International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Investigations of Nickel (II) removal from Aqueous Effluents using Electric arc Furnace Slag

Author Affiliations

  • 1Department of Chemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia, 43400 UPM Serdang, Selangor DE, MALAYSIA

Res.J.chem.sci., Volume 3, Issue (12), Pages 29-37, December,18 (2013)

Abstract

The tendency of electric arc furnace (EAF) slag to the adsorb nickel(II) from aqueous solution has been investigated through batch experiments. Scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) andEnergy Dispersive X-Ray (EDX) Analysis. Analysis was characterized in order to give inside to the properties of electric arc furnace slag (EAFS). The adsorption result revealed that the maximum up take by the EAFS was 160.92mg/g at an equilibrium time of 216hr. The pseudo-second order kinetic fitted well with the kinetic data, showing a high determination coefficient (R)2of over 0.996. The adsorption isotherms of nickel(II) on this adsorbent for both linear and non linear isotherms were well described by Langmuir model, this is because it shown a good fitting to the experimental data when compared to other isotherm models. Moreover the nickel(II) adsorption was found to be dependent on the adsorbent dosage, contact time and initial metal ion concentration. From the result it can be deduced that EAFS could be used to effectively adsorb nickel(II) from aqueous solution.

References

  1. Littui H., Yuan Yuan, S., Tao Y., Li L., Adsorption behavior of Ni (II) on Lotus stalk derived active carbon by phosphoric acid activation, Desalination, 268, 12-19 (2011)
  2. Rifaqatu, A.K., Moonish A.K., Removal and recovering of Cu(II), Cd (II) and Pb (II) ions from single and multi metal system by batch and column operation on neem oil cake (NOC), Separation and Purification Technology, 57, 397-402 (2007)
  3. Mohan, S., Streelakshmi G., Fixed bed column study for heavy metal removal using phosphate treated rice husk, J. of Hazard Mater., 153, 253-262 (2008)
  4. Jalali R., Ghafourian H., Asef, Y., Davarpanah, S. J., Sepehr S., Removal and recovery of lead using non living biomass of marine algae, J. of Hazard Mater., B 2, 253-262 (2002)
  5. Nlo H., Chua K.H. and S.H.B. Lam, A comparative investigation on the biosorption of lead by filamentous fungal biomass, Chemosphere, 39, 272-2736 (1999)
  6. Beh C., Chuah L., Choong T.S.Y.,. Kamarudzaman M.Z.B. and Abdan K., Adsorption study electric arc furnace slag for the removal of manganese from solution, American Journal of Applied Sci.,7(4), 442–446 (2010)
  7. Chungsying L., Comparisons of sorbent cost for the removal of Ni2+ from aqueous solution by carbon nanotubes and granular activated carbon, J. of Hazard Mater., 151, 239-246 (2008)
  8. Xue S.W. and Yong Q., Removal of Ni(II), Zinc(II) and Cr(VI) from aqueous solution by Alternanthra philoxeroides biomas, J. of Hazard Mater., B138, 585-588 (2006)
  9. Malkoc E., Ni (II) removal from aqueous solutions using cone biomass of Thuja orientalis, J. of Hazard Mater., 137, 899-908 (2006)
  10. Vieira M., Neto A., Gimenes M, M. da Silva, Sorption kinetics and equilibrium for the removal of nickel ions from aqueous phase on calcined Bofe bentonite clay, J. of Hazard Mater., 177, 362–371 (2010)
  11. Crini G., Recent developments in polysaccharide based materials used as adsorbents in wastewater, treatment. Proly. Sci., 30, 38-70 (2005)
  12. David W.O., A modified cellulose adsorbent for the removal of nickel (II) from aqueous solution, Journal of Chemical Technology and Biotechnology., 81, 1820-1828 (2006)
  13. Dimitrova S.V., Use of granular slag column for lead removal, Water Resource, 36, 4001 4008 (2002)
  14. Yanli M., Hongwei H.Y. and Hongxian O., A novel extracellular biopolymer produced from pseudonas fluoresces C-2 preparation, characterization and adsorption behaviours toward nickel (II) ions in aqueous solution, Inter. J. Mat Str Integration., , 74-93 (2012)
  15. Kumar P.S.; Kirthika K. Equilibrium and kinetic study of adsorption of nickel from aqueous solution ontobael tree leaf powder, J. Eng. Sci. and Tech., 40, 351-363 (2009)
  16. Bernard E., Jimoh A. and Odigure J.O., Heavy metal removal from industrial wastewater by activated carbon prepared from coconut shell, Res. J. Chem. Sci.,3(8), 3-9 (2013)
  17. Malkoc E., Nuhuoglu Y., Removal of Ni(II) from aqueous solution using waste tea factory: Adsorption on a fixed- bed column, J. of Hazard Mater., 40, 326-336 (2006)
  18. Alka T. and Prerma K., Superparamagnetic PVA-Alginate microspheres as adsorbent for Cu2+ ion removal from aqueous system, Int.Res. J. of Environ Sci.,2(7), 44-53 (2013)
  19. Ozacar M. and Sengil A., Adsorption of complex dyes from aqueous solution by pine sawdust, J. Bioresource Technol.,7, 791-795 (2005)
  20. Lu C., Liu C. and G.P. Rao, Comparisons of sorbent cost for the removal of Ni2+ from aqueous solution by carbon nanotubes and granular activated carbon, J. of Hazard Mater. 151, 239-246 (2008)
  21. Carvalho W.A., Vignado C. and Fontana J., Ni(II) removal from aqueous effluents by silylated clays, J. of Hazard Mater., 153(3), 1240–1247 (2008)
  22. Ofomaja A. E., Intraparticle diffusion process for lead (II) biosorption onto mansonia wood sawdust, J. Bioresource Technol.,, 101(15), 5868–5876, (2010)
  23. Freundlich H., Uber Die, Adsorption in lunsungen, Journal of Physical Chemistry,57, 347– 470 (1985)
  24. Lagergren S., About the theory of so-called adsorption of soluble substances, Kungliga Svenska Vetenskapsakademiens Handlingar, 24 (4), 1–39 (1898)
  25. HoY., Ng J., McKay G., Kinetics of pollutant sorption by biosorbents: review, Separation Purification Technology., 29(2), 189–232 (2000)