds (4a, 4b and 4c) for rare earths decreases in the order 4a > 4b > 4c. The effects of the stripping agent type, concentration, contact time and O/A ratio on the stripping efficiency of the rare earth elements from the loaded extractants were also tested. A rare earth cake was finally obtained from the strip solution by the addition of oxalic acid as a precipitating agent<#LINE#> @ @ Scargill D., Alcock K., Fletcher J.M., Hesford E. and McKay H.A.C., J. Inorg. Nucl. 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Essays., 7, 3751-3757, (2012) @No $ @ @ Chhonker Y.S., Veenu B., Hasim S.R., Niranjan Kaushik, Devendra kumar., and Pradeep kumar., Synthesis and Pharmacological Evaluation of Some New 2-Phenyl benzimidazoles Derivatives and their Schiff’s Bases, E-Journal of Chemistry., 6(S1), S342-S346, (2009) @No $ @ @ Meiser F., Cortez C., and Caruso F., Biofunctionalization of Fluorescent Rare-Earth-Doped Lanthanum Phosphate Colloidal Nanoparticles, Angew. Chem., Int. Ed., 43, 5954–5957, (2004) @No $ @ @ Moraillon A., Gouget-Laemmel A. C., Ozanam F., and Chazalviel J.-N., Amidation of Monolayers on Silicon in Physiological Buffers: A Quantitative IR Study, J. Phys. Chem. C., 112, 7158–7167, (2008) @No $ @ @ Jayanna N.D., Vagdevi H. M., Darshan J.C., Prashith kekuda., Hanumanthappa B.C., and Gowdershivannavar B.C., synthesis and biological evaluation of novel 5,7-dichloro-1,3-benzoxazole derivatives, journal of chemistry., 2013, (2012) @No <#LINE#>Thermal decomposition Kinetics and mechanism of Co(II), Ni(II), and Cu(II) complexes derived from Anthracene carboxaldehyde L-Tyrosine<#LINE#>IndiraDevi@G.,P.G.@Sabu,Geetha@Parameswaran<#LINE#>58-63<#LINE#>10.ISCA-RJCS-2013-138.pdf<#LINE#>Department of Chemistry, Zamorin’s Guruvayurappan College, Calicut, Kerala-673014, INDIA @ M.A.M.O. College, Mukkam, Calicut, Kerala-673602, INDIA @ Department of Chemistry (Retired), University of Calicut, Kerala, INDIA <#LINE#>10/8/2013<#LINE#>31/8/2013<#LINE#> Cobalt(II), nickel(II), and copper(II) complexes of the Schiff base anthracene – 9 –carboxaldehyde - tyrosine were synthesized and characterized on the basis of elemental analysis, magnetic moment, molar conductance, UV- visible and IR spectra. Cobalt (II), nickel (II), and copper (II) complexes were subjected to thermal analysis to determine their thermal stability and decomposition pattern. The kinetic parameters like activation energy (E), frequency factor (A), entropy of activation (S), and order parameter (n) were calculated from TG curves using Coats Red fern and Horowitz Metzger equations. Evaluation of the reaction mechanism by non-iso thermal methods has been employed using the nine mechanistic equations. In all these cases the final products of decomposition were identified as respective oxides. The relative thermal stability of the chelates is in the order Co complex > Cu complex > Ni complex. The complexes of anthracene carboxaldehyde - tyrosine with Co(II) and Ni(II) having the formulae [M ACT (H O)] exhibited a one stage decomposition pattern in its TG curve. While [Cu ACT (H O)] gives a two stage decomposition pattern. <#LINE#> @ @ Aravindahshan K.K. and Muraleedharan K., J. Ind. Chem. Soc, 68, 348 (1991) @No $ @ @ Rehina and Parameswaran G., J. of Ther. Anal. and Calorimetry, 55, 