@Editorial
<#LINE#>Cathodes for Electrochemical Processes (Part - II)<#LINE#>Vasudevan@S<#LINE#>Res.J.chem.sci.<#LINE#>
@Research Paper
<#LINE#>Heavy Metals Removal from Industrial Wastewater by Activated Carbon Prepared from Coconut Shell<#LINE#>E.@Bernard,A.@Jimoh,@,J.O.@Odigure<#LINE#>3-9<#LINE#>1.ISCA-RJCS-2013-087.pdf<#LINE#>Department of Chemical Engineering, Federal University of Technology, P.M.B. 65, Minna, NIGERIA<#LINE#>3/6/2013<#LINE#>20/7/2013<#LINE#> Activated carbon produced from coconut shell (ACS) was used as adsorbent to removeCu2+, Fe2+, Zn2+ and Pb2+ ions from electroplating industrial wastewater. The activated carbon produced was chemically activated with zinc chloride. Batch adsorption experiment was conducted to examine the effects of adsorbent dosage, contact time, pH and stirring rate on adsorption of Cu2+, Fe2+, Zn2+ and Pb2+ from the wastewater. The obtained results showed that, the adsorption of the metal ions was adsorbent dosage, contact time, pH and stirring rate dependent. The optimum adsorbent dosage, stirring rate and pH, were found to be at 1 g, 350 rpm and pH 6 respectively. Kinetic studies showed that pseudo-second-order reaction model best described the adsorption process. The study also showed that activated carbon prepared from coconut shell can be efficiently used as low cost alternative for removal of metal ions.<#LINE#> @ @ Mehmet E.A., Sukru D., Celalettin O. and Mustafa K., Heavy metal adsorption by modified oak sawdust, J. of Hazard. Mater,In Press(2006) @No $ @ @ Chand S., Aggarwal V.K. and Kumar P. Removal of Hexavalent Chromium (1994) @No $ @ @ Iqbal Ahmad, J.Appl. Sci. Enviorn.Mgt., 9(1), 123-126 (2005) @No $ @ @ Kadirvelu K., Thamaraiselvi  K. and Namasivayam C., Bioresource Techn., 76, 63-65 (2001) @No $ @ @ Vaishnav V., Daga K., Chandra S. and Lal M., Adsorption Studies of Zn (II) ions from Wastewater using Calotropis procera as an Adsorbent, Res.J.Recent.Sci., 1, 160-165 (2012) @No $ @ @ Abia A.A. and Igwe J.C., Sorption Kinetics and Intraparticulate diffusivities of Cd, Pb, and Zn ions on Maize Cob, J. of Biotech., 4(6), 509-512 (2005) @No $ @ @ Gueu S., Yao B., Adouby K. and Ado G., Heavy metals removal in aqueous solution by activated carbons prepared from coconut shell and seed shell of the palm tree, J. Appl.Sci.,6 (13), 2789-2793 (2006) @No $ @ @ Senthilkumar P. and Kirthika K.,Kinetics and Equilibrium studies of Zn2+ Ions removal from aqueous solutions    by use of Natural Waste,  EJEAF Che.,9(1), 264-265 (2010) @No $ @ @ Chowdhury Z., Zain S.M. and Rashid A.K., Equilibrium Isotherm Modeling, Kinetics and Thermodynamics Study for Removal of Lead from Wastewater, J. of Chem.Sci.,8 (1), 333-339 (2010) @No $ @ @ Horsfall M. J.,  Abia A. A. and Spiff A. I., Kinetic Studies on the adsorption of Cd2+, Cu2+ and Zn2+ Ions from aqueous solutions by Cassava (Manihot esculenta) Tuber Bark Waste, J. of Biores Technol.,97, 283-291 (2006) @No $ @ @ Gopalakrishnan S., Kannadasan T., Velmurugan S., Muthu S. and Vinoth Kumar P, Biosorption of Chromium (VI) from Industrial Effluent using Neem LeafAdsorbent, Res. J. Chem. Sci 3(4), 49 @No $ @ @ Ekpete O. A., Kpee F., Amadi J. C. and Rotimi R. B., Adsorption of Chromium (VI) and Zinc (II) Ions on the Skin of Orange Peels, J. of Nep Chem Soc., (26), 32-38 (2010) @No $ @ @ Onyeji L. I. and Aboje A. A., Removal of Heavy Metals from Dye Effluent using activate carbon produced from Coconut Shell, Int. J. of Eng Sci and Technol., 3(12),  8240-8243 (2011) @No $ @ @ Norhafizahbinti A., Nurul A., Imibinti R. and Wong C., Removal of Cu (II) from Water by Adsorption on Papaya Seed, Asian Trans on Eng., 1(5), 49-50 (2011) @No $ @ @ Jain K.K., Guru P. and Singh V., J. of ChemTechnol Biotech.,29, 36–38 (1979) @No $ @ @ Ho Y. S. and Mckay G., A Comparison of Chemisorption Kinetic, Models Applied to Pollutant Removal     On     various Sorbents, J. of Inst of Chem Eng Trans.,76, 332-340 (1998b) @No $ @ @ Rafeah W., Zainab N. and Veronica U., Removal of Mercury, Lead and Copper from aqueous solution by     activated carbon of Palm Oil Empty Fruit Bunch, World Applied Sci J,, 84-91 (2009) @No $ @ @ 8.Abbas S.T, Mustafa M., Al-Faize and Rah A.Z., Adsorption of Pb2+ and Zn2+ ion from oil wells onto activated carbon produced from Rice Husk in batch adsorption process, J. Chem. Pharm. Res.,5(4), 240-250 (2013) @No $ @ @ Lohani M.B., Singh A., Rupainwar D.C. and Dhar D.N., Studies on efficiency of guava (Psidiumguajava) bark as bioadsorbent for removal Hg(II) from aqueous solutions, J. of Hazard Mater.,159, 626-629 (2008) @No $ @ @ Atkins P.W., Physical Chemistry. 5th Edition, New York, Oxford University Press, 122-124 (1995) @No
<#LINE#>Characterization of Aluminosilicates (Zeolites) by Laboratory Screening Tests for Selective Synthesis of Value Added Products: Case Studies<#LINE#>V.R.@Chumbhale<#LINE#>10-17<#LINE#>2.ISCA-RJCS-2013-090.pdf<#LINE#>Catalysis and Inorganic Chemistry Division, CSIR-National Chemical Laboratory, Pune-411008, INDIA<#LINE#>5/6/2013<#LINE#>28/7/2013<#LINE#> Synthetic zeolites are widely used in chemical industries for the manufacture of value added products because of their acidic and sorption properties. In this work zeolite mordenite metal impregnated mordenites catalyst’s samples are investigated for alkylation of benzene to cumene. The effect of varying process parameters and different alkylating agents on conversion and selectivity are presented. The alkylation of aniline with methanol to Monomethyl aniline (NMA) and N, N DMA (dimethyl aniline) is also studied. The Arrhenius activation energy for parent and modified catalysts are compared and discussed considering the extent of modifier species.<#LINE#> @ @ Mishra S.R., Mohanty M.K., Das S.P. and Pattanaik A.K., Production of biodiesel (methyl ester) from simarouba glauca oil, Res.J.Chem.Sci 2(5), 66-71 (2012) @No $ @ @ Narayanappa madhusudhana, Kambalagere Yogendra and Kittappa M. Mahendran, Photocatalytic degradation of violet GL2B azo dye by using calcium acuminate nanoparticle of solar light, Res.J.Chem.Sci., 2(5), 72-77 (2012) @No $ @ @ Lisnyak V.V., Safono VA V.V., Ischenko E.V., Stratiichuk O.A., Boldyrievao.Yu and Yatsymyrsky A.V., Preparation and activity of Pt (Pd) /WP catalysts for H oxidation, Res.J.Chem.Sci. 2(6), 50-54 (2012) @No $ @ @ Diwya, Iyengar puspa and Ramachandrappa R., Oxidation of tranexamic acid by bromamine T in HCl medium catalyzed by RuCl: A kinetic and mechanistic approach, Res.J.Chem.Sci., 2(7), 7-15 (2012) @No $ @ @ Kannan C., Devi M.R., Muthuraja K. Esaivani K. and Sudalai Vadivoo V., Green catalytic polymerization of styrene in the vapor phase over alumina, Res.J.Chem.Sci. 2 (7), 27-35 (2012) @No $ @ @ Chandrasekar, Venkatesha B.M., and Ananda S., Kinetics of oxidation of vitamin-B (Niacin) by sodium N-bromo benzenesulphonamide (bromamine-B) in HCl medium and catalysis by Ru (III) ion, Res.J.Chem.Sci., 2 (8), 26-30 (2012) @No $ @ @ Deshpande D.P., Urunkar Y.D. and Thakare P.D., Production of biodiesel from castor oil using acid and base catalysts, Res.J.Chem.Sci., 2(8) 51-56 (2012) @No $ @ @ Deshpande D.P., Warfade V.V., Amaley S.H., and Lokhande D.D., Petro-chemical feed stock from plastic waste, Res.J .Recent.  Sci. 1(3), 63-67 (2012) @No $ @ @ Mishra Sruti Ranjan, Mohannanty Mahrndra Kumar and Pattanaik Ajay Kumar, Preparation of biodiesel from crude oil of simarouba glauca using Cao as a solid base catalyst, Res. J. Recent Sci., 1(9), 49-53 (2012) @No $ @ @ Patel Fernina and Patel Sanjay, Carbon monoxide oxidation on LaCoO perovskite type catalysts prepared by reactive grinding, Res. J. Recent Sci., 1(ISC-2011), 152-159 (2012) @No $ @ @ G. Centi, P. Ciambelli, S. Perathoner and P. Russo, Environmental catalysis: trends and outlook, Catalysis Today 75, 3 (2002) @No $ @ @ Meier W.M. and Olson D.H., Atlas of Zeolite Structure Type, Butterworths, London (1987) @No $ @ @ Bajpai P.K. Synthesis of mordenite type zeolite, Zeolites 6 (1), 2-8 (1986) @No $ @ @ Babu G.P., Hegde S.G. and Ratnasamy P., Active centres over HZSM5 zeolites: I. Xylene isomerization, J.Catal 81(2) , 471-477  (1983) @No $ @ @ Das D., Mishra H.K., Dalal A.K.,  and Parida K.M.,  Isopropylation of benzene over sulfated ZrO–TiO
