Fe(III) Complexes with Schiff base Ligands : Synthesis, Characterization, Antimicrobial Studies
Author Affiliations
- 1Department of Chemistry, P.S.G.R. Krishnammal College for Women, Peelamedu, Coimbatore, Tamil Nadu, INDIA
Res.J.chem.sci., Volume 3, Issue (2), Pages 35-43, February,18 (2013)
Abstract
The synthesis of Fe(III) complexes derived from Schiff base ligands. Obtained by the condensation of o-phenylenediamine, salicylaldehyde and isatin / 2-hydroxy Naphthaldehyde / acetyl acetone is presented. The complexes were characterized by elemental analyses, molar conductance, magnetic susceptibility, IR, Uv-Vis spectral data and thermal analyses. The elemental analysis of the complexes confine to the stoichiometry of the type [ML (H2O)2] (OAc)2. The complexes were found to be electrolytic in nature on the basis of value of molar conductance. From the spectral datas an octahedral geometry has been proposed for all the complexes. The possible geometries of metal complex were evaluated using 3D molecular modelling picture. The metal complexes have been screened for their antibacterial and antifungal activity.
References
- Rai B.K., Synthesis, spectral and antimicrobial study of Co(II), Ni(II), Cu(II) complexes with Schiff bases of 3-pridinyl n-pentyl ketone, J. Ind. Council Chem., 25(2), 137-141 (2008)
- Raman N., Pitchaikani Raja Y. and Kulandaisamy A., Synthesis and Characterization of Cu(II), Ni(II), Mn(II), Zn(II) and Vo(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide, Proc. Ind Acad. Sci., 113, 183-189 (2001)
- Nagajothi A., Kiruthika A., Chitra S., Parameswari K., Synthesis and Characterization of Tetradentate Co(II) Schiff base complexes : Antimicrobial and DNA Cleavage studies, Int. J. Pharm and Biomedical Sci., 3(4), 1768-1778 (2012)
- Raman N., Dhaveethu Raja J. and Sakthivel A., Synthesis, spectral characterization of Schiff base transition metal complexes: DNA cleavage and antimicrobial activity studies, J. Chem. Sci., 119, 303-119 (2007)
- Shilpa Sharma, Monica Bedi, Monica Gupta, Varshney. S, Varshney. A. K., Studies of some new coordination compounds of Al(III) with semicarbazones and thiosemicarbazones, Rasayan J. Chem., 3, 483-489 (2010)
- Angela kriza, Lucica viorica, Nicoleta cioatera., Synthesis and structural studies of complexes of Cu, Co, Ni and Zn with isonicotinic acid hydrazide and isonicotinic acid (1-naphthylmethylene) hydrazide, J. Serb. Chem. Soc, 75 (2), 229-249 (2010)
- Bhagat T.M., Swamy D.K. and Deshpande M.N., Synthesis and characterization of transition metal complexes with newly synthesized substituted benzothiazole, J. Chem and Pharm Research, 4, 100-104 (2012)
- Figgis. B. N, Lewis. J., Co(II) and Fe(III) Complexes of Schiff bases derived from Isatin with some amino acids, Prog. Inorg. Chem., 157, 37-67 (1964)
- Neelakantan M.A, Russal Raj F., Dharmaraja J., Johnsonraja S. and Jeyakumar T., Synthesis, Characterization and Biocidal Activitiese of some Schiff base metal complexes., Spectrochimica Acta., 71 A, 1599-1609 (2008)
- Kalia S.B., Lumba K., Kaushal G., Sharma M., Magnetic and spectral studies on Co(II) chelates of a dithiocarbazate derived from isoniazid, Ind. J. Chem, 46 A, 1233-1239 (2007)
- Fahmideh Shabani, Lotf Ali, Saghat Foroush, Shahriar Ghammamy., Synthesis, Characterization and anti-tumour activity of Fe (III) Schiff base complexes with unsymmetric tetradentate ligands, Bull. Chem. Soc. ETHIOP, 24, 193-199 (2010)
- Kulkarni, Sangamesh Patil A., Prema Badami S., Electrochemical Properties of some transition metal complexes: Synthesis and characterization and In-vitro antimicrobial studies of Co(II), Ni(II), Cu(II), Mn(II) and Fe(III) complexes, Int. J. Electrochem. Sci, 94, 717-729 (2009)
- Mendu Padmaja, Pragathi J. and Gyanakumari C., Synthesis, spectral characterization, molecular modeling and biological activity of first row transition metal complexes with Schiff base ligand derived from chromone-3-carbaldehyde and o-amino benzoic acid, J. Chem and Pharm Res., 3, 602-613 (2011)