817–831 (1999) @No $ @ @ Indira V. and Parameswaran G., Thermo. Chim. Acta., 101, 145 (1986) @No $ @ @ Laly S. and Parameswaran G., React. Kinet. Cal. Lett.,43, 169 (1991) @No $ @ @ Dhar M.L. and Singh O., J. Thermal Anal,37, 499 (1991) @No $ @ @ Sestak J. and Berggren G., Thermo. Chim. Acta,, (1971) @No $ @ @ Satava V., Thermo Chim. Acta., 2, 423 (1971) @No $ @ @ Haines P.J., Thermal Methods of Analysis, London, Blakie, (1995) @No $ @ @ Luckaszewski G.M. and J.P. Redfern, Lab. Pract., 10, 721 (1961) @No $ @ @ Duval C., In org. Ther. Grav. Analysis, Elsevier, New York, 2nd ed., (1962) @No $ @ @ Smoothers W.J. and M.S. Yao Chiang, Hand book of differential thermal analysis, Chemical publishing Co:, New York, (1966) @No $ @ @ Wendlandt W.W, Thermal methods of analysis, John Wiley, New York, 2nd Ed. (1974) @No $ @ @ Nath mala, Thermochim. Acta, 185(1), 11-24 (1991) @No $ @ @ Montazerozohori Morteza, Musavi Sayed Ali Reza and Joohari Shiva, Res. J. Recent Sci., 1(11), 9–15 (2012) @No $ @ @ Mostafa M., Res. J. Chem. Sci., 1(7), 1-14 (2011) @No $ @ @ Fasiulla K.R., Reddy Venugopala, Keshavayya J., Moinuddin Khan M.H., Anitha and Vittala Rao, Res. J. chem. sci., 1(9), 29-36 (2011) @No $ @ @ Gupta Y.K., Agarwal S.C., Madnawat S.P. and Ram Narain, Res. J. chem. sci.,2(4), 68-71 (2012) @No $ @ @ Coats A.W. and J.P. Redfern, Nature London, 68, 201, (1964) @No $ @ @ Coats A.W. and J.P. Redfern, Analysist, 88, 2938 (1963) @No $ @ @ Horowitz H.H. and G. Metzger, Anal. Chem, 36, 1464(1963) @No $ @ @ Nikolaev A.V., Logvinenko V.A. and Myachina L.T., Thermal analysis, Acad. Press, New York, 779, (1969) @No <#LINE#>Study of Physical and Chemical Properties of Biodiesel from Sorghum Oil<#LINE#>Ved@Kumar,Padam@Kant<#LINE#>64-68<#LINE#>11.ISCA-RJCS-2013-141.pdf<#LINE#>Department of Chemistry, University of Lucknow, Lucknow-226007, INDIA<#LINE#>14/8/2013<#LINE#>24/8/2013<#LINE#>There has been great awareness in the area of the development of biodiesel especially in the developing countries during the recent time. Significant research activities have been performed for its production and new development. Biodiesels can be the fuel of the future as it provides an option of economical, eco-friendly, alternative renewable energy source. In the present investigation sorghum bicolor seed oil and its methyl ester have been chosen to find out their suitability as petro-diesel. Experimental investigation has been made to find out the physico-chemical properties of sorghum oil. Laboratory scale quantities of sorghum oil biodiesel were produced through transesterification reaction using 100 g sorghum oil, 17% methanol (wt% sorghum oil), 1.0% sodium hydroxide catalyst at 60°C in 90 minutes. The experiments were triplicate and average results were evaluated. The obtained biodiesel was characterized as an alternative diesel fuel through series of ASTM and European organization (EN 14214) standard fuel tests. The transesterification process yielded 93.5% sorghum oil biodiesel. The sorghum oil biodiesel had 89.9% reduction of viscosity over its raw vegetable oil at 40°C. Higher specific gravity, pour point and cloud point were obtained and comparison has been carried out to petroleum diesel. Specific gravity values were found to favorable with results for other vegetable oil biodiesel. Results obtained were found to be within limits set by various International standards for biodiesel.