mixed-oxide catalyst, Appl Catal A: Gen 243(2) 271-284 (2003) @No $ @ @ Bronwer D.M. and Hogeveen H., Prog. Phy.Org.Chem, 9,179 – 183 (1972) @No $ @ @ Rao G.N., Joshi P.N., Kotastane A.N. and V.P.Shiralkar V.P., Sorption properties of EU-1 zeolites, J.Phy.Chem. 94 (23), 8589- 8593  (1990) @No $ @ @ Kaeding W.W. Young L.B., Chu C. C, Weinstein B and Butter S.A., Selective alkylation of toluene with methanol to produce para-xylene, J.Catal, 67(1) ,  159-174  (1981) @No $ @ @ Meier W.M., Molecular Sieves, Soc of Chem Ind, London (1968) @No 
<#LINE#>A Simple and Effective method of the Synthesis of Nanosized Cu0.5Zn0.5Fe2O4 Particles<#LINE#>AvnishKumar@Arora,@Ritu<#LINE#>18-28<#LINE#>3.ISCA-RJCS-2013-103.pdf<#LINE#>Department of Chemistry, Maharishi Markendeshwer University, Mullana -133203, Haryana, INDIA<#LINE#>24/6/2013<#LINE#>1/8/2013<#LINE#> Nanosized Copper-zinc ferrites Cu0.5Zn0.5Fe have been synthesized by aqueous precipitation method and characterized by using XRD (X-ray diffraction), TGA/DTA (Thermo gravimetric analysis), SEM (Scanning Electron Microscopy)/ TEM (Transmission Electron Microscopy) and magnetic measurements by using VSM (vibrating sample magnetometer). XRD studies confirm the formation of cubic spinnel structure. SEM (scanning electron microscopy)/ TEM (transmission electron microscopy) was used to characterize the microstructure of the ferrite samples. A homogeneous and fine grain microstructure was found. Magnetic measurements shows that Ni05Cu0.5Fe is super paramagnetic in nature at room temperature and hence used in magnetic device. The particle size of synthesized Cu05Zn0.5Fe varied from 18nm to 68nm which is good agreement of the theoretically predicted size of nanomaterials. The method is easier more effective and convenient in comparison to the known methods of the synthesis Cu05Zn0.5Fe nano materials like combustion synthesis, thermal cracking and conventional ceramic methods.<#LINE#> @ @ Sayed A.M.El, Ceramics International, 28, 363-367 (2000) @No $ @ @ Ravinder D., Vjaya Kumar K.and Boyanov B.S., Material Letters, 38, 22-27(1999) @No $ @ @ Islam M.U., Ahmad I., Abbas T. and Chaudhry M.A.,6th International Symposium on advanced materials, 155-158(1999) @No $ @ @ David Lide R., Handbook of chemistry and physics, CRC Press, New York (1995) @No $ @ @ Goldman A., Modern Ferrite Technology, Van Nostr and Reinhold, New York (1990) @No $ @ @ Gonzalez Angeles A., Mendoza-Suarez G., Gruska A., Papanova M. and Slama J., Materials letters, 59, 20-31 (2005) @No $ @ @ Monica Sorescu, Diamandescu L., Peelamendu R., Roy R.and Yadoji P., Journal of Magnetism and Magnetic Materials,279, 195-201 (2000) @No $ @ @ Bayliss P., Erd D.C., More Annp Sabina M.E. and Smith D.K., Mineral Powder diffraction file, JCPDS, USA (1986) @No $ @ @ Moinuddin M.K. and Murthy S.Ramana, Journal of Alloys and Compounds, 194105-107, JALCOM 539 (1993) @No $ @ @ Martha Pardavi-Horvath, Journal of magnetism and Magnetic Materials, 215-216,171-183 (2000) @No $ @ @ Noborce Ichinose, Introduction to fine ceramics, Ohmsa (publisher) Ltd. Japan (1987) @No $ @ @ Hussain S.S., Kamran M., Dr. A.Q. Khan on scienceand education, Niaz Ahmad (Publishers) Ltd., Lahore, Pakistan (1997) @No $ @ @ Lawrence Van H. Vlack, Elements of material science and Engineering, 6th Ed. Addison-Wesley Co (Publishers) Ltd. New York (1989) @No $ @ @ Heck Dr. Ing. Carl, Magnetic Materials and their applications, Butterworth Co. (Publishers) Ltd. London 1974) @No $ @ @ Shah Dr. Muzaffer Ali, Electricity and Magnetism, edited by Dr. Muzaffer Ali Shah Sh.Ghulam Ali and Sons (Publisher) Ltd., Lahore, Pakistan (1971) @No $ @ @ Chickazumi S. and Charap S.H., Physics of magnetism, Krieger Malabar (1978) @No $ @ @ Smith William F., Principles of material science and Engineering, 2nd Ed., Mc Graw Hill Co. (Publishers) New York  (1986) @No $ @ @ Snelling E.C., Soft Ferrites properties and applications, Butterworth and co. (publishers) Ltd. London (1988) @No $ @ @ Goldman A., Modern ferrite technology, Van Nostrand Reinhold, New York (1990) @No $ @ @ William H. Von Aulock, Handbook of microwave ferrite materials, Academic press, New York, London (1965) @No $ @ @ WWW.Ferrite web.com (2013) @No $ @ @ Jakubocics J.P., Magnetism and magnetic materials, ndEd., Institute of materials, London, (1994) @No
<#LINE#>Electrochemical study of Mn2  Redox System on 4-hydroxybenzylidene-Carbamide -CTAB modified Glassy Carbon Electrode<#LINE#>Ramalakshmi@N.,Muthukumar@S.,B.@Marichamy<#LINE#>29-37<#LINE#>4.ISCA-RJCS-2013-106.pdf<#LINE#>Post-graduate and Research Department of Chemistry, Presidency College, Chennai, Tamil Nadu, INDIA<#LINE#>25/6/2013<#LINE#>7/7/2013<#LINE#>The 4-hydroxybenzylidenecarbamide-cetyltrimethylammoniumbromide modified glassy carbon electrode (ligand-CTAB/GCE) is prepared by drop coating technique. The complexation effect of Mn2+ with the ligand is studied through scan rate effect, concentration effect in cyclic voltammetry technique. Transfer coefficient number (n) of Mn2+ ion on ligand-CTAB/GCE is found to be 0.204. The surface concentration of electroactive species () on ligand-CTAB/GCE was found to be 0.9436 x 10-8 molcm-2. The rate constant for manganese ion redox system is first order and found to be 1.857s-1. The optimum pH for manganese redox system on ligand-CTAB/GCE is found to be 6. The interference of Cu2+, Cd2+ and Hg2+ions on manganese redox system is investigated through the interference study. Cyclic voltammetry, chronoamperometry and chronocoulometry study shows that manganese redox system has diffusion controlled process. The stability of the film on GCE is investigated through the multisweep cycle experiment and is found to be stable.<#LINE#> @ @ Brown A.G. and Roberty S.M., The Royal Society of Chemistry, London (ed.) (1984) @No $ @ @ Anacona J.P., Synthesis and Antibacteiral activity of some metal complexes of Beta lactamic antibiotics,  J.Coord.Chem., 54, 355-365 (2001) @No $ @ @ Forghierri F., Preti C., Tosi G., Zonnini P., Antibiotics as ligands. The coordinating abilitiy of deprotonated cycloserine towards transition metals, Aust.J.Chem., 36, 1125 (1983) @No $ @ @ Al-Yu Shen, Shen-Nan Wu, Chih-Tsao Chiu., Synthesis and cytotoxicity evaluation of some 8-hydroxyquinoline derivatives,  J.Pharm.Pharmcol51, 543 (1999) @No $ @ @ Plarsic M., Krznaric D. and Cosoric B., The electrochemical process of copper in the presence of triton-x-100, Electroanalysis 6, 469 (1994) @No $ @ @ Rusling J.F. and Nassar A.F., Enhanced electron transfer for myoglobin in surfactant films on electrodes, J.Am.Chem.Soc., 115, 11891 (1993) @No $ @ @ Yang J., Hu N.F. and Rusling J.F., Enhanced electron transfer for hemoglobin in poly(ester sulphonic acid) films on pyrolytic graphite electrodes, J.Elecroanal.Chem, 46353 (1999) @No $ @ @ Scholz F. and Lange B., Abrasive stripping voltammetry-an electrochemical solid state spectroscopy of wide applicability, Trends in Analytical Chemistry,11, 359 (1992) @No $ @ @ Tan W.T., Ng G.K. and Bond A.M., Electrochemical oxidation of microcrystalline tetrathiafulvalene (TTF) at an electrode-solid-aqueous (KBr) interface, Malaysian. J. Chem.,  2, 34 (2000) @No $ @ @ Shap M., Peterson M. and Eelstrain K., Preliminary determinations of electron transfer kinetics involving ferrocene covalently attached to a platinum surface,  J.Electroanal.Chem.,95, 123 (1979) @No $ @ @ Laviron E., General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems, J.Electroanal.Chem., 101, 19 (1979) @No $ @ @ Cotton F.A. and Wilkinson G., Advanced Inorganic Chemistry, Fifth edition, John Wiley and Sons (1998) @No $ @ @ Radhi M.M., Tan W.T., M.Z.B.Ab. Rahman and Kassim A.B., Electrochemical reduction of Mn(II) mediated by 60/Li modified glassy carbon electrode, Int.J.Electrochem.Sci.,  254-266 (2010) @No $ @ @ Bard A.J. and Faulknev L.R., Electrochemical methods, Fundamentals and Applications, wiley, New York (2001) @No $ @ @ J.Ph.pititpierre, ch.Comninellis, E.Plattner, Oxidation Du MnSO en dioxyle manganese ions HSO 30%, Electrochim Acta. 35 281(1990) @No
