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Synthesis, Characterization and antimicrobial activity of macrocyclic metal complexes of Ni(II) and Cd(II)

Author Affiliations

  • 1Department of chemistry, University of Rajasthan, Jaipur 302004, India
  • 2Department of chemistry, University of Rajasthan, Jaipur 302004, India
  • 3Department of chemistry, University of Rajasthan, Jaipur 302004, India

Res.J.chem.sci., Volume 12, Issue (1), Pages 18-25, February,18 (2022)

Abstract

New macrocyclic complexes derived from the template condensation reaction of bis(benzil)4-chloro1, 2-phenylenediamine(ML1) and bis(benzi1) 4-nuro1, 2-phenylenediamine (ML2) respectively with different diamines in the presence of transition metal chlorides. The complexes were characterized by elemental analysis and spectral techniques i.e. JR, UV­visible, IH-NMR and mass. Spectral studies show that the geometry around the metal center is octahedral. The Schiff base ligand and its metal complexes were tested against pathogenic bacteria and fungi. All the complexes exhibit antibacterial and antifungal activities against various organisms.

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