<#LINE#> @ @ Encinar J. M., Gonzalez J. F. and Rodriguez R. A., Ethanolysis of used Frying oil. Biodiesel preparation and characterization, Fuel Processing Technology, 88, 513-522, (2007) @No $ @ @ Pramanik K., Properties and use of jatropha curcas oil and diesel fuel blend in compression ignition engine, Renewable Energy, 28, 239-248 (2003) @No $ @ @ Knothe, Gerhard and Steidley R. K., Kinematic viscosity of biodiesel fuel component and related compounds. Influence of compound structure and comparison to petro-diesel fuel components, Fuel, 84, 1059-1065 (2005) @No $ @ @ Muragesan A., Umarani C., Chinnusamy T. R., Krishanan R., Subramanean R., and Neluzchezhain N., Production and analysis of biodiesel from non-edible oils: A Review. Renewable and Sustainable Energy Reviews, 13, 825-834 (2009) @No $ @ @ Ma F., Hanna A. M., Biodiesel production: a review, Bioresour. Technol., 70, 1-15 (1999) @No $ @ @ Francis G., Edinger R. and Becker K., A concept for simultaneous wasteland reclamation, fuel production, and socio-economic development in degraded areas in India: need, potential and perspectives of Jatropha plantations, Natural Resources Forum, 29, 1, 12–24 (2005) @No $ @ @ Kaidea M., Samukawa T., Kondo A., Fukuda H., Lipasecatalyzed production of biodiesel fuel from vegetable oils,J. Biosci. Bioeng.,91, 12-15 (2001) @No $ @ @ Mittelbach M., (1990): Lipase catalyzed alcoholysis of sunflower oil, . Am. Oil Chem .Soc., 67, 168 (1990) @No $ @ @ Antolin G, Tinaut F. V., Briceno Y., Castano V., Perez C., Ramirez A. I., Biodiesel preparation by lipase- catalyzed transesterification of jatropha oil. Bioresour. Technol., 83, 111 (2002) @No $ @ @ Oznur K., Tuten M., Aksoy H. A., (2002):Enzymatic transesterification for biodiesel production, Bioresour. Technol., 83, 125 (2002) @No $ @ @ Linko Y. Y., Lamsa M. W. X., Vosu Kairun W., Sapala J., Linko P. J., Bioderadable product by lipase biocatlysis, J. Biotehnol., 66, 41-50 (1999) @No $ @ @ Crabbc E., Nolasco-Hipolito C., Kobayashi G., Sonomoto K., Is Hizaki A., Recent advances in microbial polyhydroxyalkanoate, Process. Biochem. 37, 65-71 (2001) @No $ @ @ Rayan T. W., Callahan T. J., and Dodge L. G., Characterization of vegetable oils for use as fuels in diesel engines, Vegetable oils as Fuels-proceeding of the International Conference on Plant and Vegetable oils as Fuels, August, 70-81 (1982) @No $ @ @ Frot E. F., and Blumberg P. N., Performance and durability of a turbocharged diesel Fueled with Cottonseed oil Blend, Vegetable oils as Fuels-proceeding of the International Conference on Plant and Vegetable oils as Fuels, August, 374-382 (1982) @No $ @ @ Walter J.P. and Derry J., The 1981 Flower Power Field Testing Program, Vegetable oils as Fuels-proceeding of the International Conference on Plant and Vegetable oils as Fuels, August, 384-393 (1982) @No $ @ @ Baranescu R.A. and Lusco J.J., Performance, durability and Low Temperature Evaluation of Sunflower oil as a Diesel Fuel Extender, Vegetable oils as Fuels-proceeding of the International Conference on Plant and Vegetable oils as Fuels, August, 312-328 (1982) @No $ @ @ Graboski M. S. and Mccormick R. L., Combustion of fat and vegetable