<#LINE#>Synthesis, Characterization and Solvatochromic studies of 3-{2-(5-Bromothiazol-2-yl) diazeny l}-4-Bromopyridine-2, 6-Diamine<#LINE#>Savanor@PrasannaM.,Keshavayya@Jathi,K.@BhatSubramanya,N.Rajesh@Tantry<#LINE#>38-43<#LINE#>5.ISCA-RJCS-2013-110.pdf<#LINE#>Department of Chemistry, Kuvempu University, Shankaraghatta 577 451, Karnataka, INDIA <#LINE#>2/7/2013<#LINE#>8/7/2013<#LINE#> The 3-{2-(5-bromothiazol-2-yl)diazenyl}-4-bromopyridine-2,6-diamine was synthesized by carrying the diazotization of 5-bromothiazol-2-amine in coupling with 4-bromopyridine-2, 6-diamine as a coupling component to yield a azo dye. The structure of the dye was confirmed by UV-visible spectrophotometry, Fourier Transfer Infrared spectroscopy (FTIR), LC-MS, H and 13C NMR spectroscopic methods. The change in the absorption maxima of the synthesized compound in different solvents were determined, the solvatochromic property of the dye showed a medium red shift in different solvents and has shown the moderate solvent dependency over the bathochromic shift.<#LINE#> @ @ Ahmed K.A., Elhennawy H.M. and Elkashouti M.A., Microwave Assists the Synthesis of Pyridone azo Dyes and their Application in Polyester Printing, Research Journal of Chemical Sciences 2(11), 14-19 (2012) @No $ @ @ El- Kashouti M.A., Tawfik S.S., Ahmed K.A., Mohamed Sh. S., Application of the synthesized Arylazopyrazolopyrimidine dyes in Printing Polyester and Polyamide Fabrics, Research Journal of Chemical Sciences, 2(9), 79-89 (2012) @No $ @ @ Ravi R. Vidule, Shirodkar S.G., Synthesis and Antimicrobial studies of few New Substituted 2-methyl-3-(aryldiazenyl) pyrazolo[5,1-b]quinazolin-9(3H)-ones, Research Journal of Chemical Sciences, 3(6), 60-68 (2013) @No $ @ @ Hyeyoung P., Eung-Ryul K., Dong J K., and Haiwon L.,Synthesis of Metal-Azo Dyes and Their Optical and Thermal Properties as Recording Materials for DVD-R, Bulletin of the Chemical Society of Japan, (75), 2067–2070(2002) @No $ @ @ Hans-Tobias M., Eduard M., Ruediger B., Pflieger D and Bansi L K., Use of Iron azo complex compound a charge controllagents, US-PATENT2002/0028401 A1 1-10 (2002) @No $ @ @ Kazuhito Watanabe, Numazu., ToshikiNanya, Mishima, Toner for developing electrostatic latent imageUS-PATENT5,597,673, 1-14 (1997) @No $ @ @ Ryuzo Ueno Nishinomiya, Masaya Kitayama Takarazuka, Kenji Minami Sennan, Hiroyuki Wakamori, Hyogo-ken, Azo compounds and process producing the same, US-PATENT6,409,812 B1, 1-6 (2002) @No $ @ @ Birkett K.L and Gregory P., Metal Complex Dyes as Charge Control Agents, Dyes and Pigments, (7), 341-350, (1986) @No $ @ @ Ashkar S.M., El-Apasery M.A., Touma M.M. and Elnagdi M.H., Synthesis of Some Novel Biologically Active Disperse Dyes Derived from 4-Methyl-2,6-dioxo-1-propyl-1,2,5,6-tetrahydropyridine- 3-carbonitrile as Coupling Component and Their Colour Assessment on Polyester Fabrics,  Molecules, (17), 8822-8831 (2012) @No $ @ @ Khosravi A., Moradian S., Gharanjig K., Afshar T.F., Synthesis and spectroscopic studies of some naphthalimide based disperse azo dyestuffs for the dyeing of polyester fibres, Dyes and Pigments, (69), 79-92 (2006) @No $ @ @ Metwally M.A., Abdel-Galil E, Metwally A and Amer F. A., New azodisperse dyes with thiazole, thiophene, pyridone and pyrazolone moiety for dyeing polyester fabrics,  Dyes and Pigments, (92), 902-908 (2012) @No $ @ @ Arcoria A., Cerniani A., Giorgi R. D., Longo M. L and Toscanoa R. M., Carrier dyeing of polyester fibre with some disperse azo dyes, Dyes and Pigments(11), 269-276 (1989) @No $ @ @ Ertan N., Synthesis of some hetarylazopyrazolone dyes and solvent effects on their absorption spectra, Dyes and Pigments, 44(1), 41-48 (1999) @No $ @ @ Ertan N. and Eyduran F., The synthesis of some hetarylazopyridone dyes and solvent effects on their absorption spectra. Dyes and Pigments, 27(4), 313-320 (1995) @No $ @ @ Snavely F.A. and Yoder C.H., Study of tautomerism in arylazopyrazolones and related heterocycles with nuclear magnetic resonance spectroscopy, Journal of Organic Chemistry, 33(2), 513-516 (1968) @No $ @ @ Lestina G.J. and Regan T. ., Determination of the azo-hydrazonotautomerism of some 2-pyrazolin-5-one dyes by means of nuclear magnetic resonance spectroscopy and 15N-labeled compounds, Journal of Organic Chemistry, 34(6), 1685-1686 (1969) @No $ @ @ Saylam A., Seferoglu Z and Ertan N., Synthesis and spectroscopic properties of new hetarylazo 8-hydroxyquinolines from some heterocyclic amines, Dyes and Pigments, 76(2), 470-476 (2008) @No $ @ @ Gary M., Allan J G., Joseph B C., Kevin B., Michael M., Cooke G., Vincent M R., Model Systems for Flavoenzyme Activity: Interplay of Hydrogen Bonding and Aromatic Stacking in Cofactor Redox Modulation, Organic letters 6(3), 385-388 (2004) @No
<#LINE#>Removal of Cr(VI), Cu(II), Pb(II) and Ni(II) from Aqueous Solutions by Adsorption on Alumina<#LINE#>S.Sheeba@Thavamani,Rajkumar@R.<#LINE#>44-48<#LINE#>6.ISCA-RJCS-2013-112.pdf<#LINE#>PG and Research Department of Chemistry, V.O. Chidambaram College, Tuticorin- 628008, Tamilnadu, INDIA @ PG and Research Department of Chemistry, Aditanar College of Arts and Science, Trichendur- 628216, Tamilnadu, INDIA<#LINE#>4/7/2013<#LINE#>21/7/2013<#LINE#>The extent of removal of heavy metal ions (Chromium, copper, lead and nickel) by adsorption on alumina has been investigated. Adsorption experiments were performed in batch technique from synthetic solutions using alumina as adsorbent.  Several experimental parameters that affect the extent of adsorption of the metal ions of interest have been investigated such as adsorbent dosage, concentration of the adsorbate, contact time, temperature and pH of the system under study.  The equilibrium nature of the adsorption of the metal ions at different concentrations has been followed by Freundlich and Langmuir adsorption isotherms. This work proposes a cost-effective method for the efficient removal of Cr(VI), Cu(II), Pb(II) and Ni(II)from aqueous solutions. The conditions required for effective removal have been optimized.