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Asafoetida Extract (ASF) as green Corrosion Inhibitor for Mild Steel in Sea Water

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Author Affiliations

  • 1Department of Chemistry, GTN Arts College, Dindigul Tamil Nadu, INDIA
  • 2 Department of Chemistry, APA College for Arts and Culture Palani, INDIA
  • 3 Department of Chemistry, RVS School of engineering and Technology, Dindigul, Tamil Nadu, INDIA

Int. Res. J. Environment Sci., Volume 1, Issue (5), Pages 14-21, December,22 (2012)

Abstract

An aqueous extract of asafoetida has been used as a corrosion inhibitor in controlling corrosion of carbon steel. The main constituent of this extract is umbelliferone. It has excellent inhibition efficiency (IE) of 98% at Zn2+ (25 ppm) by the weight loss method. The protective film has been analyzed using Atomic Force Microscopic (AFM) and FTIR spectroscopic techniques. Protective film formed on the metal surface is confirmed by using Electro chemical studies such as potentiodynamic polarization technique. Polarization study reveals that this system functions as mixed type of inhibitor.

References

  1. Mangale Sapana M., Chonde Sonal G. and Raut P.D., Use of Moringa Oleifera (Drumstick) seed as Natural Absorbent and an Antimicrobial agent for Ground water Treatment Res.J.Recent Sci.,1(3), 31-40 (2012)
  2. Sinha Kanak and Verma Anita K., Evaluation of Atimicrobial and Anticancer activities of Methanol Extract of in vivo and in vitro grown Bauhinia variegate L. I.Res.j.Biological Sci.,1(6), 26-30 (2012)
  3. Hegde Chaitra R., Madhuri M., Swaroop Nishitha T., Das Arijit., Bhattacharya Sourav and Rohit K.C., Evaluation of Antimicrobial Properties, Phytochemical Contents and Antioxidant Capacities of Leaf Extracts of Punica grantum L. ISCA J. Biological Sci.,1(2), 32-37 (2012)
  4. Sessou Philippe, Farougou Souabou, Azokpota Paulin, Youssao Issaka and Sohounhlou Dominique, In vitro Antifungal activities of Essential oils extracted from Fresh Leaves of Cinnamomum zeylanicum and Ocimum gratissimum against Foodborne pathogens for their use as Traditional Cheese Wagashi conservatives. Res.J.Recent Sci.,1(9), 67-73 (2012)
  5. Masih Usha, Shrimali R. and Nagvi S.M.A., Antibacterial Activity and Ethanol Extracts of Cinnamon (Cinnamomum Zeylanicum) and Ajowan (Trachyspermum ammi) on four food Spoilage Bacteria I.Res.J.Biological Sci., 1(4), 7-11 (2012)
  6. Anuradha K., Vimala R., Narayanasamy B., Arockia Selvi J., Rajendran S., Corrosion inhibition of carbon steel in low chloride media by an aqueous extract of Hibiscus rosa –sinensis Linn, Chem Eng Comm., 195-352 (2008)
  7. Arockia Selvi J., Susai Rajendran, Ganga sri V., John Amalraj A., Narayanasamy B., Corrosion inhibition by Beet Root extract, Portugaliae Electrochemica Acta. 27 (1), 1-11 (2009)
  8. Sumithra P., Shyamala Devi B., Jeyasundari J., Corrosion inhibition by Spirulina, Zastita Materijala,50, 223-226 (2009)
  9. Rajendran S., Paulraj J., Rengan P., Jeyasundari J. and Manivannan M., Corrosion behavior of metals in artificial saliva in presence of spirulina powder, Journal of Dentistry and Oral Hygiene1(1), 001-008 (2009)
  10. Obot I.B., Obi Egbedi N.O., An interesting and efficient green corrosion inhibitor for aluminium from extracts of Chlomolaena Odorata L. in acidic solution, Journal of Electro Chemistry40(11), 1977-1984 (2010)
  11. Ating E.I., Umoren S.A., Udousors I.I., Ebenso E.E., Udon A.P., Leaves extract of ananas sativum as green corrosion inhibitor for aluminium in hydrochloric acid solutions, Green Chemistry Letters and Revies3(2), 61-68 (2010)
  12. Obot I.B., Obi Egbedi N.O., Umoren S.A., Ebenso E.E., Synergistic and antagonistic effects of anions and Ipomoea invulcrata as green corrosion inhibitor for aluminium dissolution in acidic medium, International Journal of Electrochemical science5(7), 994-1007 (2010)
  13. Sangeetha M., Rajendran S., Muthumegala T.S., Krishnaveni A., Green corrosion inhibitors-An Overview, Zastita Materijala, 52, 3-19 (2011)
  14. Vijayalakshmi P.R, Rajalakshmi R., Subhashini S., Corrosion Inhibition of Aqueous Extract of Cocos nucifera - Coconut Palm - Petiole Extract from Destructive Distillation for the Corrosion of Mild Steel in Acidic Medium, Port Electrochim Acta29(1), 9-21 (2011)
  15. Lahhit N., BouyanzerA., Desjobert J.M.et al. Fennel (Foeniculum Vulgare) Essential Oil as Green Corrosion Inhibitor of Carbon Steel in Hydrochloric Acid Solution, Port Electrochim Acta29(2), 127-138 (2011)