oil derived fuels in diesel engines, Prog. Energ Combust. Sci., 24, 125-164 (1998) @No $ @ @ Noureddini H., Teoh B. C., and Clements D. L., Viscosities of vegetable oils and fatty acids, J. Am. Oil Chem. Soc., 69, 1189-1191 (1992) @No $ @ @ Gouw T. H., Vlugter J. C. and Roelands C. J. A., Physical properties of fatty acid methyl esters, J. Am. Oil Chem. Soc., 43, 433-436 (1966) @No $ @ @ Khothe G., Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters, Fuel Processing Technology 86, 1059-1070 (2005) @No $ @ @ www.chempro.in/ fatty acid.htm (2013) @No $ @ @ Andrew K., Cuevas J. A., Mark F., Daniele R. and Graham I. A., Potential of jatropha curcas as a source of renewable oil and animal feed, Journal of Experimental Botany , 60, 2897-2905 (2009) @No $ @ @ Keith O. A review of jatropha curcas: an oil plant of unfulfilled promise, Biomass and Bioenergy, 19, 1-15 (2000) @No $ @ @ Raja S. A., Robinson Smart D. S. and Robert Lee C. L., Biodiesel production from jatropha oil and characterization, Research Journal of Chemical Science, 1 (1) 81-87 (2011) @No $ @ @ Indian Standard Methods of Sampling and Test for Butterfat’s, Fifth edition, December, (1995) @No <#LINE#>Microwave Assisted Synthesis and Characterisation of Diamagnetic Complexes<#LINE#>Jeeva@J.,Ramachandramoorthy@T.<#LINE#>69-76<#LINE#>12.ISCA-RJCS-2013-148.pdf<#LINE#>PG & Research Department of Chemistry, Bishop Heber College (Autonomous), Tiruchirappalli – 620 017, Tamilnadu, INDIA<#LINE#>28/8/2013<#LINE#>10/9/2013<#LINE#>New Cadmium and Mercury complexes with mixed ligands 4-hydroxypyridine and Cyanate ion were synthesised using microwave field. These complexes were characterized by analytical and spectral studies. And also by electrochemical and thermal behavior, the formulae and the geometry of the complexes were confirmed.<#LINE#> @ @ Yogesh P. Patil, Sachin H. Pawar, Sharu Jadhav and Jitendra S. Kadu, Biochemistry of metal absorption in Human body: Reference to check impact of nano particles on human being, Int. J. of Sci and Res Pubs, 3(4), (2013) @No $ @ @ Colman J. and Hegedu L.S., Principles and Applications of Organotransition Metal Chemistry, University Science Book, California (1980) @No $ @ @ Godbert N., Pugliese T., Aziello I., Bellusci A., Crispini A., Ghedini M., Efficient, ultrafast, microwave – assisted syntheses of cycloplatinated complexes, European Journal of Inorganic Chemistry, (32), 5105-5111 (2007) @No $ @ @ Elisabete C.B. Alagria, Luisam D.R.S., Martins Matti Haukka and Armando J.L. Pombeiro., Rhenium complexes of tris (pyrazolyl) methanes and sulfonate derivative, Dalton Tran, 4954–4961 (2006) @No $ @ @ Geary W.J., The use of Conductivity Measurements in Organic solvents for the Characterization of Coordination Compounds, Coordi. Chem. Rev., 7(1), (1997) @No $ @ @ Silverstein R.M., Bassler G.L. and Morrill T.C., Spectrometric Identification of Organic Compounds, thedn, wiley, 166 (1981) @No $ @ @ Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, wiley, rd edn (1997) @No $ @ @ George Socrates, Infrared and Raman Characteristic Group frequencies Tables and Charts, John wiley & sons, 18 (2004) @No $ @ @ Lever A.B.P., Inorganic Electronic Spectroscopy, nd edn., Elsevier, (1984) @No $ @ @ Cotton F.A. and Wilkinson G., Advanced Inorganic Chemistry, th