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Cyclic Voltammetric Studies of Synthesized Cardanol based Azo Dyes

Author Affiliations

  • 1Dept. of P.G. Studies and Research in Industrial Chemistry, Kuvempu University, Jnana Sahyadri, Shankarghatta-577451, Shimoga(D), Karnataka(S), INDIA

Res.J.chem.sci., Volume 3, Issue (10), Pages 44-50, October,18 (2013)

Abstract

The efficient method for the synthesis of ten cardanol azo dyes using aniline and its derivatives is described. Coupling reaction of cardanol affording high yield in slightly acidic media was observed. All the dyes were characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, ultra violet - visible spectroscopy and mass spectrometry. The electrochemical behavior of these cardanol based azo dyes has been investigated by cyclic voltammetric technique by using sulfuric acid as supporting electrolyte. In addition, the effect of scan rate on dyes (2a 2j) showed irreversible one step two electron diffusion controlled reduction process. The peak potential was found to shift in the cathodic direction with increase in scan rate indicating the irreversible nature of the electrode reaction.

References

  1. Swain J.R., Biswal S.K., Lenka S., Polymer from renewable resources: Studies on synthesis, characterization, and thermal properties of resins derived from diazotized cardanol-formaldehyde-organic compounds, Polym. Plast. Technol. Eng., 39, 927-936 (2000)
  2. Saminathan M., Pillai C.K.S., Synthesis of novel liquid crystalline polymers with cross-linked network structures. Polymer, 41, 3103-3108 (2000)
  3. George John, Praveen Kumar Vemula, Design and development of soft nanomaterials from biobased amphiphiles, Soft Matter, 2, 909-914 (2006)
  4. Orazio Attanasi A., Stefano Berretta, Cinzia Fiani, Paolino Filippone, Giuseppe Mele, Raffaele Saladino, Synthesis and reactions of nitro derivatives of hydrogenated cardanol, Tetrahedron Lett., 62, 6113-6120 (2006)
  5. Attanasi O. A., Del Sole R., Filippone P., Ianne R., Mazzetto S. E., Mele G., Synthesis of Fullerene-Cardanol Derivatives, Synlett, 5, 799-802 (2004)
  6. Attanasi O. A., Ciccarella G., Filippone P., Mazzetto S. E., Mele G., Spadavecchia J., Novel phthalocyanines containing cardanol derivatives, J. Porphyrins Phthalocyanines, 7, 52-57 (2003)
  7. Mele G., Sole R. D., Vasapollo G., Garcia-Lopez E., Palmisano L., Mazzetto S. E., Polycrystalline TiO2 impregnated with cardanol-based porphyrins for the photocatalytic degradation of 4-nitrophenol, Green Chem., 6, 604-608 (2004)
  8. Attanasi O. A., Del Sole R., Filippone P., Mazzetto S. E., Mele G. J., Vasapollo G., Synthesis of novel lipophilic porphyrin-cardanol derivatives, J. Porphyrins Phthalocyanines, 8, 1276-1284 (2004)
  9. Guo Y. C., Xiao W. J., Mele G., Martina F., Margapoti E., Mazzetto S. E., Synthesis of new meso-tetraarylporphyrins bearing cardanol and further transformation of the unsaturated chains, J. Porphyrins Phthalocyanines, 10, 1071-1079 (2006)
  10. Guo Y. C., Mele G., Martina F., Margapoti E., Vasapollo G., Xiao W. J., An efficient route to biscardanol derivatives and cardanol-based porphyrins via olefin metathesis, J. Organomet. Chem., 691, 5358-5390 (2006)
  11. Somsaluay Suwanprasop, Thumnoon Nhujak, Sophon Roengsumran, Amorn Petsom, Petroleum Marker Dyes Synthesized from Cardanol and Aniline Derivatives, Ind. Eng. Chem. Res., 43, 4973-4978 (2004)
  12. Siriorn Puangmalee, Amorn Petsom, Patchanita Thamyongkit, A porphyrin derivative from cardanol as a diesel fluorescent marker, Dyes and Pigments, 82, 26-30 (2009)
  13. Ongera Gilbert, Kumara Swamy B. E., Umesh Chandra, Sherigara B. S., Simultaneous detection of dopamine and ascorbic acid using polyglycine modified carbon paste electrode: A cyclic voltammetric study, J. Electroanal. Chem., 636, 8085 (2009)
  14. Ghoneim M. M., Issa R. M., Issa Y. M., Mansour I. A., Tawifk A., Voltammetric Studies of some Formazan Compounds in Buffer Solutions, Bull. Electrochem., 14, 29- 33 (1998)
  15. Shalaby Yasin A., Electrochemical studies and thermodynamic parameters of citrazinic acid azo dye and its nitro derivatives in DMF-aqueous solutions, Portugaliae Electrochimica Acta, 24, 23-36 (2006)