<#LINE#> @ @ Doina A., Laura B., Elena B., Lead (II) removal from aqueous solutions by adsorption onto chitosan, Cellul. Chem. Technol.,43(4-6), 211-216 (2009) @No $ @ @ Oladoja N.A., Aboluwoye C.O., Oladimeji Y.B., Kinetics and Isotherm studies on methylene blue adsorption onto ground palm kernel coat, Turkish J. Eng. Env. Sci., 32, 303-312 (2008) @No $ @ @ Yahya S., Musa I., Amjad H., Gavin M., Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon, Dyes and Pigments, 20, 1-8 (2007) @No $ @ @ Nikam G.H. and Mohite B.S., Liquid-Liquid extraction and separation of Cobalt(II) from sodium acetate media using Cyanex 272, Res. J. chem. Sci.,2(1), 75-82 (2012) @No $ @ @ Nandkumar D.V. and Lawrence T.L., Zinc, Cadmium and Lead Separation from aqueous streams using solid – phase extract ants, Ind. Eng. Chem. V, 36, 399–406 (1997) @No $ @ @ Vedula R.K. and Balomajumder C., Simultaneous Adsorptive Removal of Cyanide and Phenol from Industrial Wastewater: Optimization of Process Parameters, Res.J.chem.sci.,1(4), 30-39 (2011) @No $ @ @ Nirmal Kumar J.I., Cini O., Removal of heavy metals by biosorption using fresh water alga Spirogyra hyaline, J. Environ. Biol., 33, 27-31 (2012) @No $ @ @ Kadirvelu K., Kavipriya M., Karthika C., Radhika M., Vennilamani N., Pattabhi S., Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions, Bioresour. Technol.,87(1), 129-132 (2003) @No $ @ @ Murhekar G.H., Assessment of Physico-Chemical Status of Ground Water Samples in Akot city Res. J. chem. sci.,1(4), 117-124 (2011) @No $ @ @ Shabudeen P.S.S., Study of the Removal of Malachite Green from Aqueous Solution by using Solid Agricultural Waste, Res.J.chem.sci.,1(1), 88-104 (2011) @No $ @ @ Vengris T., Binkiene R., Sveikauskaite A., Nickel, Copper and Zinc removal from wastewater by a modified clay sorbent, Appl. Clay Sci., 18(3–4), 183–190 (2001) @No $ @ @ Newton D.F.L., Adsorption of Copper(II) and Cobalt(II) Complexes on a silica gel surface chemically modified with 3-amino-1, 2,4-triazole, Colloids Surf., A,1441–3), 219 – 227 (1998) @No $ @ @ Meenakshi G., Rattan V.K., Bansal R.C., Removal of Copper from aqueous solutions by adsorption on activated carbons, Colloids Surf., A,1903), 229–230 (2001) @No $ @ @ Gottipatti R. and Mishra S., Application of Response surface Methodology for Optimization of Cr(III) and Cr(VI) Adsorption on Commercial Activated carbons, Res.J.chem.sci.,2(2), 40-48 (2012) @No $ @ @ Bin Y., Alka S., Shyam S.S., Kenneth D.L., The Removal of heavy metal from aqueous solutions by sawdust adsorption – Removal of copper, J. Hazard. Mater.,  801-3), 33–42 (2000) @No $ @ @ Ramiro J.E.M., Rosano P., Rui A.R.B., Cadmium(II) and Zinc(II) adsorption by the aquatic moss Fontinalis antipyretica: effect of temperature, pH and water hardness, Water Res.,38(3), 693-699 (2004) @No $ @ @ Jaroniec M., Adsorption on heterogenenous surfaces: The exponential equation for the overall isotherm, Surf. Sci.,50(2), 553-564 (1975) @No $ @ @ Charles H.G., David S., A treatment and classification of the solute adsorption isotherm, J. Colloid Interface Sci.,47(3), 755-765 (1974) @No
<#LINE#>Determination of optimum period of Saccharification of water hyacinth using Trichoderma Reesei and Aspergilus Niger<#LINE#>HariNarayanan@Rangarajan,SathvikV.@Varma,Kamala@Krishnappa,J.Shivashankar@Basavara,J.H.@Patil<#LINE#>49-52<#LINE#>7.ISCA-RJCS-2013-113.pdf<#LINE#>Department of Chemical Engineering, R.V. College of Engineering, Bangalore-560059, INDIA<#LINE#>4/7/2013<#LINE#>22/7/2013<#LINE#> Alternative energy sources like bioethanol have become increasingly important in the recent past due to rapidly depleting oil reserves. Lignocellulosicfeedstocks are considered as an attractive raw material for bioethanol synthesis. Water hyacinth, an aquatic weed, tolerates variation in pH and temperature and is unaffected by toxic substances. It has high growth rates and creates problems to ecosystems and irrigation, which have called for control measures. It is found to be a suitable substrate for bioethanol production due to high cellulose and low lignin content. The two major steps involved in the conversion processes are Saccharification and Fermentation. This paper focuses on the experimental work carried out in the Saccharification stage. Pretreated Water hyacinth was added to the growth media and inoculated with Saccharification micro-organisms Trichoderma Reesei and Aspergillus Niger in different conical flasks. The optimum Saccharification period for both micro-organisms was found to be 72 hours. On testing, it was found that both organisms were capable of producing glucose, with Trichoderma Reesei (275 µg/ml) giving a better yield than Aspergillus Niger (175 µg/ml).  <#LINE#> @ @ Patil J.H., MolayanLourdu Antony Raj, Bhagyashree, Vantimar Dinesh and Rohith., Kinetic Modeling of Anaerobic Co-digestion of Water Hyacinth and  Poultry Litter, Research Journal of Chemical Sciences, 3(6), 69-73 (2013) @No $ @ @ GO. Ogawa Masami, Ishida YukinariUsui and Naoto Urano., Ethanol production from the water hyacinth Eichhornia crassipes by yeast isolated from various hydrospheres, African Journal of Microbiology Research, (2), 110-113 (2008) @No $ @ @ Lynd L.R., Production of ethanol from lignocellulosic materials using thermophilic bacteria: critical evaluation of potential and review, Advances in Biochemical Engineering / Biotechnology, 38, 1–52 (1989) @No $ @ @ Parisi F., Advances in lignocellulosics hydrolysis and in the utilization of the hydrolysates, Advances in Biochemical Engineering / Biotechnology, 38, 53–87 (1989) @No $ @ @ Anjanabha Bhattacharya and Pawan Kumar,  Water hyacinth as a potential biofuel crop, Electronic Journal of Environmental, Agricultural and food chemistry,(2010) @No $ @ @ Nigam J.N., Bioconversion of water-hyacinth (Eichhornia crassipes) hemicellulose acid hydrolysate to motor fuel ethanol by xylose–fermenting yeast, Journal of Biotechnology, 97,107–116 (2002) @No $ @ @ Lynd L.R., Overview and evaluation of Fuel ethanol from cellulosic Biomass, Annual Review of Energy and the Environment, 21, 403–65 (1996) @No $ @ @ Sunitha Mukhopadhyay and Narayan Chandra Chatterjee, Bioconversion of water hyacinth hydrolysate into ethanol, Bioresources, 5(2), 1301-1310 (2010) @No $ @ @ Yi Zhenget All, Overview of biomass pretreatment for cellulosic ethanol production, International Journal of Agricultural & Biological Engineering,2(3), 51 (2009) @No $ @ @ Pillai Raji K., Natarajan P. and Kurup G.M. Bioconversion of ligno-cellulosic residues of water hyacinth to commercial product, International Biannual journal of Environmental Sciences, 2(2), 261 - 264 (2008) @No
<#LINE#>Physico-Chemical Analysis and Microbial Degradation of Spent Wash from Sugar Industries<#LINE#>Chandrakant@Mane,Kedar@Rokade<#LINE#>53-56<#LINE#>8.ISCA-RJCS-2013-114.pdf<#LINE#>Shri Vijaysinha Yadav Arts and Science College, Peth Vadgaon, Dist. Kolhapur-416112, MS, INDIA<#LINE#>8/7/2013<#LINE#>21/7/2013<#LINE#>Distilleries are responsible for the generation of ecotoxic wastewater spent wash. Spent wash contains caramel, melanoidin and much more toxic chemicals. Melanoidin is a recalcitrant pigment responsible to give brownish colour to spent wash. In this study the physicochemical properties of spent wash effluent are studied. The isolated indigenous bacterial strain K was selected for the study of melanoidin degradation. Spent wash dilution up to 20% was used to study the degradation of melanoidin by means of isolated bacterial strain. The maximum degradation of about 55% was observed by use of isolated strain K5. This study shows that by analyzing physicochemical parameters and using indigenous bacterial strains biodegradation of spent wash contaminated land or water can be possible.