edn, Wiley, New York (1988) @No $ @ @ Gupta Y.K., Agarwal S.C., Madnawat S.P. and Ramnarain., Synthesis, Characterization and Antimicrobial studies of some Transition metal complexes of Schiff Bases, Res. J. Chem. Sci.,2(4), 68-71 (2012) @No $ @ @ Balc, M., Basic PsH and p13s - NMR spectroscopy, st edn., Elsevier, pxii, 427 (2005) @No $ @ @ Bagihalli G.B., Patil S.A. and Badami P.S., Synthesis, Physicochemical Investigation and Biological studies of zinc(II) complexes with 1,2,4-Triazole Schiff Bases, J. of Ira. Chem. Soc., 6(2), 259-270 (2009) @No $ @ @ Neves E.A., De Andrade J.F and Chierice G.O., Anal. Chim. Acta, 155, 269 (1983) @No $ @ @ Chaudhary Rakhi and Shelly, Synthesis, Spectral and Pharmacological Study of Cu(II), Ni(II) and Co(II) Coordination Complexes, Res. J. of Chem. Sci., 1(5), 1-5 (2011) @No $ @ @ Chandran Ambily, Kuriakose Sunny and Mathew Tessymol, Synthesis, Characterization and Thermal Studies on natural polymers modified with 2-(5-(4-dimethylamino-benzylidin)-4-oxo-2-thioxo-thiazolidin-3-yl) acetic acid,Res. J. of Chem. Sci.,2(12), 37-45 (2012) @No $ @ @ Break L.M. and Mosselhi M.A.N., Synthesis, Structure and Antimicrobial Activities of new 3- and 2-arylmethyl and arylacyl 3-H[1,2,4]triazino[3,2-6]quinazline-2,6(1H)diones, Res. J. of Chem. Sci., 2(5), 23-28 (2012) @No @Short Communication <#LINE#>Effect of Dielectric constants of Dioxane-Water mixtures on Proton-Ligand Dissociation constants (pK) and formation Constants of Cu (II) complexes with 1, 3-Diphenyl Thiazines pH-metrically at 0.1M ionic strength<#LINE#>M.M.@Rathore,V.V.@Parhate,P.R.@Rajput<#LINE#>77-79<#LINE#>13.ISCA-RJCS-2013-017.pdf<#LINE#>Department of Chemistry, Vidya Bharati Mahavidyalaya, C. K. Naidu road, Camp, Amravati, MS, INDIA <#LINE#>2/2/2013<#LINE#>12/7/2013<#LINE#>The interactions between Cu(II) and nitro-phenyl thiazine(L), chlorodiphenyl-thiazine (L), chloro, 1,3.thiazine (L), 1,3 phenyl thiazine (L), and 1,3 diphenyl thiazine (L), have been investigated by pH-metric technique at 0.1M ionic strength and in different percentage of dioxone-water mixture with Cu(II)-1,3, diphenyl thiazine data obtained can be used to study the effect of dielectric constants on proton–ligand stability constant. It showed that Cu (II) forms 1:1 and 1:2 complexes with substituted thiazines. It could be also seen that pK and log k values are found to be increased with increasing the percentage of dioxane-water mixtures.<#LINE#> @ @ Mane G.V., Kolhatkar D.G. and Shinde L.P., pH – Metric studies in binary and ternary complexes of dicarboxylic acids and amino acids with some transition and inner transition metal ions, Journal of Chemical and Pharmaceutical Research,4(2), 1022-1027 (2012) @No $ @ @ Gharib F., Farajtabar A. and Bahmani F., Solvent effects on protonation constants of tryptophan in some aqueous aliphatic alcohol solutions, J. Chem. Eng. Data,55(1),327–332 (2010) @No $ @ @ Ramteke A.A. and Narwade M.L., Spectrophotometric Studies on stability constant of chlorosubstituted pyrazoles with Cu (II) Nd (III) and Tb (III) metal ions at 0.1 M Ionic strength, Der Chemica Sinica,3(4), 770-774, (2012) @No $ @ @ Meshram U.P., Narwade M.L. and Yaul A.R., Studies in formation constant of Al(III), Cr(III) and Fe(III) complexes with some substituted