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DAPA, EA, TU and BI as Vapour Phase Corrosion Inhibitors for Mild Steel under Atmospheric Conditions

Author Affiliations

  • 1 Material Science Lab., Dept. of Chemistry, Ch. Devi Lal University, Sirsa, Haryana 125 055, INDIA

Res.J.chem.sci., Volume 2, Issue (2), Pages 10-17, February,18 (2012)

Abstract

Four new vapour phase corrosion inhibitor (VPCI) i.e. 3,3-diaminodipropylamine (DAPA), ethylamine (EA), thiourea (TU), and benzimidazole (BI)were tested for mild steel in different atmospheric conditions at 500C by weight loss, Eschke test, salt spray method, SO2 test and metallurgical research microscopy technique. All investigated VPCIs exhibited very good corrosion inhibition efficiency for mild steel. DAPA showed the best corrosion inhibition efficiency. The result obtained from weight loss technique, Eschke test, salt spray method, SO2 test were supported by metallurgical research microscopy technique. Inhibition of corrosion in vapour phase by VPCI takes place because they alkaline the medium to pH value at which the rate of corrosion becomes significantly low.

References

  1. Free M.L., Klang W. and Ryu D.Y., Prediction of Corrosion Inhibition Using Surfactants, Corrosion, 60 837-844 (2004)
  2. Rozenfeld I.L., Corrosion Inhibition, New York, McGraw Hill Inc (1982)
  3. Kuznestor Y.L., Organic inhibitors of Corrosion of metals, Plenum Press, New York 70 (1996)
  4. Jones D.A., Principles and Preventions of Corrosion, nd Ed, Upper Saddle River, Prentice Hall, NJ, 503 (1996)
  5. Bregmann J.L., Corrosion Inhibition, Macmillan Co., New York (1963)
  6. Singh D.D.N. and Banerjee M.K., Anticorrosion Method, 31 4-8 (1984)
  7. Stupnisek-Lisac E., Cinotti V. and Retchenabach D., J. Appl. Electrochem, 29, 117-122 (1999)
  8. Subrumanian A., Natsen M., Murlitharan V.S., Balakrishan K. and Vasudevan T., An overview: vapor phase corrosion inhibitors, Corrosion, 56 144-155 (2000)
  9. Sastri V.S., Corrosion Inhibitors Principles and Applications, John Wiley & Sons, New York 787(1998)
  10. Rajgopalan K.S. and Ramaseshan G., J. Sci. Ind. Res., 19A, 275-280 (1960)
  11. Subrumanian A., Gopalakrishan R., Bhupati C.S., Balakrishan K., Vasudevan T. and Natesan M.N.S., Bull. Electrochem, 14, 739-744 (1998)
  12. Saurbier K., Rengaswamy M.V., Hchultze G.W., Geke J., Penninger J. and Robmeler H., Corros. Sci,33, 351 (1992)
  13. Vuarinew E.K., Br. Corros. J., 29, 120 (1994)
  14. Sekine I., Sambongih M., Hogiuda H., Oshibe T., Yuasa M., Imohama T., Shibata Y. and Wake T., J. Electrochem. Soc,139, 167 (1992)
  15. Muralitharan S., Pitchumani S., Ravichaneran S. and Iyur S.V.K., J. Electrochem. Soc, 142, 478 (1995)
  16. Zhang D.Q., Gao L.X., Mater. Perform., 42, 40(2003)
  17. Quraishi M.A., Jamal D., Synthesis and evaluation of some organic vapor phase corrosion inhibitors, Ind. J. Chem. Tech., 11, 459-464 (2004)
  18. Quraishi M.A. and Jamal D., Corrosion, 58, 387(2002)
  19. Tuken Yazici T. and Erbil B., Progress in organic coating, 50, 115 (2004)
  20. Starostina M., Smorodin A. and Galor L., Meter. Perform., 38, 52 (2000)
  21. Rajendran S., Apparao B.V. and Palaniswamy N., Corrosion and its Control, Proc. of International Conf. on Corrosion, Mumbai (1997)
  22. Quraishi M.A., Bhardwaj V. and Jamal D., Ind. J. Chem. Tech., 12, 98 (2005)
  23. Persiantsava V.P., Chemistry Review in Corrosion, Soviet Scientific Reviews of Mascow, OSSR, 8, 64(1987)
  24. Subrumanian A., Natesan M., Balakrishan K. and Vasudevan T., Bull. Electrochem.,15, 54 (1999)
  25. Dogra S.K., Dogra S., Physical Chemistry through Problems, Wiley Eastern Limited, New Delhi, 231 (1986)
  26. Narayan R., An Introduction to Metallic Corrosion and its Prevention, 1st ed, Oxford and IBH (1983)
  27. Furman A. and Chandler C., Test methods for Vapour Corrosion Inhibitors, Proc. 9th Eur. Sym. Corros. Inhib., Ann. Univ., 11, 465 (2000)