<#LINE#> @ @ Kalaiselvi P. and Mahimairaja S., Effect of Biomethanated Spent Wash on Soil Enzymatic Activities,  BRI.,2 (4),267-272 (2009) @No $ @ @ Rath P., Pradhan G., Misra M.K., Effect of distillery spent wash(DSW) and fertilizer on growth and chlorophyll content of sugarcane (Saccharrum officinarum L.) plant,RecentRes. Sci. and Technol., 3(4), 169-176 (2011) @No $ @ @ Diangan Jr., Perez M.T., and Claveria R., Analysis of land application as a method of disposal of distillery effluent, Int. J. Env. Health.,,258- 271 (2008) @No $ @ @ Moosvi S., Keharia H., Madamwar D., Degradation of textile dye reactive violet 5 by a newly isolated bacterial consortium RVM 11.1, World J. Microbiol. Biotechnol.,21, 667–672 (2005) @No $ @ @ Kumar V., Wati L., Nigam P., Banat I.M., Yadav B.S, Singh D., Marchant R., Degradation and biodegradation of anaerobically treated digested sugar cane molasses spent wash effluent from biomethanation plants by white rot fungi, Proc. Biochem.,33,83–88 (1998) @No $ @ @ Gahlot D.K., Kukreja K., Suneja S., and Dudeja S.S., Effect of digested distillery spent wash on nodulation, nutrient uptake and photosynthetic activity in chick pea (Cicer arietinum), Acta. Agronomica. Hungarica.,59(1), (2011) @No $ @ @ Agarwal R., Sneh Lata, Gupta M and Pratibha Singh.,Removal of melanoidin present in distillery effluent as a major colorant: A Review, J. Environ. Biol.,31, 521-528 (2010) @No $ @ @ Yedla S., Mitra A., Bandyopadhyay M., Purification of pulp and paper mill effluents using Cichornia crassipes, Environ. Technol., 23,453-465 (2002) @No $ @ @ Eriksson K.E., Grunewald A. Vallander L., Studies on growth conditions for three white rot fungi and their cellulose mutants, Biotechnol and Bioeng., 22, 363-368 (1980) @No $ @ @  Victorio L., Allen D.G., Gilbride K.A., Liss S.N., Rapid monitoring of metabolic and biodegradation activity of microbial communities in wastewater treatment systems, Water Res.,30, 1077–1086 (1996) @No $ @ @ Manivasakam N., Physico-chemical Examination of Water, Sewage and Industrial Effluent, 3rd ed., Pragati Prakashan, Meerut, India (1996) @No $ @ @  Maiti S.K., Handbook of methods in environmental studies, 1st ed. ABD  Publisher, Jaipur (2001) @No $ @ @ Kumar V., Wati L., Fitzgibbon F., Nigam P., Banat I.M., Biorenmediation and degradation of anaerobically digested distillery spent wash, Biotechnol let.,19, 311-313 (1997) @No $ @ @ Rokade K.B., Mali G. V., Biodegradation of chlorpyrifos by Pseudomonas desmolyticum NCIM 2112, Indian J of pharma and biosci.,4(2), (B) 609 – 616 (2013) @No $ @ @  Shah V., Joshi J.B., Kukarni P.R., Aerobic biological treatment of alcohol distillery waste: kinetics and microbiological analysis, Indian chem. eng.,,67-66 (1989) @No $ @ @  Ghosh M., Verma S.C., Mengoni A., and Tripathi A.K., Enrichment and identification of bacteria capable of reducing COD of anaerobically treated molasses spent wash, J Appl Microbiol.,10,1-9 (2004) @No $ @ @  Rodriguez S., Fernandez M., Bermudez R.C., and Morris H., Treatment of coloured industrial effects with Pleurotus spp., Current Microbiol.,42, 57-63 (2003) @No $ @ @  Namdhari B.S., Rohilla S.K., Salar R.K., Gahlawat S.K., Bansal P., and Saran A.K.,Decolorization of Reactive Blue MR, using Aspergillus species Isolated from Textile Waste Water, I. Res. J. Biological Sci., 1(1),24-29,(2012) @No $ @ @  Jain N., Nanjundaswamy C., Minocha A.K., Verma C.L., Isolation, screening and identification of bacterial strains for degradation of predigested distillery waste water, Indian J. Exp. Biol.,39,490-492 (2001) @No $ @ @  Chavan M.N., Kulkarni M.V., Zope V.P., Mahulikar P.P., Microbial degradation of melanoidins in distillery spent wash by indigenous isolate. Indian J. of biotechnol., 5,416-421 (2006) @No $ @ @ Rokade K.B., and Mali G.V., Biodegradation of tallowamine ethoxylate by Pseudomonas desmolyticumNCIM 2112, I. Res. J. Biological Sci.,1(4),1-8 (2012) @No $ @ @ Rokade K.B., and Mali G.V.,Optimization of soil parameters for benzyl benzoate degradation by Pseudomonas desmolyticum NCIM 2112, Res. J. Agriculture and Forestry Sci. 1(5)1-9,(2013) @No $ @ @ Praveen Kumar G.N. and Bhat Sumangala K., Decolorization of Azo dye Red 3BN by Bacteria, I. Res. J. Biological Sci., 1(5),46-52, (2012) @No $ @ @ Bhise R.M., Patil A.A., Raskar A.R., Patil P.J. and Deshpande D.P.,Removal of colour of spent wash by activated charcoal adsorption and electrocoagulation,Res.J.Recent Sci. 1(6),66-69,(2012) @No $ @ @ Deshpande D.P etal., Petro-Chemical Feed stock from Plastic Waste, Res. J. Recent Sci.,1(3), 63-67 (2012) @No $ @ @ Munesh, Swati and Meena R.C., Photocatalytic decolorization of acid red 186 using alternative developed  photocatalyst MBIR dowex 11, Res.J.Chem.Sci.,2(9), 56-62,(2012) @No $ @ @ Anju S.G., Jyothi K.P., Sindhu Joseph, Suguna Y. and  Yesodharan E.P., Ultrasound assisted semiconductor mediated catalytic degradation of organic pollutants in water: Comparative efficacy of ZnO, TiO2 and ZnO-TiO2, Res. J. of Recent Sciences.,1 (ISC-2011), 191-201, (2012) @No $ @ @ Santhanalakshmi J. and Komalavalli R., Visible light  induced photocatalytic degradation of some textile dyes using silver nano particles, Res. J. of Chem. Sciences 2(4), 64-67, (2012) @No
<#LINE#>Electrodeposition of Nano Zinc - Nickel Alloy from Bromide Based Electrolyte<#LINE#>Chandran@M.,RameshBapu@G.N.K.<#LINE#>57-62<#LINE#>9.ISCA-RJCS-2013-118.pdf<#LINE#>Vivekananda College, Agasteeswaram - 629 701, Kanyakumari, Tamilnadu, INDIA @ Central Electro Chemical Research Institute, Karaikudi - 630 006, Tamilnadu, INDIA <#LINE#>9/7/2013<#LINE#>24/7/2013<#LINE#> Zinc coatings offer sacrificial protection to iron and steel components at low cost. The basic reason for plating from an alloy bath is to produce some desired change in the electrodeposits unobtainable from the pure metal baths. Zinc-nickel alloy coatings can be obtained from two different systems, acidic and alkaline, both capable of producing deposits of exceptional corrosion resistance with the nickel content of 10-14% and 5-10% respectively. In this study, nano crystalline zinc-nickel coatings were electro-deposited on mild steel substrates from an electrolyte containing zinc bromide, nickel chloride and boric acid at pH 4. The bath and deposit characteristics such as cathode current efficiency, rate of build up, nature of deposit, anode efficiency, throwing power and micro hardness were studied. The morphology and structure were also examined by SEM and XRD.<#LINE#> @ @ Hall D.E, Plat.Surf.Fin., 70, 59 (1983) @No $ @ @ Hsu G.F, Plat.Surf.Fin., 71, 52 (1984) @No $ @ @ Baker R.G and.Holden C.A, Plat.Surf.Fin., 72, 3 (1985) @No $ @ @ Abibsi A., Dennis J.K. and Short N.R, Trans.Inst.Met.Fin.,69, 145 (1991) @No $ @ @ Brenner A: Electrodeposition of Alloys, Vol. I & II, (Academic Press, New York and London, (1963) @No $ @ @ Divisek J., Mergel P. and Schmitz H., Int. J. Hydr. Energy, 13, 141 (1988) @No $ @ @ de Giz M.J., Machodo S.A., Gonzalez L.A, J. Appl.Electrochem., 22, 973 (1992) @No $ @ @ Giridha J. and Wanm Ooij W.J, Surf.Coat.Technol., 53, 35 (1992) @No $ @ @ Baker R.G and Holden C.A, Plat.Surf.Finish., 72, 54 (1965) @No $ @ @ Ramanauskas R, Gudaviciute L, Scit O, Bucinskiene D and Juskenas R, Trans.Inst.Met.Fin., 86, 103 (2008) @No $ @ @ RajagopalanS.R,  et.al., Met.Fin., 70,52 (1972) @No $ @ @ Raman V., Pushpavanam M., Jayakrishnan S. and Shenoi  B.A.,  Met.Fin., 81, 85 (1983) @No $ @ @ Malathy Pushpavanam, Trans.SAEST., 38,1 (2003) @No $ @ @ Kariyanna K.G., Arthoba Naik Y. and Venkatesha T.V, Trans. SAEST., 39, 39 (2004) @No $ @ @ Visalakshi Ravindran and Muralidhran V.S, Indian, Jourl. Chem.Tech., , 330 (1995) @No $ @ @ Gomez E., Muller C., Sarret M. and Valles E., Met.Fin., 90, 87 (1992) @No $ @ @ Roland Pfiz and Gernot Strube, Trans.Inst.Met.Fin., 74,158 (1996) @No $ @ @ Rajendran  S., Bharathi  S. and Vasudevan T., Trans.Inst.Met.Fin., 78, 129 (2000) @No $ @ @ Ravidran V. and Muralidharan V.S., Trans.Inst.Met.Fin.,85, 153 (2007) @No $ @ @ Shanmugasigamani S. and Pushpavanam M., Trans.Inst.Met.Fin., 86, 122 (2008) @No $ @ @ Karahan I.H. and Guder H.S., Trans.Inst.Met.Fin., 87, 155 (2009) @No $ @ @ Mohan S., Ravindran V., Subramanian B. and Saravanan G., Trans.Inst.Met.Fin., 87, 85 (2009) @No $ @ @ Ilayaraja M., Mohan S., Gnanamuthu R.M. and Sarayanan G.,  Trans.Inst.Met.Fin., 87, 145 (2009) @No $ @ @ Eliaz N., Venkatakrishna K., Chitharanjan Hegde A., Surface & Coatings Technology, 205, 1969 (2010) @No $ @ @ Mohan Kumar Praveen Kumar C., Venkatesha T.V., Vathsala K., Nayana K.O., J. Coat. Technol. Res.,9(1), 71 (2012) @No $ @ @ Rizwan R. et.al.,  Materials Transactions, 48, 1558 (2007) @No $ @ @ Gabe R. and Willcox G.D., Trans. Inst. Met. Finish, 71(2),71 (1993) @No $ @ @ H Silmen, G Isserlis and A F Averill (Ed.), ‘Preventive and Decorative Coatings for Metals’, Finishing Publications Ltd., Teddington, England, (1978) @No $ @ @ Mc Cormick M and Kuhn A T, Trans. Inst. Met. Finish, 71(2), 74 (1993) @No $ @ @ Iwasaki M. and Hara M. and Ito S., J. Mater. Sci.,35, 943 (2000) @No 