isoxazoline, pyrazole and pyrazoline pH-metrically, spectrophotometrycally and polarizibility constant refractometrically, J. Chem. Pharm. Res., 3(3), 77-82 (2011) @No $ @ @ Zaker Y.M., Hossain A. and IslamT.S.A., Adsorption kinetics of methylene blue onto clay fractionated from bijoypur soil, Bangladesh, Res. J. Chem. Sci., 3(2), 65-72 (2013) @No $ @ @ Hirpaye B.Y., Zekarias M.T. and Rao G.N., Chemical speciation studies of binary complexes of malonic acid with some essential biologically important metal ions in 1, 2-propanediol-water mixtures, Journal of Chemical and Pharmaceutical Research,4(3), 1725-1733 (2012) @No $ @ @ Raymond P., Peter P.R., Rajendran S. and Manivannan M., Investigation of corrosion inhibition of stainless steel by sodium tungstate patric, Res. J. Chem. Sci., 3(2), 54-58 (2013) @No $ @ @ Gaikwad M.N., Gaikwad S.T. and Rajbhoj A.S., Potentiometric study of menadione complexes with transition metals in DMSO-Water and DMF-Water medium, J. Chem. Bio. Phy. Sci. Sec., A2(4), 1651-1656 (2012) @No $ @ @ Zaida A.A., Farooquia M. and Janrao D.M., Study of stability constant of biological active molecules (drug) using potentiometric titration technique, J. Chem. Bio. Phy. Sci. Sec. A.,2(1), 67-81 (2012) @No $ @ @ Gangwar M.K. and Saxena A.K., Ultrasonic study of molecular interactions in binary mixtures of isopropylbenzene (Cumene) with Benzene, Toluene and Acetone at 303K, Res. J. Chem. Sci.,3(2), 27-30 (2013) @No $ @ @ Maldhure A.K., Agarkar S.S., Taywade R.K. and Wankhade R.S., Metal-ligand stability constants of Co(II), Ni(II) and Cu(II) metal ion complexes with N-(5-methyl-2-hydroxyacetophenone) - N’ - (2-hydroxyacetophenone)ethylenediamine at 0.1 M ionic strength pH metrically, Journal of Chemical and Pharmaceutical Research,4(8),3865-3868 (2012) @No $ @ @ Anderegg G., Delgado R., Felcman J., and Popov K., Critical evaluation of stability constants of metal complexes of complexones for biomedical and environmental applications, Pure Appl. Chem., 77(8),1445–1495 (2005) @No $ @ @ Patil S.S. and Mirgane S.R., Thermo acoustic study of acrylates with decane-1-ol, Res. J. Chem. Sci., 3(2), 73-78 (2013) @No $ @ @ Onigbinde A.O., Munson B. and Amos-Tautua B.M.W., Gas chromatography/ chemical ionization mass spectrometry of polyethylene glycol monoalkyl ethers,Res. J. Chem. Sci., 3(2), 4-9 (2013) @No <#LINE#>A Concise Report on the Status of Groundwater of Babhnan Town, Basti, UP, India<#LINE#>R.V.@Prasad,D.R.@Tripathi,Vinod@Kumar<#LINE#>80-82<#LINE#>14.ISCA-RJCS-2013-134.pdf<#LINE#>Deptt. of Chemistry, A.N.D. Kisan P.G. College, Babhnan Gonda, UP, INDIA @ Deptt. of Zoology, A.N.D. Kisan P.G. College, Babhnan Gonda, UP, INDIA<#LINE#>7/8/2013<#LINE#>26/8/2013<#LINE#>The Present study deals with the water quality index of ground water of various locations of Babhnan town during Feb-Apr. (2013). Ten water samples from hand pumps at various locations were collected using standard methods and analyzed for pH, turbidity, chloride, total hardness, nitrate, fluoride, iron, and free chlorine. The results shows that the ground water from all sampling sites is very hard and beyond permissible limit provided by WHO. Over all water quality of Babhnan town is very poor and unsuitable for drinking purposes.