  16. Vinod Kumar K.P., Narayanan Pillai N.S., Rexin Thusnavis G., Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium, Port Electrochim Acta28(6) 373-383 (2010)
  17. Bouyanzer A., Hammouti B., Majidi L.,et al. Testing Natural Fenugreek as an Ecofriendly Inhibitor for Steel Corrosion in 1 M HCl, Port Electrochim Acta28(3), 165-172 (2010)
  18. Odiongenyi A.O., Odoemelam S.A., Eddy N.O., Corrosion inhibition and adsorption properties of ethanol extract of Vernonia Amygdalina for the corrosion of mild steel in SO, portugaliae Electrochimica Acta,27(1), 33-45 (2009)
  19. .Obot I.B., Obi-Egbedi N.O., Ipomoea involcrata as an ecofriendly inhibitor for aluminium in alkaline medium, Portugaliae Electrochimica Acta27(4), 517-524 (2009)
  20. Aboia O.K., James A.O., The effects of Aloevera rxtract on corrosion and kinetics of corrosion process of zinc in HCl solution. Corrosion Science52(2), 661-664 (2010)
  21. Janaina Cardozo da Rocha, Jose Antonio da Cunha PoncianoGomes, Eliane D Elia, Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extract, Corrosion Science52(7), 2341-2348 (2010)
  22. Quraishi M.A., Singh A., Singh V.K., Yadav D.K., Singh A.K., Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves, Materials chemistry and Physics 122(1), 114-122 (2010)
  23. Al-Awadi FM et al. On the mechanism of the hypoglycaemic effect of a plant extract, Diabetologia, 28,432-434 (1985)
  24. Srinivasan K.,Role of Spices Beyond Food Flavoring: Nutraceuticals with Multiple Health Effects, Food Reviews International, 21(2), 167–188 (2005)
  25. Abdin M.Z. and Abdin Y.P., Abrol. Published Alpha Science Int'l Ltd. Traditional Systems of Medicine, ISBN 81-7319-707-5(2006)
  26. Rajendran S., Jeyasundari J., Usha P., Selvi J.A., Narayanasamy B., Regis A.P.P., Rengan P., Corrosion behavior of aluminium in the presence of an aqueous extract of Hibiscus rosa–sinensis. Portugaliae Electrochemica Acta,27(2), 153-164 (2009)
  27. Kasthuri P.K., Arulanantham A., Ecofriendly extract of Euphobia hirta as corrosion inhibitor on mild steel in sulphuric acidmedium. Asian Journal of Chemistry,22(1),430-434 (2010)
  28. Rajendran S., Agasta M., Bama Devi R., Shyamala Devi B., Rajam K., Jeyasundari J., Corrosion inhibition by an aqueous extract of Henna leaves (Lawsonia Inermis L), Zastita Materijala50(2), 77-84 (2009)
  29. Sangeetha M., Rajendran S., Sathiyabama J., Krishnaveni A., Shanthy P., Manimaran N., Shyamaladevi B., Corrosion inhibition by an aqueous extract of phyllanthus amarus, Portugaliae Electrochimica Acta, 29(6), 429-444 (2011)
  30. Lalitha A., Ramesh S. , Rajeswari S., Electrochim. Acta, 51, 47–55 (2005)
  31. Robert M. and Silverstein Francis X. Webster Spectrometric Identification of Organic Compounds, VI Edition, Wiley Student Editor:108 (2007)
  32. Satapathy A.K., Gunasekaran G., Sahoo S.C., Kumar Amit and Rodrigues P.V., Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution. Corrosion science, 51(12), 2848-2856 (2009)
  33. Benita Sherine, Jamal Abdul Nasser A., Rajendran S., In J. Eng. Sci. and Technol, 24, 341-357 (2010)
  34. Singh Ashish Kumar and Quraishi M.A., Corros.Sci., 53,1288-1297(2011)
  35. Wang B., Du M., Zhang J., Gao C.J., Corros.Sci., 53, 353-361 (2011)
  36. Lebrini M., Robert F., Roos C., Inhibition effect of alkaloids extract from Annona Squamosa plant on the corrosion of C38 steel in normal hydrochloric acid medium. International Journal of Electrochemical Science5(11), 1698-1712 (2010)
  37. Saratha R., Vasudha V.G., Emblica Officinalis (Indian Gooseberry) leaves extract as corrosion inhibitor for mild steel in 1N HCl medium, E-Journal of chemistry,7 (3),677-684 (2010)
  38. Badiea A.M., Mohana K.N., corrosion mechanism of low- carbon steel in industrial water and adsorption thermodynamics in the presence of some plant extracts,Journal of Materials Engineering and Performance, 18(9), 1264-1271 (2009)
  39. Raja P.B., Rahim A.A., sman H.O. and Awang K., Inhibitory effect of Kopsia singapurensis extract on the corrosion behavior of mild steel in acid media, Wuli Huaxue Xuebao/Acta Physico- Chimica Sinica, 26(8),2171-2176 (2010)
  40. Sharmila A., Prema A.A, Sahayaraj P.A., Influence of Murraya koenigii(curry leaves) extract on the corrosion inhibition of carbon steel in HCl solution, Rasayan Journal of Chemistry3(1), 74-81 (2010)