International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Inhibition of Corrosion of Carbon Steel in Sea Water by an Aqueous Extract of Eclipta alba Leaves-Zn2+ system

Author Affiliations

  • 1PG and Research Department of Chemistry, GTN Arts College, Dindigul - 624005, Tamil Nadu, INDIA
  • 2PG and Research Department of Chemistry, APA College of Arts and Culture Palani, Tamil Nadu, INDIA
  • 3Department of Chemistry, RVS School of Engineering and Technology, Dindigul-624005, INDIA

Res.J.chem.sci., Volume 3, Issue (2), Pages 10-15, February,18 (2013)

Abstract

The Inhibition efficiency [IE] of an aqueous extract of eclipta alba leaves in controlling corrosion of carbon steel in sea water [Thondi, Tamil Nadu, India] has been evaluated by weight loss method. The weight loss study reveals that the formulation consisting of 6mL of EAE (Eclipta alba extract ) and 25 ppm of Zn2+ has 92% inhibition efficiency in controlling corrosion of carbon steel in sea water. Polarization study reveals that EAE and Zn2+ system functions as mixed type inhibitor. The nature of the metal surface has been analysed by FTIR spectra and SEM analysis.

References

  1. LaQue F.L., Marine corrosion and prevention, John Wiley & sons, 116 (1975)
  2. Raja P.B. and Sethuraman M.G., Natural products as corrosion inhibitor for metal in corrosive Media – a review, Mater. Lett., 62, 113 -116 (2008)
  3. El Hosary A.A., Saleh R.M., Shams El Din A.M., Corrosion inhibition by naturally occurring Substances, I. Effect of Hibiscus subdariffa (karkade) extract on the dissolution of aluminum and Zinc, Corros. Sci., 12, 897-904 (1972)
  4. Saleh R.M., Ismail A.A., El Hosary A.A., Corrosion inhibition by naturally occurring Substances, V11, The effect of aqueous extracts of some leaves and fruit peels on the Corrosion of steel, aluminium, zinc and copper in acids, Br. Corros. J., 17, 131- 135 (1982)
  5. Saleh R.M., Ismail A.A., El Hosary A.A., Corrosion inhibition by naturally occurring Substances, V11, The effect of aqueous extracts of some seeds, leaves, fruits peels on the Corrosion of aluminium in sodium hydroxide, Corrs. Sci., 23, 1239 - 1241 (1983)
  6. Ekpe U.J., Ebenso E.E., Ibok U.J., Inhibitory action of Azadirachta leaves extract on Corrosion of mild steel in tetraoxosulphate (VI) acid, J. West African Assoc., 37, 13-30 (1994)
  7. C.A. Loto The effect of Vernonia amygdalina (bitter leaf) solution extract on the Corrosion inhibition of mild steel, Nig. Cor. J., 19, 20-28 (1998)
  8. Eclipta prostrate paramount for hair loss and alopecia citation of Bible. Healthy Hair Highlights News, 22 July 2011, Retrieved (2011)
  9. Roy R.K., Thakur M., Dixit V.K., (Epub 2008 May 14), Hair growth promoting activity of Eclipta Prostrate in male albino rats, Arch Dermatol Res. 2008 Aug; 300(7), 357-64 (2012)
  10. Wranglen G., Synergistic effect of 2-chloroethyl phosphonic acid and Zn2+ Introduction to Corrosion and protection of Metals (Chapman & Hall, London) 236 (1985)
  11. Fontana Mars G., Corrosion Engineering, TATA McGraw-Hill publishing company Limited, New Delhi, Third edition, 171 (2006)
  12. Umamathi T., Arockia Selvi J., Agnesia Kanimozhi S., Rajendran S. and John Amalraj A., Indian J. Chem. Technol, 15, 560-565 (2008)
  13. Felicia Rajammal Selvarani, Santhamadharasi S., Wilson Sahayaraj J., John Amalraj A. and Susai Rajendran, Bull. Electrochemistry., 20, 561-566 (2004)
  14. Johnairani V., Rajendran S., Sathiyabama J., Muthumegala T.S., Krishnaveni A. and Hajara Beevi N., Bulgarian Chemical Communications., 44, 41–51 (2012)
  15. Kavipriya K., Sathiyabama J., Rajendran S. and Krishnaveni A., Surface morphology of protective film formed on carbon steel in presence of 2 – carboxyethyl phosphonic acid and Zn2+ system, International journal of Advances in Engineering, Science and Technology., 2 (2), 341 – 351 (2012)
  16. Sangeetha M., Rajendran S., Sathiyabama J., Krishnaveni A., Shanthy P., Manimaran N. and Shyamaladevi B., Corrosion Inhibition by an Aqueous Extract of Phyllanthus Amarus, Portugaliae Electrochimica Acta., 29 (6), 429 – 444 (2011)
  17. Manivannan M. and Rajendran S., Corrosion Inhibition of carbon steel by Succinic acid – Zn2+ system, Research Journal of Chemical Sciences., 1(8), 42-48 (2011)
  18. Neuropharmacological studies on Wedelia calendulacea Less stem extract. Prakash T., Rao N. Rama and Swamy A.H.M. Viswanatha, Phytomedicine, International Journal of Phytotherapy & Phytopharmacology, November 01, (2008)
  19. Muruganantham S., Anbalagan G. and Ramamurthy N., FT-IR and SEM-EDS analysis of medicinal plants Eclipta Alba hassk and Eclipta Prostrata linn, ROMANIAN J. BIOPHYS.,19(4), 285-294 BUCHAREST, (2009)
  20. Robert M Silverstein Francis X. Webster Spectrometric Identification of Organic Compounds, Vl Edition, Wiley Student Edition, 108 (2007)
  21. Xu Yang, Fu Sheng Pan and Ding Fei Zhang, A study on corrosion inhibitor for magnesium alloy, Mat. Sci. Forum, 610-613, 920-926 (2009)
  22. Gogoi P.K. and Barhai B., Corrosion Inhibition of carbon steel in open recirculating cooling water system of Petroleum refinery by a multi-component blend containing zinc (11) diethyldithio carbamate, Indian J. Chem. Technology, 17, 291-295 (2010)
  23. Hamdy A., Farag A.B., EL – Bassoussi A.A., Salah B.A. and Ibrahim O.M., Electrochemical behavior of brass Alloy in different saline media: Effect of Benzotriazole, World App. Sci. Journal, 8, 565-571 (2010)
  24. Weihua Li, Lichao Hu, Shengtao Zhang and Baorong Hou, Effects of two fungicides on the corrosion Resistance of copper in 3.5% Nacl solution under various conditions, Corrosion Sci., 53, 735-745 (2011)