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Decolorization of acid orange 8 from textile effluent using alkaline OsO4/Chloramine-B solutions: Optimization and kinetic study

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Author Affiliations

  • 1Department of Chemistry, Don Bosco Institute of Technology (Affiliated to Visvesvaraya Technological University - Belagavi), Mysore Road, Bengaluru 560 074, India
  • 2Department of Chemistry, Presidency University, Bengaluru-560 064, India
  • 3Department of Chemistry, Jnanabharati Campus, Bangalore University, Bangalore-560 056, India
  • 4Department of Physics, Siddaganga College of Arts, Science and Commerce, Tumakuru, 572102, India

Res.J.chem.sci., Volume 12, Issue (1), Pages 48-57, February,18 (2022)

Abstract

The detoxification of dye effluents produced by the fabric industries is the key challenge in waste water treatment.. The oxidation process developed in the present studies shows many benefits viz., simple, low cost, mild experimental conditions, reduced reaction time, and environmental benevolence. Mono azo dye, acid orange 8 (AO 8) was used as model to explore the feasibility of using chloramine-B (CAB) with osmium tetroxide (OsO4) as a homogeneous catalyst in the practical decolorization of dye in waste water. The influence of process parameters such as dye concentration, CAB concentration, OsO4 concentration, alkali concentration and temperature was examined. The relative reactivity studies with other platinum group metal ions shows that OsO4 is an effective catalyst in the present redox system. The suggested oxidation process has appreciably reduced the Chemical Oxygen Demand (COD). The treated dye was less toxic and it was verified by phytotoxicity analysis. Importantly, this method can be expediently scaled up for industrial applications with appropriate adaptations to minimize the toxicity present in industrial effluents.

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