International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

A study of suggested Formula (ADJ) of Specific Refraction

Author Affiliations

  • 1 Department of Chemistry, the H.N.S.B. Ltd. Science College, Himatnagar-383001, Gujarat, INDIA

Res. J. Physical Sci., Volume 2, Issue (5), Pages 1-7, September,4 (2014)

Abstract

The measurement of refractive index and optical activity of organic liquids is of great importance in chemistry. These measurements provide invaluable information regarding the molecular structure, purity of organic compounds and the composition of binary mixtures. Early years there are so many formulae found out by the various scientists. Amongst Lorentz and Lorenz formula is very familiar for the calculation of specific refraction of the organic compounds. It is worthwhile to suggest one more empirical formula for the calculation of specific refraction of organic compounds. This formula is known as Andher Desai Joshi (ADJ)’s formula. The suggested formula compared with that of Lorentz and Lorenz formula. From the comparison it is remarkable fact that the suggested formula holds good to the extent of ±0.02 marginal differences.

References

  1. Yadev J.B. Adv. Pract. Phys. Chem., 16, 157 (1998)
  2. Sylvester Havid, Kristian O., Per-Olof Astrand, Mark A. Ratner and Kurt. V., Mikkensen, Frequency depended Molecular Polaizability and Refractive index: Are Substituent Contributions Additive?, J. Phys. Chem. A.,103(12), 1818 (1999)
  3. Weisberg, Physical method of organic chemistry 3rdedition, 1 part II chapter 28, 1163 Wiley- Inter Science, New-York, (1960)
  4. Bauer N. and Fajans K., J. Ame. Chem. Soc.,64, 1163-1164 (1942)
  5. Eykman, Chem. Weckbel , 3, 653, 685, 701 (1906)
  6. Lorentz H.A., The Theory of Electrons, Dover, New York, NY,USA, (1952)
  7. Gadhawala Z.M., Andher S.S., Chavda M.R., Joshi H.D. and Desai C.M., J. Institution of Chemists (India), 78(4), 127-128 (2004)
  8. Chavda M.R., Andher S.S., Z.M. Gadhawala, Desai C.M. and Joshi H.D., J. Institution of Chemists(India),80(2), 42-44 (2008)
  9. Hynes W.M., Handbook of Chemistry and Physics, 92ndEdition. CRC press Boca Rotan FL (2011–2012)
  10. Sahu S., Nath G. and Paikary R., Res. J. Chem. Sci.,2(11), 64-66 (2012)
  11. Prathima A., Karthikeyan S., Jayalaxmi Band Veerapandiyan G., Res. J. Chem. Sci.,3(5), 43-46 (2013)
  12. Ali A., Nain A.K. and Kamil M., Physico-chemical studies of nonaqueous binary liquid mixtures at various temperatures, Thermochim Acta, 274, 209 (1996)
  13. Ali A., Hyder S. and Nain A.K., Studies of molecular interaction in binary liquid mixtures by velocity and viscosity measurements, Acoustics Lett., 21, 21 (1998)
  14. Nithiyanantham S. and Palaniappan L., Ultrasonic Study of the Self-Association of Aniline in Ethanol-Cyclohexane MixturesActa Ciencia Indica, 36(4), 533-538 (2005)
  15. Palaniappan L. and Karthikeyan V., Study of Acoustical Parameters of Binary Liquid Mixtures at 298K, Indian J Phys.,79(2), 155 (2005)
  16. Nithiyanantham S. and Palaniappan L., Correlation of the rates of solvolysis of tert-butyl chlorothioformate and observations concerning the reaction mechanism, Acta Ciencia Indica, 37(3),382-392 (2006)
  17. Vadamala R., Ram D. and Balakrishnan, Ultrasonic study of Binary Liquid Mixture of Methyl Methacrylate with alcohols, Resi J. Chem. Sci.,1(9), 79-82 (2011)
  18. Saravanakumar K. and Kubendran T.R., Density and Viscosities for the Binary Mixtures of 1, 4-Dioxane and Benzene or Chlorobenzene at 303.15, 308.15, 313.15 K and a Pressure of 0.1MPa, Research Journal of Chemical Sciences, 2(4), 50-56, (2012)
  19. Saravanakumar K. and Kubendran T.R., Density and viscosity of the Binary mixtures of 1,4 Dioxane and Benzene of cholorobenzene at 303.15, 308.15,313.15kand a pressure of 0.1 Mpa, Res. J. Chem. Sci.,2(4), 50-56 (2012)
  20. Gaurang Mahendra Kumar and Saxena Ashish KumarUltrasonic study of Intrections in Binary mixtures of Isopropyl benzene(cumene) with benzene,toluene and Acetone at 303, Res. J. Chem. Sci.,3(2), 27-30 (2013)