<#LINE#> @ @ Dhar B.B., Ratan S. and Jamal A., J. mines, metals and fuels, 596 (1986) @No $ @ @ Agrawal R., Physico-chemical analysis of some groundwater sampler of Kotputlu town Jaipur, Rajasthan. International Journal of Chemical Environmental and Pharmaceutical Research, Rajasthan, ), 111-113 (2010) @No $ @ @ Raja R.E., Sharmila, Merlin P. and Chritopher G., Physico Chemical analysis of some groundwater samples of Kotputli Town Jaipur, Rajsthan, India, Indian J. Envirion Port., 22(2), 137 (2012) @No $ @ @ Parihar S.S., Kumar A., Kumar A., Gupta R.N., Pathak M., Shrivastav A. and Pandey A.C., Physico Chemical and microbiogicesf analysis of underground water in and ground Gwalior city, M.P., India, Res. J. Recent Sci., 1(6), 62-65 (2012) @No $ @ @ WHO, International standard for drinking water, 3rd ed.,Geneva (2008) @No $ @ @ BIS, Specification for drinking water, Bureau of Indian standards, New Delhi, 171-178 (1998) @No $ @ @ Behera B., Das M. and Rana G.S., Studies on ground water pollution due to iron content and water quality in and around Jagdalpur, Bastar District, Chattisgarh, India, J.Chem. Pharma Res., 4(8), 3803-3807 (2012) @No $ @ @ Dharmaraja Vadiuel J.S. and Ganeshkarthick E., Physico-Chemical Enalysis of ground water samples of selected districts of Tamilnadu and Kerala, Int.J. of Scientific Tech.Res, 1(5), 92-95 (2012) @No $ @ @ Sehra S., Naz I., Ali M.I. and Ahmed S., Monitoring of physic-chemical and microbiological analysis of under groung water samples of District Kallar Syedan, Rawalpindi-Pakistan, Res.J.Cherm.Sci., 1(8), 24-30 (2011) @No $ @ @ Bundela P.S., Sharma A., Pandey A.K. and Awasthi A.K., Physico analysis of ground watrer near municipal solid waste dumping sites in Jabalpur M.P. India, Int J.of plant animal and Environ. Sci., 2(1), 217-222 (2012) @No $ @ @ Durfor C.N. and Becker E. Public water supplies of the 100 largest cities in the united states, US Geog.Sur. Water supply paper, 1812, 364 (1964) @No $ @ @ Meenakshi Garg, V.K. Kavita, Renuka and Malik A., Ground water quality in some villages of Haryana, India: focus on fluoride and fluorosis, J. Hazard. Mater., 106, 85-97 (2004) @No $ @ @ Veeraputhiran V. and Alagumuthu G., A report on fluoride distribution in drinking water, Int.J.Env.Sc., 1(4), 558-566 (2010) @No $ @ @ Arya S., Kumar V., Minakshi and Dhaka A., Assessment of underground water quality: A Case study of Jhasni City, U.P. India, International multidisciplinary Research Journal, 1(7), 11-14 (2011) @No $ @ @ Vaishnav M.M. and Dewangan S., Assessment of water quality status in reference to statistical parameters in different aquifers of Balco Industrial area, Korba, C.G. India, Res.J.Cherm.Sci.,1(9) , 67-72 (2011) @No $ @ @ Desh Pande S.M. and Aher K.R, Evaluation of ground water quality and its suitability for drinking and agriculture use in parts of Vaijapur, District Aurangabad , MS,India, Res.J.Cherm.Sci., 2(1), 25-31 (2012) @No $ @ @ Patil N., Ahmed A., Suresh Babu H. Kottureshwar N.M., Jayashree M. and J Nijalingappa, Study on the physico-chemical characteristics of ground water of Gulbarga city (Karnataka), Int. J Appli. Biopharm. Tech. 1(2), 518-523 (2010) @No $ @ @ Rajgopal, Ground water quality assessment for public policy in India, 1st Annual report. Deptt. of geography, IOWA University, IOWA, 10-11 (1984) @No <#LINE#>Simple Synthesis of Large pore Mesoporous Iron Substituted Aluminophosphate Molecular Sieves<#LINE#>Devi@M.R.,C.