<#LINE#>Effect of the Micellar Catalysed Hydrolysis of BIS -4-Chloro-3-Methyl Phenyl Phosphate Ester<#LINE#>A.P.@Singh,R.C.@Verma,R.S.@Kushwaha<#LINE#>63-67<#LINE#>10.ISCA-RJCS-2013-119.pdf<#LINE#>Department of Chemistry, Janta College, Bakewar, Etawah, INDIA @ Department of Chemistry, Agra College, Agra, UP, INDIA <#LINE#>22/11/2012<#LINE#>1/1/2013<#LINE#>The micellar catalysed reactions between hydroxide anions and bis-4-chloro-3-methyl phenyl phosphate ester (bis-4-CMPP) has been examined in buffered medium at pH 8 to10. The first order rate constant (K) for the reaction of OH with 4-CMPP go through maxima with increasing the concentration of cetyltrimethyl ammonium bromide(CTABr). Concentration of the surfactant can be analyzed in terms of Br ions in micellar pseudophases, which occur readily by aqueous CTABr and calculated second order rate constants.<#LINE#> @ @ Fendler J.H. and Fendler E.J., Catalysis in micellar and macro molecular systems, Academic Press, New York (1975) @No $ @ @ Singh A.P. and Yadav G.C., Proc. Nat. Conf. Current Concept. Scie, Educational Research-T.D.C., JAUNPUR, 41-45 (2011) @No $ @ @ Singh A.P., Verma R.C. and Kushwah R.S., J. of ultra chemistry, 9(1), 23-30 (2012) @No $ @ @ Mortinek K., Yatsiimirski A.V. and Berezin I.V., Micellization Solubilization and micro emulsion, Mittal, K.L., Ed. Plenum Press, New York, 2, 489 (1977) @No $ @ @ Romsted L.S. and Mittal K.L., Ed. Plnum Press New York, 2, 50 (1977) @No $ @ @ Quina F.H. and Chaimovich H., J.of Physical Chem., 83, 1844, (1979) @No $ @ @ Chaimovich H., Bonihla J.B.S., Politi M.J., Quina F.H., J.of Physical Chem., 83, 1851 (1979) @No $ @ @ Funasaki N. and Murata A., Chem Pharm Bull.,28, 805 (1980) @No $ @ @ Bunton C.A., Romosted L.S., Supelveda L., J. of Physicai Chem.,84, 2611 (1980) @No $ @ @ Al. Lohedon, H., Bunton, C.A., Romosted, L.S., J. of Physicai Chem., 85, 2123 (1981) @No $ @ @ Bunton C.A., Romosted L.S., Savelli, G., J.of American Chem. Soc.,101, 1253 (1979) @No $ @ @ Bunton C.A., Romosted L.S., Thamabit, J.of American Chem. Soc., 102, 3900 (1980) @No $ @ @ Bunton C.A., Romosted L.S., Savelli, G.,Gan, L.H., Moffat, J.R., J. of Physical Chem.,85, 4118 (1981) @No $ @ @ Al. Lohedon H., Bunton, C.A., J. of Org.Chem.,47, 1160 (1982) @No $ @ @ Bunton C.A., Romosted L.S., Solution behavior of surfactants, Theoretical and Applied Aspects, Mittal, K.L., Ed. Plenum Press, New York, 2, 975 (1982) @No $ @ @ Bunton C.A., Robinson L., J. of Org. Chem.,34, 733 (1969) @No $ @ @ Bunton C.A., Cerichelli G., Ihara Y., Supelveda L., J. of American Chem. Soc,101, 2429 (1979) @No $ @ @ Menger F.M. and Protony C.E., J. of Amer. Chem. Soc.,89, 4968 (1967) @No $ @ @ Bunton C.A. and Junggern S.L., J of Chem. Soc., Perkin Trans.2, 20. 355 (1984) @No
<#LINE#>Inhibition of Aluminum Corrosion by Salvia Judica Extract<#LINE#>M.Nawafleh@Eyad,Bataineh@TareqT.,Irshedat@MunaK.,@MahmoudA.Al-Qudah,T.AbuOrabi@Sultan<#LINE#>68-72<#LINE#>11.ISCA-RJCS-2013-124.pdf<#LINE#>Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, JORDAN<#LINE#>22/7/2013<#LINE#>28/7/2013<#LINE#>The inhibitive effect of the extract of Salvia Judica on aluminum corrosion in 1 M NaOH solutions was investigated by using the weight loss method at different temperatures. It was found that the extract play as corrosion inhibitor for aluminum corrosion in 1 M NaOH solution. The inhibition action of the extract was discussed in view of Langmuir and Temkin adsorption isotherms. It was found that the adsorption of the extract on aluminum surface is a spontaneous process. The inhibition efficiency was found to increase with increasing concentration of the extract and decreased with increasing temperature.<#LINE#> @ @ Zucchi F.  and Omar  I.H.,  Plant  extracts  as  corrosion  inhibitors  of  mild  steel  in  HCl  solution,  Surf. Tech., 24(4), 391-399 (1985) @No $ @ @ Abiola Olusegun K., Otaigbe J.O.E. and Kio O.J., Gossypium hirsutum L. extracts as green corrosion inhibitor for aluminum in NaOH solution, Corros. Sci., 51(8), 1879-1881(2009) @No $ @ @ Abdel-Gaber A.M., Khamis E. and Abo-Eldahab H., Inhibition of aluminium corrosion in alkaline solutions using natural compound, Mater. Chem. Phys, 109(2-3),297–305(2008) @No $ @ @ Oguzie E.E., Corrosion  inhibition  of  aluminium  in  acidic and  alkaline  media  by  Sansevieria  trifasciata  extract, Corros. Sci., 49, 1527–1539(2007) @No $ @ @ Irshedat M., Nawafleh E., Bataineh T., Muhaidat R., Al-Qudah M.A. and Alomary A.A, Portugaliae Electrochimica Acta, 31(1), 1-10 (2013) @No $ @ @ Nawafleh E., Irshedat M., Bataineh T., Muhaidat R., Al-Qudah M. and Alomary A., The effects of Inula viscosaextract on corrosion of copper in NaOH solution, Res. J. Chem. Sci., 2(9), 37-41 (2012) @No $ @ @ Obot I. B. and  Obi-Egbedi N. O., Ipomoea Involcrata as an Ecofriendly Inhibitor for Aluminium in Alkaline Medium, Portugaliae Electrochimica Acta, 27(4), 517-524(2009) @No $ @ @ Al-Jaber H. I., Abrouni K. K., Al-Qudah M. A. and Abu Zarga M. H., J. Asian. Nat. Prod. Res., 14 (7), 618-625 (2012) @No $ @ @ Lu Y.R. and Foo L.Y., Polyphenolic of Salvia—a review. Phytochemistry,59, 117-140 (2002) @No $ @ @ Narukawa Y., Fukui,M., Hatano, K., Four new diterpenoids fromSalvia fulgens Cav, J. Nat. Med., 60, 58-63 (2006) @No $ @ @ Topc ¸u, G., Bioactive triterpenoids from Saliva species, J. Nat. Prod., 69, 482-487 (2006) @No $ @ @ Liu, J., Oleanolic acid and ursolic acid: research perspectives. J. Ethnopharmacol., 100, 92-94 (2005) @No $ @ @ Mitaine-Offer A.C., Hornebeck W., Sauvain M. and Hanrot M. Z., Triterpenes and phytosterols as human leucocyte elastase inhibitors. Planta Med., 68(10), 930-932 (2002) @No $ @ @ Misra L.N., Dixit A.K. and Sharma R.P., High concentration of hepatoprotective oleanolic acid and its derivatives in Lantana camara roots, Planta Med., 63, 582-589 (199) @No $ @ @ Ebenso E.E., Ibok U.J., Ekpe U.J., Umoren S., Jackson E., Abiola O.K., Oforka N.C. and Martinez S., Corrosion inhibition studies of some plant extracts on aluminium in acidic medium, Trans ofsaest., 39(4), 117-123 (2004) @No $ @ @ El-Etre A.Y., Inhibition of aluminium corrosion using Opuntia extract, Corros.Sci., 45, 2485 -2495(2003) @No $ @ @ Onuchukwu A.I., The inhibition of aluminum corrosion in an alkaline medium II: influence of hard bases, Mater. Chem. Phys., 24, 337-343 (1990) @No $ @ @Tarasova N. S., Khachaturyan M. A.  and Nikolaev L. A.,  Russ. J. Phys. Chem., 58, 628-633 (1984) @No $ @ @ Doche M. L., Rameau J. J., Durand R. and Novel-Cattin F., Electrochemical behaviour of aluminium in concentrated NaOH solutions,  Corros. Sci., 41, 805-826 (2007) @No $ @ @ Valek L. and Martinez S., Copper corrosion inhibition by Azadirachta indica leaves extract in 0.5 M sulphuric acid, Mater Lett.,61, 148-151 (2007) @No $ @ @ Awad M. I., Eco friendly corrosion inhibitors: Inhibitive action of quinine for corrosion of low carbon steel in 1 M HCl,  J. Appl. Electrochem., 36(10), 1163-1168 (2006) @No $ @ @ Manivannan M. and Rajendran S., Corrosion Inhibition of Carbon steel by Succinic acid Zn2+ system  Res.J.chem.sci.,1(8), 42-48(2011) @No $ @ @ 3Baumgaertner M. and Kaesche H., Aluminum pitting in chloride solutions: morphology and pit growth kinetics, Corros. Sc., 31, 231-236 (1990) @No
