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Triphenylphosphine Sulphide as a Complexing Agent : Synthesis and Characterisation of Complexes of Rhodium (I) and Ruthenium (II)

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Author Affiliations

  • 1P.G. Centre, Department of Chemistry, College of Commerce, Patna-8000 020, INDIA

Res.J.chem.sci., Volume 3, Issue (6), Pages 81-82, June,18 (2013)

Abstract

Rhodium(I) complexes of Wilkinson's catalyst [Rh(P.Ph3)Cl] types, have been synthesised and characterised by elemental analysis, IR, 1H NMR, 13C NMR and magnetic measurements. The complexes have been found to be four coordinated with square planar geometry around the Rhodium metal ions with diamagnetic character, while ruthenium metal forms five coordinated with trigonal bipyramid geometry with paramagnetic character.

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