@Kannan<#LINE#>83-85<#LINE#>15.ISCA-RJCS-2013-137.pdf<#LINE#>Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli-627012, Tamilnadu, INDIA<#LINE#>9/8/2013<#LINE#>24/8/2013<#LINE#>Iron containing mesoporous aluminophosphate (FeAlPO) synthesized by simple synthesis using anionic sodium dodecyl sulphate (SDS) as structure directing agent leads to an active, selective and recyclable catalyst for the esterification reaction. This material was characterized by FT-IR, N adsorption desorption, temperature programmed desorption (TPD) and thermal analysis (TG/DTA). The influence of this synthesis procedure makes the material more stable, reusable and it exhibits uniform large pore diameter (27 nm) with the surface area of 116m/g. This material exhibits highly acidic nature and hence the activity of the catalyst FeAlPO was analyzed for esterification of acetic acid and n-butanol in liquid phase and the experimental conditions were determined. The same reaction has been done again to find out the reusability of the catalyst and it is found active with high yield of ester.<#LINE#> @ @ Lisnyak V.V., Ischenko E.V., Stratiichuk D.A., Zaderko A.N., Boldyrieva O.Yu., Safonova V.V.and Yatsymyrskyi A.V., Pt, Pd Supported on Niobium Phosphates as Catalysts for the Hydrogen Oxidation, Res. J. Recent Sci.,3(3), 30-33 (2013) @No $ @ @ Sumathi T., and Kannappan A.N., Ultrasonic Investigation on Sodium and Calcium Tungsten Phosphate Glass System, Res. J. Recent Sci.,2(9), 14-17 (2012) @No $ @ @ Safaee Hoda, Sohrabi Morteza and Falamaki Cavus, Synthesis of Some Baria-Modified -Al2O3 for Methanol Dehydration to Dimethyl Ether, Res. J. Recent Sci.,3(1), 57-62 (2013) @No $ @ @ Kannan C., Devi M.R., Muthuraja K., Esaivani K. and Sudalai Vadivoo V., Green catalytic Polymerization of Styrene in the Vapor phase over Alumina, Res.J.Chem. Sci.,2(7), 1-8 (2012) @No $ @ @ Hartmann M. and Kevan L., Transition metal ions in aluminophosphate and silicoaluminophosphate molecular sieves: location, interaction with adsorbates and catalytic properties, Chem. Rev., 99, 635-663 (1999) @No $ @ @ Weckhuysen B. M., Rao R. R., Marthens J. A., and Schoonheydt R. A., Eur. J. Inorg. Chem., 565-577 (1999) @No $ @ @ Vijayasankar A. V., Deepa S., Venugopal B. R., and Nagaraju N., Amorphous mesoporous iron aluminophosphate catalyst for the synthesis of 1,5-benzodiazipenes, Chin J Catal., 31,1321–1327 (2010) @No $ @ @ Tusar N. N., Logar N. Z., Arcon I., Malia G., Mazaj M., Ristic A., Lazar K., and Kaucic V., Local environment of iron in the mesoporous hexagonal aluminophosphate molecular sieves, Micropor. Mesopor Mater.,87, 52–58 (2005) @No $ @ @ Tiemann M., Schulz M., Jager C., and Froba M., Mesoporous aluminophosphate molecular sieves synthesized under nonaqueous conditions, Chem. Mater.,13, 2885-2891 (2001) @No $ @ @ Karthik M., Vinu A., Tripathi A. K., Gupta N.M., Palanichamy M., Murugesan V., Micropor. Mesopor. Mater.,70, 15–25 (2004) @No $ @ @ Sarshar Z., Zahedi-Niaki M. H., Huang Q., and Kaliaguine S., Synthesis, structural and acidity characterizations of the large-pore zeolite SSZ-42 for controlling cold-start emissions, Micropor. Mesoporous Mater.,118, 373–381 (2009) @No