<#LINE#>Study of Interactions of Tryptophan through Acoustic and Thermodynamic Properties<#LINE#>P.R.@Malasane<#LINE#>73-77<#LINE#>12.ISCA-RJCS-2013-129.pdf<#LINE#>Department of Engineering, College of Engineering and Technology, Amravati, MS, INDIA <#LINE#>9/11/2012<#LINE#>5/1/2013<#LINE#>Molecular interactions of Tryptophan (an essential amino acid) in the presence of essential metal ions like Zn2+ and Co2+ at 303.15K have been studied by using ultrasonic interferometer supplied by M/s Mittal Enterprises, New Delhi, operating at a frequency of 2 MHz. and a bicapillary pyknometer to measure the density of solution. The data is processed to obtain the various acoustic and thermodynamic parameters to study the molecular interactions in aqueous solutions. The values of apparent molar volume, apparent molar compressibility, partial molar volume, partial molar compressibility, specific acoustic impedance, relative association, intermolecular free length have been calculated by using standard mathematical relations. The concentration dependences of the density and ultrasonic velocity were tried to fit into linear and polynomial equations. It is interesting to see the associative interaction among the molecules and ions as well as the increase in the stacking interactions between the metal ions and tryptophan.<#LINE#> @ @ CRC Handbook of Chem and Phys 78th Ed (1997) @No $ @ @ Mishra A.P., Ultrasonic, viscometric and volumetric studies of some bioapplicable systems involving ZnCl, dextrose and methionine in water, Ind J Chem, 43A, 730(2004) @No $ @ @ Das Debashis, Ray S.K. and Hazra D.K., A study on volumetric and compressibility properties of some lithium salts in N, N-dimethylacetamide at 25C, Ind J Chem, 41A, 1812 (2002) @No $ @ @ Pal Amalendu and Suresh Kumar, Volumetric studies of some amino acids in binary aqueous solutions of MgCl.6HO at 288×15 and 308×15 K., J. Chem. Sci., 117(3), 267 (2005) @No $ @ @ Mishra A.P., Mishra R.K. and Shrivastava S.P., Structural and antimicrobial studies of coordination compounds of VO(II), Co(II), Ni(II) and Cu(II) with some Schiff bases involving 2-amino-4-chlorophenol,  J. Serb. Chem. Soc. 74(5), 523 (2009) @No $ @ @ Thirumaran S. and Sabu K., Job, Ultrasonic Investigations of amino acids in aqueous sodium acetate medium, Ind J of Pure & Appli. Physics, 47,  87 (2009) @No $ @ @ Mehra Rita and Malav Brij Bihari, Acoustic, volumetric and visco metric studies of DL-alanine in aqueous galactose solution in the presence of sodium chloride at 298, 308 and 318 K, RJPBCS,2(3), 709  (2011) @No $ @ @ Iqbal M., Mateeullah M., Partial molar volumes of some dipolar ions in water at 35°C, Canadian Journal of Chemistry , 68(5), 725 (1990) @No $ @ @ Millero J., Surdo A.L. and Shin C., The apparent molal volumes and adiabatic compressibilities of aqueous amino acids at 25, J Phys Chem, 82, 784 (1978) @No $ @ @ Pande J.D., Shukla A., Rai R.D. and Mishra K.J., Ultrasonic, Volumetric and Viscometric studies of tetracycline and it’s allied compounds, J Chem Eng data, 34, 29 (1989) @No 
<#LINE#>Physico-chemical Assessment of Deep Groundwater Quality of Various Sites of Kathmandu Metropolitan City, Nepal<#LINE#>ChirikaShova@Tamrakar,PawanRaj@Shakya<#LINE#>78-82<#LINE#>13.ISCA-RJCS-2013-130.pdf<#LINE#>Department of Chemistry, Faculty of Science, Padma Kanya Multiple Campus, Tribhuvan University, Bagbazar, Kathmandu, NEPAL <#LINE#>2/8/2013<#LINE#>6/8/2013<#LINE#>The present study was carried out to assess deep tubewell groundwater quality of Kathmandu metropolitan city. To study various water quality parameters, groundwater samples from eight major locations of the city were collected and analyzed. Samples were collected in pre-monsoon (month of April-May 2013) and preserved using suitable preservation methods. The collected groundwater samples were analyzed for the following physico-chemical parameters: temperature, colour, turbidity, pH, electric conductivity (EC), total alkalinity, phenolphthalein alkalinity, total hardness, calcium, magnesium, iron, chloride and total ammonia using the procedure outlined in the standard methods. Results showed that the water quality status was found to vary from place to place. High levels of turbidity, total alkalinity, total hardness, iron and total ammonia were found in the groundwater of many sites. The results were compared with WHO water quality guideline and National Drinking Water Quality Standard (NDWQS) of Nepal. <#LINE#> @ @ Ikem A., Odueyungbo S. and Egiebor Nyavor N.O.K., Chemical Quality of  Bottled Waters from Three Cities in Eastern Alabama, Sci. Total Environ, 285, 165-175 (2002) @No $ @ @ Lerda D.E. and Prosperi C.H., Water mutagenicity and toxicology in Rio Tercero (Cordoba, Argentina), Water Res., 30, 819-824 (1996) @No $ @ @ World Health Organization, Guidelines for drinking water quality, 3rd Edn., WHO, Geneva, (2006) @No $ @ @ International Center for Integrated Mountain Development (ICIMOD), Kathmandu Valley Environmental Outlook, Kathmandu, Nepal (2007) @No $ @ @ Japan International Cooperation Agency (JICA) and Environment and Public health Organization (ENPHO), Arsenic vulnerability in groundwater resources in Kathmandu valley, Final report (2005) @No $ @ @ Katiwada N.R., Takizawa S., Tran T.V.N. and Inoue M., Groundwater contamination assessment for sustainable water supply in Kathmandu valley, Nepal, Water Sci. Tech., 46, 147-154 (2002) @No $ @ @ Kouras A., Katsoyiannis I. and Voutsa D., Distribution of arsenic in ground water in the area of Chalkidiki, Northern Greece, J. Hazard. Mater., 147, 890-899 (2007) @No $ @ @ WHO, Guidelines for drinking-water quality, 3rd ed. WHO, Geneva, Switzerland, (2004) @No $ @ @ Standard methods for examination of waters and waste waters, 16th ed., APHA, AWWA and WPCF Inc. New York (1985) @No $ @ @ Trivedy R.K. and Goel P.K., Chemical and Biological Methods for Water Pollution Studies, Environmental Publications, Oriental Printing Press, Aligarh (1986) @No $ @ @ Parihar S.S., Kumar A., Kumar A., Gupta R.N., Pathak M., Shrivastav A. and Pandey A.C., Physico-Chemical and Microbiological Analysis of Underground Water in and Around Gwalior City, MP, India, Res. J. Recent Sci., 1, 62-65, (2012) @No $ @ @ Wetzel R.G., Limology, W.B., Saunders Co., Philadelphia, USA, 743 (1975) @No $ @ @ Wetzel R.G. and Likens G.E., Limnology Analyses, Springer-Verlag, New York (1991) @No $ @ @ Manivasakam N., Physicochemical Examination of Water, Sewage and Industrial Effluents, 2nd edn., Pragati Prakashan (2000) @No $ @ @ Fulvio D.E. and Olori L., In: Hardness of Drinking Water and Public Health, Pergamon Publication, New York (1965) @No $ @ @ McCarthy M.F., Should we restrict chloride rather than sodium? Med Hypotheses, 63, 138-148 (2004) @No $ @ @ Park K., In: Text book of Preventive and Social Medicine, 15th ed, Banarsidas Publication, Jabalpur (1997) @No $ @ @ Purohit S.S. and Saxena M.M., In: Water life and pollution, Agro Botanical Publication, New Delhi (1990) @No $ @ @ Lovley, D.R., Microbial Fe (III) reduction in subsurface environments. FEMS Microbiol. Rev., 20, 305-313 (1997) @No $ @ @ Versari A., Parpinello G.P. and Galassi S., Chemometric survey of Italian bottled mineral waters by means of their labelled physico-chemical and chemical composition, J. Food Compos. Anal., 15, 251-264 (2002) @No $ @ @ Pandey V.P., Chapagain S.K. and Kazama F. Evaluation of groundwater environment of Kathmandu Valley, Environ. Earth Sci., 60, 1329-1342 (2010) @No
