International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Application of Multivariate Statistical and Geochemical methods for Assessing of Groundwater pollution near controlled Landfill in Oum Azza area, NW Morocco

Author Affiliations

  • 1Science Faculty, Zoological Laboratory, Mohamed V Agdal University, Rabat, MOROCCO
  • 2 Scientific Institute, Pollution, Environmental Toxicology and Health Hazards laboratory, Mohamed V Agdal University, Rabat MOROCCO
  • 3 National Institute of Health, Department of toxicology, Health Ministry, Rabat MOROCCO
  • 4 Chemical Laboratory, Science Faculty, Mohamed V Agdal University, Rabat MOROCCO

Int. Res. J. Earth Sci., Volume 3, Issue (3), Pages 9-14, March,25 (2015)

Abstract

The concentration of various physico–chemical parameters including heavy metals was studied in the water samples collected around the controlled landfill (Rabat, Morocco); in order to assess the hydrochemical hydro-chemical quality of groundwater and to study the possible impact of leachate percolation on groundwater quality. The high level of hardness and low concentration of heavy metals demonstrate strong mineralization of groundwater. In exception, lead shows in some wells higher concentrations than the WHO standard. The Piper diagram was used to identify geochemical processes occurring in the Oum Azza area. The Principal Component Analysis(PCA) technique was used to identify natural and anthropogenic factors, which are at the origin of three main classes of water proved including; calcium bicarbonate water Mg - HCO -Ca2 + -Mg2 + , sodium chloride- water Cl -Na and Cl - Ca2+ water. The results of PCA, hydro-chemical and geochemical interpretation suggest that the great variation in groundwater quality is influenced by the nature of the rock host which modifies significantly the water chemistry, with high concentration of NO, NO, NH, suggesting the possible negative impacts of the landfill leachate on groundwater quality. The excess of lead metal may have occurred from the percolation of leachate in the nearby landfill, processing the urban and industrial waste from the municipalities of Rabat. This investigation demonstrates that the hydrochemistry quality of groundwater of Oum Azza could be traced back to both natural and anthropogenic processes.