@Short Communication
<#LINE#>Physico-Chemical Analysis of Drinking Ground Water in Varangaon Region, Dist Jalgaon, Maharashtra, India<#LINE#>SudhakarP.@Mote,HemantA.@Mahajan<#LINE#>83-85<#LINE#>14.ISCA-RJCS-2013-101.pdf<#LINE#>Dept. of Chemistry, Shri J.J.T. University, Rajasthan, INDIA @ Dept. of Chemistry, Smt. G.G.K Science College, Muktainagar, INDIA<#LINE#>20/6/2013<#LINE#>1/8/2013<#LINE#> The open well water quality in Varangaon region was assess for the effect on the water quality which is used in domestic as well as agricultural purposes. The open well samples were collected from the five wells around this region. The physico-chemical parameters such that colour, odour, temperature, pH, Electrical conductivity, total hardness, total dissolved solids, calcium, magnesium, chloride, total alkalinity, dissolved oxygen, chemical oxygen demand and biological oxygen demand were analysed and to know monsoon status in this region of water quality. Drinking water quality of premonsoon season was better than post monsoon season, one samples were slightly alkaline along with high dissolved solids. <#LINE#> @ @ APHA (American Public Health Association): American water works association and water pollution control/ federation, Standard method for the examination of water and waste water, American publication Health Association, washington  USA (1980) @No $ @ @ Gasim M.B., Ismail B.S., Toriman E., Mir S.I., and Chek T.C., A physico-chemical assessment of the bebar river pahana, Malaysia, Global Journal of Environment Research, 1(1), 7-11 (2007) @No $ @ @ Gautam A., Ecology and pollution of mountain waster’s, Ashish Publishing house, New Delhi (1990) @No $ @ @ Horrison R.M., pollution- causes, Effect publication No.44, Royal Society of Chemistry, London @No $ @ @ ICMR Indian Council of Medical Research, Manual of standard of quality of drinking water supplies 2nd ed. Special report series no. 44 New Delhi (1975) @No $ @ @ Trivedi D.K. and Goal P.K, Chemical and biological methods for water pollution studies, Environment Publication, karad, India (1984) @No $ @ @ Davis S.N. and Dewiest R.J., Hydrology, John wiley and sons, New York (1966) @No $ @ @ Bheshdadia B.M., Chauhan M.B. and Patel P.K., Physico-chemical analysis of underground drinking water in morbid-malia Territor, Current World Environment, 7(1), 169-173 (2012) @No $ @ @ Mahananda M.R., Mahanty M.P. and Behera N.R physicochemical analysis of surface and ground water of Bargarh District, Orissa, India, IJRRAS, 2(3), 284-295 (2010) @No $ @ @ Pandey S.K. and Tiwari S., physico-chemical analysis of ground water of selected area of ghazipur city – A case study Nature and Science, 7(1), 17-20 (2009) @No $ @ @  Parihar S.S., kumar Ajit, kumar Ajay, gupta R.N., Pathak M., Shrivastav A. and Pandey A.C., Physico-chemical and microbiological analysis of underground water in and around Gwalior city, M.P. India, Research Journal of Recent Sciences, 1(6), 62-65(2012) @No $ @ @ Reza R. and Singh G., physico-chemical analysis of ground water in angul- Talcher region of Orissa, India, Journal of American Science, 5(5), 53-58 (2009) @No $ @ @ Tripathy J.K, Ground water hydro chemistry in and around Bhanjabihar, Ganjam District, Orissa poll Res.,22(2), 185-188 (2003) @No $ @ @ Mahananda H.B., Mahananda M.R.,Mahanty B.P., physico – chemical and microbiological analysis of textile industry effluent, of wardha region, Ecol. Envi and Cons.,11, 537 (2005) @No 
@Mini Review Paper
<#LINE#>Lead Poisoning -A Review<#LINE#>Seema@Tiwari,I.P.@TripathiI.P.,H.L.@Tiwari<#LINE#>86-88<#LINE#>15.ISCA-RJCS-2013-133.pdf<#LINE#>AISECT University, Bhopal, MP, INDIA @ MGCG University, Chitrakoot, Satna, MP, INDIA @ MANIT, Bhopal, MP, INDIA<#LINE#>6/7/2013<#LINE#>6/8/2013<#LINE#>The lead has been explored and used since last 6000 years and the history of lead poisoning is nearly 2500 years. Symptomatic lead poisoning is the result of very high levels of lead in the tissues. It is possible that the content of lead in the body that is insufficient to cause obvious symptoms can nevertheless give rise to slowly evolving and long lasting adverse effects. It is clear that a continued rise in the pollution of the human environment with lead could eventually produce levels of exposure with adverse effects on human health. Traces of lead are almost ubiquitous in nature and minute amounts are found in normal diets. This article reviews the work done in the field of lead poisoning pertaining to sources of lead, symptoms of toxicity and effects on heme biosynthesis.<#LINE#> @ @ Rosenstock L., The environment as a Cornerstone of public Health, Environmental Health Perspectives,111(7), A376-A377 (2003) @No $ @ @ WHO, Lead, World Health Organization. Geneva, (1977) @No $ @ @ WHO, Lead –Environmental Aspects, World Health Organization Geneva (1989) @No $ @ @ Lamphear B.P., Hornung R., HOM Howard C.R., Eberly S. and Knauf K., Environmental Lead Exposure During Early Childhood, J Pediatr., 140(4), 490 (2002) @No $ @ @ Ziegler E.E., Edwards B.B., Jensen R.L., Mahaffey K.R. and Fomon S.J., Absorption and Retention of Lead by Infants, Pediatr Res.Jan.,12(1), 29-34 (1978) @No $ @ @ Lindsky T.I. and Schneider J.S., Lead Neurotoxicity in Children, Basic Mechanisms and Clinical Correlates, Brain,126,  5-19 (2003) @No $ @ @ Travis R.J., Solon O., Quimbo S.A., Tan C.M.C., Butrick E. and Peabody J.W.,  Elevated Blood –Lead Levels among Children Living in the Rural Philippines, Bulletin of the World Health Organization, 85(9), 674-680 (2007) @No $ @ @ Balakrishnan, Kalpana Study of Lead Exposure and Outcomes Amongst Children in Chennai, India, Ph.D. Thesis, (2007) @No $ @ @ Patric Michael and Mac Roy A.B. Brown university In search of safe housing, Blood Lead Levels of Past Occupants as an Indicator of Present Lead Safety, (2000) @No $ @ @ Karri S.K., Saper R.B. and Kales S.N., Lead Encephalopathy Due to Traditional Medicines Current drug safety(1), 54–59 (2008) @No $ @ @ Kosnett M.J., Lead, In Olson, K.R. Poisoning and Drug Overdose (5th ed.), McGraw-Hill Professional, (2006) @No $ @ @ Mycyk M., Hryhorczuk D. and Amitai Y., Lead, In Erickson, TB; Ahrens, WR; Aks, S; Ling, L. Pediatric Toxicology: Diagnosis and Management of the Poisoned Child. McGraw-Hill Professional, (2005) @No $ @ @ Pearce J.M., Burton's line in lead poisoning, European neurology,57(2), 118–129 (2007) @No $ @ @ Needleman H., Lead poisoning,  Annual review of medicine,55, 209–22 (2004) @No $ @ @ Bellinger D.C., Lead,  J Pediatrics,113(4), 1016–1022 (2004) @No $ @ @ Merrill J.C., Morton J.J.P. and Soileau S.D., Metals, In Hayes, A.W. Principles and Methods of Toxicology (5th ed.), CRC Press, (2007) @No $ @ @ Kosnett M.J. Lead, In Brent J., Critical Care Toxicology: Diagnosis and Management of the Critically Poisoned Patient, Gulf Professional Publishing, (2005) @No $ @ @ Henretig F.M., Lead, In Goldfrank, LR. Goldfrank's Toxicologic Emergencies (8th ed.), McGraw-Hill Professional, (2006) @No $ @ @ Seema Tiwari and I.P. Tripathi, Lead Pollution - An Overview, Int. Res. J. Environment Sci.,1(5), 84-86 (2012) @No $ @ @ Julian J. and  Chisolm Jr. Lead Poisoning,  Scientific American Journal, 224(2), 15-23  (1971) @No $ @ @ Kapoor Neeti and Tiwari Prakash, Effects of Heavy Metals Poisoning during Pregnancy, Int. Res. J. Environment Sci., 2(1), 88-92 (2013) @No