References

  1. HakooLa décharge publique de Marrakech. Caractérisation des lixiviats, étude de leur impact sur les ressources en eau et essais de leur traitement, Thèse de Doctorat, (2001)
  2. Chofqi, A., Younsi, A., Lhadi E., Mania J., Mudry, J., Veron, A. Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco), J. Ear. Sc., 39, 509–516(2004)
  3. Rassam A., Bourkhiss B., A. Chaouch. and Bourkhiss M., Caractérisation des lixiviats et évaluation de la pollution de la décharge de la ville D´al hoceima / Maroc, J. Science Lib.,(2012)
  4. Zalaghi A. and Merzouki M., Caractérisation physicochimique de lixiviats du centre d’enfouissement technique de la ville d’Essaouira (Maroc), J. Sci.lib., (2013)
  5. Jensen D.L, Ledin A. and Christensen T.H., Speciation of heavy metals in landfill-leachate polluted groundwater, J.of Wat. Res., 33(11),2642–2650 (1999)
  6. Jupsin H., Praet E. and Vasel J.L., Sanitary landfill characterization and modelisation of their evolution,Preceding. International. Symposium: Environmental Pollution Control and Waste Management, 884–896 (2000)
  7. Baun A., Jense, S.D, Bjerg L., Christensen T.H. and Nyholm N., Toxicity of organic chemical pollution in groundwater down gradient of a landfill (Grindsted, Denmark), J. Env. Tech., 34, 647–1652 (2000)
  8. Bernache G., The environmental impact of municipal waste management: the case of Guadalajara metro area, Resour. Conserv, Recycling,39, 223–237 (2003)
  9. Christensen T.H, R. Kjeidsen R, Bjerg P.L, Jensen D.L, Christensen J, Bauna A, Albrechtsen H., Heron. J.G., Biogeochemistry of landfill leachate plumes. J. App. Geoch., 16, 659–718, (2001)
  10. Freyssin et P., Piantone P., Azaroual M., Y. Itard B. Clozel Leloup, D. Guyonnet and J.C. Baubron, Chemical changes and leachate mass balance of municipal solid waste bottom ash submitted to weathering, J. Was. Manag, 22,159–172 (2002)
  11. Zaïri M., Ferchichi M., Ismaïl A., Jenayeh M., H. Hammami H., Rehabilitation of El Yahoudia dumping site, Tunisia, J. Was. Manag, 24(10), 1023-34 (2004)
  12. Hudak P.F., Groundwater monitoring strategies for variable versus constant contaminant loading functions, J. Env. Monit. Ass., 50, 271–288 (1998)
  13. Moo-Young H., Johnson B., Johnson A., Carson D., Lew C., Liu S. and Hancock K., Characterization of infiltration rates from landfills: Supporting groundwater modeling efforts, J. Env. Monit. Ass, 96, 283–311 (2004)
  14. Mohd H.Z, Syafalni, Ismail Abustan I. and Mohd. A.A.N., Assessment of Hydrochemical and Isotopic Characteristics at Matang Landfill Site Using Multivariate Analysis, Proce. Eng., 50, 59–68 (2012)
  15. Clark I. and Fritz P., Environmental Isotopes in Hydrology, Lewis, Boca Raton, New York. Crawford, J. F. and Smith, P.G., Landfill Technology, 84–85 Butterworths, London. (1997)
  16. Mor S., Ravindra K., Dahiya R.P. and Chandra A., Leachate Characterization and Assessment of Groundwater Pollution near Municipal Solid Waste Landfill Site,J. Env. Monit. Ass, 118(1-3),435-456 (2006)
  17. Bohlke J.K., Groundwater recharge and agricultural contamination, J. Hydrog, 10, 153–179 (2002)
  18. Aiuppa A., Bellomo S., Brusca L., D’Alessandro W. and Federico C., Natural and anthropogenic factors affecting groundwater quality of an active volcano (Mt. Etna, Italy), J. Appl. Geochem., 18, 863–882 (2003)
  19. McMahon P.B., Bohlke J.K., Regional patterns in the isotopic composition of natural and anthropogenic nitrate in groundwater, high plains, USA., J. Env. Sci. Tech., 40,2965–2970 (2006)
  20. Jiang Y.J., Wu Y.X., Groves C., Yuan D.X. and Kambesis P., Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China, J. Cont. Hydrolo, 109, 49–61 (2009)
  21. Rekha P.N., Kanwar R.S., Nayak A.K., Hoang C.K. and Pederson C.H., Nitrate leaching to shallow groundwater systems from agricultural fields with different management practices, J. Env. Monit. and Ass., 13, 2550–2558 (2011)
  22. Güler C., Kurt M.A., Alpaslan M. and Akbulut C., Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in Tarsus coastal plain (Mersin, SE Turkey) using fuzzy clustering, multivariate statistics and GIS techniques, J. Hydrol., 414 (415),435–451 (2012)
  23. WHO, Guidelines for drinking-water quality, 4th ed., WHO Press Geneva, Switzerland, 541 (2011)
  24. Jourdan B., Piantone P., Lerouge C. and Guyonnet D., Atténuation des métaux à l'aval de sites de stockage de déchets (Synthèse bibliographique), BRGM/RP, 54417,110 (2005)
  25. De Miquel G., Rapport sur les métaux lourds et leurs effets sur l'environnement et la santé Paris: Sénat, 365 (2001)
  26. Aloueimine S.O., Méthodologie de caractérisation des déchets ménagers à Nouakchott (Mauritanie) : contribution à la gestion des déchets et outils d’aide à la décision, Thèse Doctorat, Universite Limoges, n° 12, 192 (2006)
  27. FévrierL., Transfert d'un mélange Zn-Cd-Pb dans un dépôt fluvio-glaciaire carbonaté. Approche en colonnes de Laboratoire, Thèse de Doctorat, Université de Lyon, 312 (2001)
  28. Pohland F.G., Cross W.H. and Gould J.P., Metal speciation and mobility as influenced by landfill disposal practices’, in: H. E. Allen, E. M. Perdue, and D. S. Brown (eds), Metals in Groundwater, Lewis Publishers, Boca Raton, 411–429 (1993)
  29. Yanful E.K., Quigley R.M. and Nesbitt H.W., Heavy metal migration at a landfill site, Sarnia, Ontario, Canada–2: Metal Partitioning and Geotechnical Implications, Journal of Applied. Geochemical, 3, 623–629 (1988)